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Soi substrate and method for manufacturing the same

Inactive Publication Date: 2010-04-22
SEMICON ENERGY LAB CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012]A single crystal semiconductor ingot or a single crystal semiconductor wafer manufactured by the CZ method contains oxygen at a concentration of 1×1017 atoms / cm3 to 1×1018 atoms / cm3, and the concentrations of nitrogen and carbon are 4×1015 atoms / cm3 or less and 2×1016 atoms / cm3 or less, respectively, even though they are added intentionally. The impurity concentration in a single crystal semiconductor ingot manufactured by the FZ method is generally lower than that in a single crystal semiconductor ingot manufactured by the CZ method; therefore, the single crystal semiconductor ingot manufactured by the FZ method has a problem of a poor mechanical strength to be easily broken. On the other hand, since the impurity concentration in bulk silicon manufactured by the CZ method is higher than that in bulk silicon manufactured by the FZ method, bulk silicon manufactured by the CZ method has a higher mechanical strength.
[0039]When at least one element of nitrogen, oxygen, and carbon is contained in a single crystal semiconductor layer formed on an insulating surface at a predetermined concentration, the mechanical strength of an SOI substrate having the single crystal semiconductor layer can be improved. Furthermore, generation of voids in the single crystal semiconductor layer can be suppressed.

Problems solved by technology

In the case where a large-sized device such as a display or a device having a curvature is formed using, for example, a single crystal silicon layer formed on an insulating substrate such as a glass substrate as disclosed in Patent Document 2, a poor mechanical strength of the single crystal silicon layer due to its reduced thickness has been a problem.
The poor mechanical strength of the single crystal silicon layer with a reduced thickness might cause cracks and breaking of the single crystal silicon layer in the manufacture or use of the device.
In addition, there has been a problem in that linear defects (dislocations) or planar defects occur or grow, and even when a transistor is formed using the single crystal silicon layer, characteristics of the transistor are deteriorated.
The impurity concentration in a single crystal semiconductor ingot manufactured by the FZ method is generally lower than that in a single crystal semiconductor ingot manufactured by the CZ method; therefore, the single crystal semiconductor ingot manufactured by the FZ method has a problem of a poor mechanical strength to be easily broken.

Method used

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  • Soi substrate and method for manufacturing the same
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embodiment 1

[0055]In this embodiment, an example of a method for manufacturing an SOI substrate will be described with reference to drawings. Specifically, description will be made on the steps of forming a single crystal semiconductor layer over a base substrate with an insulating layer interposed therebetween by Smart Cut (registered trademark) method and recovering the crystallinity of the single crystal semiconductor layer.

[0056]First, a single crystal semiconductor substrate 100 and a base substrate 120 are prepared (see FIGS. 1A and 1B).

[0057]As the single crystal semiconductor substrate 100, for example, a single crystal semiconductor substrate formed of an element belonging to Group 14, such as a single crystal silicon substrate, a single crystal germanium substrate, or a single crystal silicon germanium substrate, can be used. A commercially-available silicon substrate is typically a circular substrate having a size of 5 inches (125 mm) in diameter, 6 inches (150 mm) in diameter, 8 inc...

embodiment 2

[0088]In this embodiment, bonding of the single crystal semiconductor substrate 100 to the base substrate 120 will be described in detail with reference to drawings.

[0089]First, the single crystal semiconductor substrate 100 is prepared (see FIG. 2A-1). It is preferable that the surface of the single crystal semiconductor substrate 100 be cleaned in advance with a sulfuric acid / hydrogen peroxide mixture (SPM), an ammonium hydroxide / hydrogen peroxide mixture (APM), a hydrochloric acid / hydrogen peroxide mixture (HPM), hydrofluoric acid / hydrogen peroxide mixture (FPM), dilute hydrofluoric acid (DHF), or the like to remove dust. Dilute hydrofluoric acid and ozone water may be discharged alternately for cleaning. In the case where a natural oxide film is formed on the surface of the single crystal semiconductor substrate 100, the natural oxide film can be removed by alternately discharging ozone water and dilute hydrofluoric acid on the surface of the single crystal semiconductor substra...

embodiment 3

[0142]In this embodiment, an apparatus for irradiating a single crystal semiconductor layer provided over a base substrate with a laser beam (a laser irradiation apparatus) will be described with reference to drawings.

[0143]The laser irradiation apparatus described in this embodiment includes a laser oscillator 602 for emitting a laser beam 600 and a stage 606 over which a processing substrate 604 is arranged (see FIG. 3). A controller 608 is connected to the laser oscillator 602. The energy, repetition rate, and the like of the laser beam 600 emitted from the laser oscillator 602 can be changed by the controller 608. Furthermore, a heating means 610 such as a resistance heating device is provided in the stage 606 so as to heat the processing substrate 604.

[0144]The stage 606 is provided inside a chamber 612. The stage 606 is provided to be able to move in the above chamber.

[0145]A part of the wall of the chamber 612 is provided with a window 616 for introducing the laser beam 600 t...

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Abstract

To provide an SOI substrate having a high mechanical strength, and a method for manufacturing the SOI substrate, a single crystal semiconductor substrate is irradiated with accelerated ions so that an embrittled region is formed in a region at a predetermined depth from a surface of the single crystal semiconductor substrate; the single crystal semiconductor substrate is bonded to a base substrate with an insulating layer interposed therebetween; the single crystal semiconductor substrate is heated to be separated along the embrittled region, so that a semiconductor layer is provided over the base substrate with the insulating layer interposed therebetween; and a surface of the semiconductor layer is irradiated with a laser beam so that at least a superficial part of the semiconductor layer is melted, whereby at least one of nitrogen, oxygen, and carbon is solid-dissolved in the semiconductor layer.

Description

BACKGROUND OF THE INVENTION[0001]1. Field of the Invention[0002]The present invention relates to a substrate in which a single crystal semiconductor layer is provided on an insulating layer, and a method for manufacturing the substrate. In particular, the present invention relates to an SOI (silicon on insulator) substrate and a method for manufacturing the same. Furthermore, the present invention relates to a semiconductor device formed using an SOI substrate and a method for manufacturing the same.[0003]2. Description of the Related Art[0004]In recent years, devices such as semiconductor integrated circuits, which use an SOI substrate including a thin single crystal semiconductor layer formed on an insulating surface, have been developed instead of those using a bulk silicon wafer. Since the parasitic capacitance between a drain of a transistor and a substrate is reduced by using an SOI substrate, SOI substrates have attracted attention as substrates for improving the performance ...

Claims

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Application Information

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IPC IPC(8): H01L29/06H01L21/762
CPCH01L21/76254H01L27/12H01L21/20
Inventor OHNUMA, HIDETOHIGA, EIJI
Owner SEMICON ENERGY LAB CO LTD