Foamed celluloid mortar propellant increment containers
a technology of propellant container and foam celluloid, which is applied in the direction of looms, explosives, weaving, etc., can solve the problems of affecting the velocity and range of foam mics affecting the combustible case of typical foam celluloid by as much as 5%, and achieving the same level of water resistance, easy moldability, and easy manufacturing
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example 1
Preferred Combined CBA / PBA Process for Manufacture of Foamed Celluloid
[0016]1. In a mixer that can be heated, such as a Measuring Mixer manufactured by Brabender GmbH & Co., Duisburg, Germany, combine about 50 weight % nitrocellulose (NC), having a nitrogen content of from 10.5 wt. % to 13.5 wt. %, preferably lower than 12.6% and most preferably about 11%; with about 15 wt. % camphor; with about 3% of a chemical blowing agent (CBA) that will generate CO2 when decomposed, potential CBAs include sodium bicarbonate, azodicarbonamide (commonly referred to as AZ), benzene sulfonylhydrazide, and 5-phenyl tetrazole, and a commercial CBA which is particularly preferred is SAFOAM FPN3-40, manufactured and distributed by Reedy International Corp., Keyport, N.J.; and about 30% by weight of a solvent, such as a 50% / 50% mixture of ethanol and methanol;
2. Run the mixer at a moderate agitation of about 30 rpm, for about 25 to about 35 minutes, at about 120 to about 125° F., until the mixture there...
example 2
Preferred PBA Process for Manufacture of Foamed Celluloid
1. A non-foamed celluloid sheet is prepared according to steps 1 through 5, above, except that no CBA ingredient is added;
2. The dried sheet is placed in a convention autoclave, capable of temperatures of at least 400° F. and pressures of up to 15,000 psi;
[0017]3. The autoclave is pressurized to from about 2,000 psi to about 12,000 psi, preferably from about 6,000 to about 8,000 psi, by the injection of a PBA, such as nitrogen, carbon dioxide, or argon, preferably nitrogen or carbon dioxide, and most preferably carbon dioxide, and set at a temperature between about 250° F. and about 350° F., preferably between about 250° F. and about 300° F., for a period of from about 10 minutes to about 24 hours;
4. The desired foamed celluloid sheet is removed from the autoclave.
[0018]The burn rate of the foamed celluloid can be enhanced by mixing an energetic additive to the initial nitrocellulose mixture of step 1 of Example 1; a preferred...
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