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Ceramic composition, ceramic sintered body, capacitor and capacitor manufacturing method

A composition and sintered body technology, applied in the direction of fixed capacitor dielectrics, multilayer capacitors, fixed capacitor components, etc., can solve the problems of increasing production costs, pending development, and decreasing MLCC insulation resistance, so as to reduce production costs and improve The effect of dielectric constant

Active Publication Date: 2022-07-19
DONGGUAN HUAKE ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, although there are literatures that use bismuth (Pb) and lead (Pb) to replace the barium of barium titanate, so that the Curie temperature can be moved to a higher temperature, so as to increase the upper limit of the operating temperature of MLCC, but it is necessary to cooperate with gold (Au) and silver. (Ag) and other noble metals are used as internal electrodes to prevent bismuth and lead and base metal electrodes from being reduced to conductors after sintering together in a reducing atmosphere, which will lead to a decrease in the insulation resistance of MLCC.
Based on the fact that multilayer internal electrodes are required inside the multilayer ceramic capacitor, if gold and silver and other precious metals are used, the production cost will be greatly increased, so the MLCC manufacturing technology that reduces production cost and meets the EIA-X8R specification is still to be developed

Method used

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  • Ceramic composition, ceramic sintered body, capacitor and capacitor manufacturing method
  • Ceramic composition, ceramic sintered body, capacitor and capacitor manufacturing method
  • Ceramic composition, ceramic sintered body, capacitor and capacitor manufacturing method

Examples

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Effect test

preparation example 1

[0070] Preparation Example 1: Capacitor

[0071] The preparation method of each embodiment of the present invention is the same as the preparation method, and the process description is as follows: using the mixed solution of ethanol and toluene as the solvent, add 100 moles of the main mixture powder into the solvent, and add a commercially available dispersant, and uniformly mix with a bead mill. , to obtain the main mixed slurry; add the auxiliary mixture powder to the same solvent, and uniformly mix with a bead mill to obtain the auxiliary mixed slurry; wherein, the mole percentages of the auxiliary mixture powder shown in Table 1 and Table 2 below, Based on 100 mole percent of the main mix powder. Mix the main mixed slurry and the auxiliary mixed slurry, add commercial organic binder PVB, and uniformly mix with a bead mill to obtain a ceramic slurry; the ceramic slurry is formed into a ceramic thin film with a thickness of 10 microns by a coating machine. Tape; on the surf...

Embodiment 1-1 to Embodiment 1-6

[0079] The preparation methods of Examples 1-1 to 1-6 are the same as those described in Preparation Example 1; the formulations of Examples 1-1 to 1-6 and the capacitance permittivity, dissipation factor (DF) and capacitance value change rate The detection results of (TCC) are shown in Table 1. When the multilayer ceramic capacitors prepared by the formulations of the above examples meet the EIA-X8R standard, it is represented by O in the table.

[0080] As can be seen from Table 1, based on the total weight of the main mixture, when the content of the first main component powder is 60 to 90 percent by weight, the content of the second main component powder is 10 to 40 percent by weight; and the main mixture 100 mole percent, rare earth oxides are 2 mole percent to 4 mole percent, silicon oxides are 0.2 mole percent to 1 mole percent, and alkaline earth metal oxides are 1 mole percent to 5 mole percent, the capacitors can meet EIA- X8R standard; in addition, the dielectric c...

Embodiment 1-1、 Embodiment 1-2、 Embodiment 2-1 to Embodiment 2-13

[0083] The preparation methods of Example 1-1, Example 1-2, Example 2-1 to Example 2-13 are the same as those described in Preparation Example 1; The detection results of the capacitance value change rate (TCC) are shown in Table 2. When the multilayer ceramic capacitors prepared by the formulations of the above examples meet the EIA-X8R standard, it is represented by O in the table.

[0084] From the comparison between Example 1-1 and Example 2-1 and the comparison between Example 1-2 and Example 2-8 in Table 2, it can be seen that when the third main component powder is further added to the ceramic composition, the loss of capacitance The factors are all halved, it can be seen that the addition of the third main component powder can help to improve the dissipation factor of the capacitor.

[0085] Second, from the comparison between Example 2-4 and Example 2-7, it can be seen that increasing the addition amount of rare earth oxide can improve the loss factor of the capacito...

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Abstract

The invention provides a ceramic composition, a ceramic sintered body, a capacitor and a capacitor manufacturing method. The ceramic composition includes a primary mixture and a secondary mixture, in which the primary mixture includes a first primary component powder and a second primary component powder, and the first primary component powder includes BaTiO3, the second primary component powder includes any one or a combination of SrTiO3, Ba0. 95Ca0. 05TiO3, BaZr0. 1Ti0. 9O3, and the secondary mixture includes a rare earth oxide, a silicon oxide, and an alkaline earth metal oxide. The invention also provides a ceramic sintered body obtained by sintering the ceramic composition, a capacitor comprising the ceramic sintered body and a capacitor manufacturing method. Wherein the capacitor meets the EIA-X8R standard, and has a high dielectric constant.

Description

technical field [0001] The present invention relates to ceramic compositions, especially ceramic compositions for capacitors. The present invention further relates to a capacitor comprising a ceramic sintered body and a method for producing the capacitor, especially a multilayer ceramic capacitor and a method for producing the same. Background technique [0002] There are many types of capacitors, among which Multi-layer Ceramic Capacitor (MLCC) uses barium titanate (BaTiO3) as the dielectric material; MLCC is widely used in consumer electronic products due to its small size and easy wafering. For example: mobile phone. In addition, MLCC also has the advantage of a wide operating temperature range, so vehicles that need to withstand severe temperature changes also rely heavily on MLCC. At present, the specification of MLCC widely used in the market is EIA-X7R; among them, EIA refers to the Electronic Industries Alliance (EIA), X indicates that the lower limit of the MLCC o...

Claims

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Application Information

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IPC IPC(8): C04B35/468C04B35/491H01G4/12H01G4/30
CPCC04B35/468C04B35/491H01G4/1227H01G4/30C04B2235/3236C04B2235/3248C04B2235/3224C04B2235/3418C04B2235/3205C04B2235/36C04B2235/3206C04B2235/3208C04B2235/3213C04B2235/3215C04B2235/96
Inventor 曾俊儒朱立文
Owner DONGGUAN HUAKE ELECTRONICS