Electrolyte liquid with fast charging and ultralow-temperature discharging performances and lithium ion battery
A lithium-ion battery and discharge performance technology, applied in secondary batteries, battery electrodes, organic electrolytes, etc., can solve the problems of limiting the application range of lithium-ion batteries, low discharge efficiency, etc. The effect of electrical and thermal conductivity
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Embodiment 1
[0040] An electrolyte solution that takes into account both fast charge and ultra-low temperature discharge performance, including solvents, electrolytes and additives.
[0041] Wherein, the solvent includes ethylene carbonate, dimethyl carbonate, ethyl methyl carbonate and propylene carbonate with a mass ratio of 1:1:1:0.5. On the basis of the original ternary solvent, propylene carbonate is added to become a quaternary solvent. Because propylene carbonate has the characteristics of low melting point and large dielectric constant, it can significantly improve the low-temperature performance of the battery.
[0042] The electrolyte includes lithium hexafluorophosphate and lithium tetrafluoroborate at a mass ratio of 1:0.5, and the molar concentration of the electrolyte is 1mol / L. The commonly used electrolyte for lithium-ion batteries is lithium hexafluorophosphate, which has stable electrochemical performance at room temperature and is easily soluble in organic solvents. How...
Embodiment 2
[0046] A lithium ion battery, comprising a positive electrode sheet, a negative electrode sheet, a separator and an electrolyte, wherein the electrolyte is as described in Example 1.
[0047] Positive sheet production:
[0048] The positive electrode slurry includes the following components in mass percentage: 92-94% main active material, 1-3% conductive carbon black, 0.5-1% graphene, 0.5-1% aluminum nitride, 2.5-4.5% polyvinylidene fluoride . The main active material is used to provide battery charge and discharge capacity; conductive carbon black is used to improve the conductivity of positive electrode materials; graphene is used to improve the superconductivity of positive electrode materials; aluminum nitride is used to improve the thermal conductivity of positive electrode materials; Ethylene is used to improve the binding properties of the positive electrode material. The main active material is preferably lithium iron phosphate.
[0049] The positive electrode slurr...
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