Polypropylene composite material for automobile bumper and prepn. thereof

A technology for automobile bumpers and composite materials, which is applied in the field of high-activity, low-expansion heat-resistant polypropylene composite materials and their preparation, can solve the problem of high requirements for bumper fixing process and size matching, bumper loosening or damage, thermal expansion coefficient High problems, to achieve the effect of improving processing rheology, not easy to loosen or destroy, and high surface activity

Inactive Publication Date: 2006-09-20
SHANGHAI KINGFA SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Sometimes if the flame is not handled properly, the whole batch of painted bumpers will be scrapped, causing heavy losses
[0005] The current bumper material has a high coefficient of thermal expansion, which requires high fixing process and dimensional matching of the bumper, and causes the size of the bumper to change due to temperature changes during use, resulting in deformation of the bumper and internal stress, which is easy to cause Loose or br

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Preparation of activated toughened masterbatch: 2 kg of activated monomer m-phenylbismaleimide, 26.5 kg of polypropylene with a molecular weight of 110,000 and polyolefin elastomer ethylene-α-ethylene-octene copolymer 70 Kilograms are reactively extruded in a screw extruder with an aspect ratio of 1:40, the reaction temperature is 230°C, and the reaction time is 30 seconds;

[0042] Preparation of filler masterbatch: 27 kg of polypropylene powder with a molecular weight of 120,000, 70 kg of pre-mixed inorganic filler calcium carbonate and aluminum silicate whiskers with a particle size of 3 microns, and 0.2 kg of heat stabilizer Irganox 1010 (CIBA company) and 0.5 kilograms of initiator two (tertiary butyl peroxy isopropyl) are extruded in extruder;

[0043] 61.4 kilograms of polypropylene, 0.2 kilograms of phenolic heat stabilizer Irganox 1010 (CIBA company), 0.4 kilograms of N-alkylated light stabilizer TINUV 770 (CIBA company), 1.0 kilograms of carbon black, 17 kilog...

Embodiment 2

[0046] (1) Preparation of activated toughened masterbatch: 2.5 kg of activated monomer ethylene glycol dimethacrylate, 30 kg of polypropylene with a molecular weight of 110,000 and polyolefin elastomer ethylene-α-ethylene-octene copolymerized 67.5 kg of the product was reactively extruded by a screw extruder with a length-to-diameter ratio of 1:40, the reaction temperature was 210° C., and the reaction time was 20 seconds;

[0047] (2) Preparation of filling masterbatch: 27 kg of polypropylene powder with a molecular weight of 120,000, 70 kg of pre-mixed inorganic filler talcum powder and magnesium sulfate whiskers with a particle size of 3 microns, and 0.2 kg of heat stabilizer Irganox 1010 and 0.5 kg of initiator diacyl peroxide are extruded in the extruder;

[0048] (3) 68.9 kilograms of polypropylene, 0.2 kilograms of phenolic heat stabilizer Irganox 1010 (CIBA company), 0.4 kilograms of N-alkylation light stabilizer TINUV 770 (CIBA company), 1.0 kilograms of carbon black, 1...

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Abstract

This invention discloses a kind of polypropylene composite materials for automobile bumpers and its preparation method. This kind of materials comprises 93.3~56.5wt% polypropylene, 0.2~1.5wt% thermo-stabilizers, 0.3~1wt% photo-stabilizers, 0.2~1% auxiliary reagents, 1~20wt% activating and reinforcing masterbatches and 5~20wt% stuffing masterbatches. The product in this invention has high surface activity, low thermo expansion rate and high thermo expansion temperature. The surface tension is 40mN/m, the linear thermo expansion rate is 10 to the power -6 to 10 to the power -7 mm per mm per deg. C, the thermo deformation temperature is 55 deg. C and some other technological indices all reach or exceed current standards for automobile materials. Thanks to the high surface tension and strong paint-adhesion of the bumpers made of this kind of materials, paints can be directly sprayed rather than flame processing. The thermo expansion rate is low, and therefore, loosening due to significant deformation might not occur with large temperature variation. Besides, it also has the advantages of high the thermo resistant temperature, short baking time and high production efficiency.

Description

technical field [0001] The invention relates to a propylene composite material and a preparation method thereof, in particular to a high-activity low-expansion heat-resistant polypropylene composite material for automobile bumpers and a preparation method thereof. Background technique [0002] In the field of automotive materials, materials for cars represent the current highest level. At present, the bumper material of cars is generally EPDM modified polypropylene, and the amount of this material reaches more than 70% of the total amount of bumper materials. [0003] At present, whether it is foreign or domestic bumper materials, although they have reached the current automotive material standards, there are still deficiencies in certain processing aspects, which need to be compensated by increasing the processing technology of auto parts manufacturers, which increases production costs. Can not fully meet the bumper material market demand. A few representative questions a...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K5/524B60R19/03
Inventor 吉继亮陈广强
Owner SHANGHAI KINGFA SCI & TECH
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