The application discloses a gradient
sintering process for improving the
elimination rate of closed
porosity of
ceramic, and belongs to the technical field of
alumina ceramic manufacturing. The process adds
lanthanum aluminum
oxide core-shell
powder as a
sintering additive and switches from an
air atmosphere to an
oxygen atmosphere during
sintering and glue removal, realizes gradient sintering, can greatly eliminate closed
porosity, improves the density and
mechanical strength of
ceramic materials, and makes the
ceramic materials less likely to crack. The sintering additive is
lanthanum aluminum
oxide core-shell
powder, the structure is a core-shell structure with
lanthanum oxide as a shell layer and gamma-
alumina as a core layer,
lanthanum oxide can reduce the concentration of lattice cation interstitials or produce a
grain boundary drag effect, thereby controlling the growth rate of the
crystal grains, ensuring the smooth removal of pores, and under
oxygen calcination, the concentration of cation interstitials in
alumina and
lanthanum oxide can be increased, the
grain boundary mobility can be controlled to a certain extent during the sintering densification process, and the formation of closed pores is further reduced.