Barium titanate ceramic capacitor medium and preparing method thereof

A technology of ceramic capacitors and barium titanate, which is applied in the direction of fixed capacitor dielectrics, ceramics, components of fixed capacitors, etc., can solve the problems of high production cost and insufficient dielectric constant, and achieves low production cost and simplified production process. , the effect of low price

Inactive Publication Date: 2006-01-11
TIANJIN UNIV
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Problems solved by technology

Chinese patent 98124799.7 discloses the composition and preparation method of a temperature-stable high-dielectric multilayer ceramic capacitor material. The material is based on barium titanate and the additive is Co 2 o 3 , Nb 2 o 5 , rare earth oxides and MnO 2 , the dielectric constant at room temperature can reach 4400, the capacity temperature change rate is ≤±15%, and the resistivity is 10 12~13 Ω cm, although the performance of this ceramic material can meet the requirements of X7R capacitors, its dielectric constant is not large enough, and the dielectric loss is not mentioned. In addition, its preparation method still adopts a two-step process of raw material synthesis and then sintering. Therefore, the production cost is higher

Method used

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Examples

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example 1

[0012] (1) First, the analytically pure BaTiO 3 calcined, heated to 1160-1200°C at a heating rate of 6-7°C / min, kept for 2 hours, and cooled for later use;

[0013] (2) Put Bi 2 O 3 , B 2 O 3 , SiO 2 Mix according to the weight ratio of 40:8:8, melt and quench to obtain glass;

[0014] (3) According to calcined BaTiO 3 The weight is 100g, add 1.25g Nb 2 O 5 , 0.35g CoCO 3 , 0.5gCeO 2 , 0.25g glass ingredients, its composition code is A, ball milled with zirconia balls and deionized water for 8 hours, and dried in an electric drying oven at 120 ° C to pass 250 holes / cm 2 A sample sieve, then add 6-7wt% paraffin to granulate, press it into a green wafer with a diameter of 15mm and a thickness of 2mm under a pressure of 60-80MPa, and finally put it into an electric furnace for firing, first press 3 ℃ The ceramic medium is prepared by heating to 500°C at a heating rate of

[0015] The sintered ceramic dielectric was re-fired with silver-infiltrated electrodes, and the ...

example 2

[0017] As calcined BaTiO 3 The weight is 100g, add 1.00g Nb 2 O 5 , 0.50g CoCO 3 , 0.25g CeO 2 , 0.50g glass ingredients, its composition code is B, the preparation and measurement of other process conditions and capacitor samples are the same as Example 1.

example 3

[0019] As calcined BaTiO 3 The weight is 100g, add 1.50gNb 2 O 5 , 0.10g CoCO 3 , 0.10g CeO 2 , 0.35g glass batching, its composition code is C, the preparation and measurement of other process conditions and capacitor samples are the same as Example 1.

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Abstract

This invention discloses a condenser medium of barium titanate ceramics and its preparation method, which takes BaTiO3 as the main composition, its weight is 1 added by the following weight percentages: Nb2O5: 1.00~1.50%, CoCO3 0.1~0.5%, CeO2: 0.1~0.5% and a fusing agent: 0.25~0.50%. They are mixed to an adjuvant to be ball-ground, prilled and dry-pressed to a round green compact sheet to be burnt in oven under 1240deg.C to be insulated for 4-8 hours and cooled for 10 hours in the oven to be manufactured to a ceramic condenser medium. Since the dielectric constant of the medium is high the medium loss is small and its volume temperature absolute value is less than 13%, thermal stability is good, it can be used in producing large volume condensers or other electronic devices.

Description

technical field [0001] The invention relates to a dielectric ceramic composition and a preparation method, in particular to a barium titanate-based ceramic medium and a preparation method thereof. Background technique [0002] With the development of surface mount technology in electronic circuits, the volume of multilayer ceramic capacitors (MLCs) is required to be more miniaturized, which requires dielectric materials with higher capacitance and better thermal stability. The dielectric materials used to manufacture low-frequency, high-dielectric and thermally stable MLCs are currently mainly X7R ceramic materials. X7R represents a temperature-capacity characteristic, that is, in the range of -55 to +125°C, its capacity-temperature change rate |ΔC / C 25℃ |≤15%. This type of capacitor is widely used in the coupling circuit of high-end electronic equipment such as mobile phones. During the transmission process of the front and rear stages, the distortion of the signal shoul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G4/12H01B3/12C04B35/468C04B35/622
Inventor 吴顺华李媛
Owner TIANJIN UNIV
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