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Method for preparing dispersion strengthened metal materials in batches

A dispersion strengthening, metal material technology, applied in metal material coating process, chemical instruments and methods, cleaning methods using liquids, etc. problems, to achieve the effect of anti-irradiation swelling and irradiation damage, excellent activation characteristics, and resistance to coolant corrosion

Active Publication Date: 2022-01-14
SOUTHWESTERN INST OF PHYSICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if the dispersed phase raw material is nano-sized ceramic particles, it is not easy to disperse it uniformly in the metal matrix melt
The specific performance is that it is easy to form clusters and uneven distribution, and it is difficult to achieve homogenization even with vigorous stirring and ultrasonic dispersion.
However, if the raw material of the disperse phase is pure metal, such as adding metals such as yttrium during smelting, and then performing subsequent internal oxidation to form a disperse phase, problems such as uncontrollable yttrium content will often be encountered, such as ablation or low solubility. Can not play an effective role in strengthening
A more effective method is to mechanically grind the mixture of metal particles and dispersed phase raw materials by means of powder metallurgy, but this method also has the problems of serious cold welding, low powder forming rate, and high content of introduced impurities; from the perspective of quality and Efficiency needs to be improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Grind and polish the surface of 99.95% vanadium rods or vanadium plates, and then cold-roll repeatedly, with a cold-rolling speed of 2m / min. A 10mm vanadium plate undergoes 95 consecutive cold-rollings, each time reducing thickness by about 0.1mm, to obtain a thickness of 0.5mm The vanadium plate, after cold rolling and hardening, has a hardness of more than 200Hv, and the vanadium plate is subjected to stress relief annealing in vacuum, with a vacuum degree of 1×10 -4 Pa, temperature 1000°C, time 3 hours, continue cold rolling after annealing, speed 0.5m / min, thinning about 0.05mm each time, 9 consecutive times until processed into a vanadium foil with a thickness of 0.05mm.

[0042] Then put the vanadium foil into acetone for 4 times of 20kHz ultrasonic cleaning, each time for 5min, and replace with fresh acetone each time, then wipe it with ethanol and dry it with cold wind to get the vanadium foil for use.

[0043] Put the vanadium foil in a vacuum of 1×10 -6 ~1×10...

Embodiment 2

[0049] Grind and polish the surface of a copper rod or copper plate with a purity of 99.99%, and then perform cold rolling repeatedly at a cold rolling speed of 5m / min. A copper rod with a diameter of 20mm undergoes 95 consecutive cold rollings with a thickness reduction of about 0.2mm each time to obtain 1mm thick copper plate. After cold rolling and hardening, based on the judgment that the copper plate is difficult to be cold rolled again, the copper plate is annealed in vacuum, and the vacuum degree is 1×10 - 3 Pa, temperature 300°C, time 3 hours. Continue cold rolling after the annealing treatment, the cold rolling speed is 2m / min, the cold rolling is about 0.1mm each time, and the rolling is divided into 8 times until it is processed into a copper foil with a thickness of 0.2mm.

[0050] Then in a vacuum of 1×10 -3 Stress-relief annealing is carried out under the condition of Pa, the temperature is 300°C, and the time is 2h; after cooling, the copper foil is cleaned i...

Embodiment 3

[0055] Grind and polish the surface of a V-4Cr-4Ti alloy plate with a material composition of 99.9%, and then repeatedly perform cold rolling at a speed of 2m / min to reduce the thickness by about 0.1mm each time. After the cold rolling is hardened, the hardness reaches 200Hv Above, the vanadium plate is subjected to stress-relieving annealing treatment in vacuum, and the vacuum degree is 1×10 -4 Pa, temperature 1000°C, time 3 hours, continue cold rolling after annealing treatment, finally repeated cold rolling into 10mm vanadium alloy plate.

[0056] The vanadium alloy plate and the 30μm thick dysprosium foil are laminated alternately, and then in the tungsten steel mold, sealed with a pure iron sheath, the temperature of 1200 ℃ and the pressure of 180MPa are used for hot isostatic diffusion connection, heat preservation and pressure 3 hours.

[0057] Afterwards, the diffusion-bonded clad plate is cold-rolled, and after hardening to 200Hv, the V-4Cr-4Ti clad plate is treated ...

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Abstract

The invention belongs to the field of material preparation, and particularly discloses a method for preparing dispersion strengthened metal materials in batches. The method comprises the following steps that metal foil / plate is machined, and the metal surface is cleaned and then subjected to repeated cold rolling treatment; ultrasonic cleaning is performed on the metal foil / plate; then stress relief annealing treatment is carried out on the metal foil / plate in vacuum; the metal foil / plate is coated, specifically, dispersed phase raw material coating is conducted on the metal foil / plate, and a dispersed phase raw material coating is obtained; multi-pass hot rolling treatment is performed, and lamination and hot rolling pretreatment is performed on the metal foil / plate; then multi-pass circulation 'lamination and vacuum hot rolling' treatment is carried out; and densification treatment is performed, the laminated metal foil is put into a mold, the mold is put into a sheath for hot isostatic pressing treatment, and the dispersion strengthened metal material is obtained through aging heat treatment. The preparation method is simple in process, efficient and good in repeatability, and the number and uniform distribution of dispersed phase particles can be effectively regulated and controlled.

Description

technical field [0001] The invention belongs to the field of material preparation, and in particular relates to a method for preparing dispersion-strengthened metal materials in batches. Background technique [0002] With the continuous development of science and technology, the service environment of materials is becoming more and more complex and harsh, and the requirements for material performance are also getting higher and higher. For example, fusion reactor structural materials, especially cladding / first wall structural materials, require materials with excellent low activation characteristics, high temperature strength, resistance to radiation swelling and radiation damage, high thermal conductivity, Low thermal expansion coefficient, good creep resistance, good processing performance, and coolant corrosion resistance. Traditional materials are increasingly unable to meet the requirements of such properties. Research and design materials with better performance and ma...

Claims

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Application Information

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IPC IPC(8): B21B1/40B21B37/16B21B37/56B21B37/74B02C17/10B08B3/08B08B3/12B21B45/02C21D1/30C21D1/773C21D1/74C23C14/34C23C24/04C23C14/16C25D5/00
CPCB21B1/40B21B45/0272B08B3/12B21B37/16B21B37/74B08B3/08B21B37/56B02C17/10C21D1/30C21D1/773C21D1/74C23C14/34C23C24/04C23C14/16C23C14/165C25D5/00Y02E30/10
Inventor 谌继明郑鹏飞张归航李峰钱伟魏然车通刘星张明徐莉莎
Owner SOUTHWESTERN INST OF PHYSICS