Dual-neuromorphic device based on charge trapping effect and electric double-layer effect and preparation method of dual-neuromorphic device
A technology of charge trapping layer and charge trapping, which is applied in the fields of electronics and materials science, can solve problems such as asymmetry change, conductance nonlinearity, cumbersomeness, etc., and achieve the effects of reducing difficulty, enhancing linearity and symmetry, and simplifying circuits
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Embodiment 1
[0033] Example 1, a method of preparing PYPN: This material is synthesized by three-step chemistry. (1) 0.245 mol of potassium carbonate, 20 ml of aniline, and 100 mL of DMF were added to 250 mL of two flasks, and nitrogen was protected, stirred at 0 ° C for half an hour, and then 19 ml of 3-bromopropylene was added to the reaction liquid. After 6 hours, 500 ml of water was added to the reaction liquid and the reaction was completed. Three times were extracted with dichloromethane, the organic phase was collected, dried over anhydrous magnesium sulfate, filtered, and the organic phase solvent was evaporated. Bottles, 15.7 mmol of allyl ionine, 12.1 mmol of 3-bromipapridine, 18.2 mmol of t-butyl sodium, and dried 20 ml toluene were added to the reaction bottle, and nitrogen was protected for 20 minutes, then 14 mg of tetrafluoride Tri-tert-butyl phosphorus and 35 mg of bis (diebenzyl acetone) palladium were rapidly added to the reaction solution, and the air in the reaction liquid ...
Embodiment 2
[0034]Example 2, a method of preparing a PN: Take 2 mmol of allyl aniline, 3 mmol of triethoxysilane and 2.0 mg of Caster catalyst addition to the reaction bottle, under nitrogen protection, reaction liquid heating to 95 ° C reaction 12 Hour. After the reaction, cooled to room temperature, the crude product was separated from the column to obtain the final product PN.
Embodiment 3
[0035] Example 3, a method of preparing DPN: This material was synthesized by two-step chemistry. (1) Take 29.9 mmol of diphenylamine, 59.9 mmol of potassium hydroxide, 45 ml of acetonitrile, added to 100 ml of two flasks, nitrogen protection, and the reaction liquid is mixed for half an hour, and 59.9 mmol of allyl bromine is added to the reaction liquid. Heating was refluxed for 6 hours, and 150 ml of ultrapure water was added to the reaction liquid to end the reaction. The organic phase was extracted with dichloromethane, dried over anhydrous magnesium sulfate, removing the organic solvent, separated by chromatography, to obtain N-allyl-N-phenylniline; (2) Take a 20 ml of Slack Bottles , 2 mmol of N-allyl-N-phenyl ketaniline, 3 mmol of triethoxysilane and 2.0 mg of Caster catalyst were added to the reaction bottle, and under nitrogen protection, the reaction liquid was heated to 95 ° C for 12 hours. . After the reaction, cooled to room temperature, the crude product was separat...
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