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Method for preparing filtering absorbing material used for water treatment

A technology of water treatment and drying treatment, applied in water/sewage treatment, water/sludge/sewage treatment, filtration and separation, etc., can solve the problems of large amount of adsorbent, small specific surface area, frequent replacement, etc., and achieve simple preparation method , The effect of cheap and easy-to-obtain raw materials

Inactive Publication Date: 2008-02-20
张大伟
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, most urban sewage and industrial wastewater (especially industrial wastewater with large discharge volume) are treated by biochemical, anaerobic, aerobic, activated sludge, chemical agents and other methods. The above methods occupy a large area and consume high power , a large amount of sludge is produced during the treatment process, and it cannot treat wastewater that is difficult to biochemically such as high-salt, high-acid, and high-COD content
At present, there are many kinds of solid adsorbents used in water treatment, such as activated carbon, charcoal, bentonite, diatomaceous earth, calcium carbonate, slag, coke powder, slag, etc. The above-mentioned adsorbents are either high in production cost, or have small specific surface area and low adsorption capacity. Low, especially for the treatment of urban sewage and industrial wastewater with large discharge and high concentration of pollutants, or the treatment cost is high or the amount of adsorbent is large or frequently replaced, so it is rarely used in the field of industrial wastewater and urban sewage treatment
Is it possible to produce a low-cost, widely used water treatment, especially urban sewage and industrial wastewater with large discharge volume and high pollutant concentration, so as to reduce the floor area and power consumption of urban sewage and industrial wastewater treatment facilities, and waste water treatment The cost is lower than the cost of biochemical treatment and can deal with high-salt, high-acid, high COD content and other difficult-to-biochemical filtration and adsorption materials, which have not been reported so far.

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0008] In the preparation method of the present invention, when selecting the raw material of the filter adsorbent, a suitable raw material should be selected according to the use requirements and parameters of the filter adsorbent, and then among a variety of suitable raw materials, a kind of filter adsorbent with the lowest cost should be selected and used raw materials. When calculating the production cost of the filter adsorbent, in addition to the price and freight of the raw material, the composition, activity of the raw material and the yield of the prepared filter adsorbent should also be compared. Generally, coal with a low degree of metamorphism has high volatile content, low ash content, and high activity. At a lower activation temperature, a filter adsorbent with a higher specific surface area can be obtained, but the yield of the filter adsorbate is low; Coal has low volatile content, high ash content, and poor reactivity. Under the same activation temperature or ...

Embodiment 1

[0022] Preparation of filter adsorbent

[0023] The raw material for preparing the filter adsorbent is long-flame coal (Shenmu bituminous coal). Long-flame coal (Shenmu bituminous coal) has high volatile content, low ash content, and high reactivity. Therefore, a filter adsorbent with a high specific surface area can be obtained at a low activation temperature, but the yield of filter adsorbate is low.

[0024] The long-flame coal (Shenmu bituminous coal) is crushed by crushing equipment, and then screened by screening equipment to make raw materials with a particle size of <10mm. The processed raw materials are transported to drying and carbonization equipment for drying and carbonization. The initial drying temperature is 120°C, and the temperature is raised at a rate of 4°C / min, and the drying temperature is 150-400°C. After the raw material is dried, continue to heat up to 580°C at a rate of 6-8°C / min, and then keep the temperature for 50 minutes to dry-distill and carbo...

Embodiment 2

[0038] (Jincheng) anthracite is used as the raw material for preparing the filter adsorbent. (Jincheng) anthracite has low volatile content, high ash content, and low reactivity. Therefore, compared with long-flame coal (Shenmu bituminous coal), the activation reaction temperature is higher, and the specific surface area of ​​the filtered adsorbent is lower, but the yield of the filtered adsorbent is higher. Its operation steps are with embodiment 1.

[0039] The main parameters of the filter adsorbent prepared by embodiment 2:

[0040] Methylene blue: 32mg / g

[0041] Ash: 15%

[0042] Filling density 200g / l

[0043] Iodine value: 260mg / g

[0044] Specific surface area: 210m 2 / g

[0045] Activation reaction temperature: 950°C

[0046] Activation time: 60min

[0047] Filter adsorption material yield: 500kg / t. Coal

[0048] Chemical oxygen demand (CODcr) adsorption capacity: <1,600mg / g

[0049] Table 3 is the experimental record of using the filter adsorbent prepared in...

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Abstract

The invention relates to a preparing method for a filtering and absorbing material to process the water. The method is to place the raw material with grain diameter smaller than ten millimeter between 120 DEG C and 150 DEG C for four minutes and dry the raw material between 150 DEG C and 400 DEG C; then the temperature is raised by 6 to 8 DEG C per minute until reaching 510 to 650 DEG C, and keep the temperature for forty to seventy minutes to carbonize the material; and then the temperature is raised by 6 to 8 DEG C per minute until reaching 800 DEG C, firstly activate with the water vapor and the activate with the smoke for ten to twenty minutes between 840 DEG C and 950 DEG C. The raw material of the invention can adopts the anthracite, the meager coal, the dry coal, the coking coal, the fat coal, the bottle coal, the flaming coal and the lignite and other coal processing products such as coke, the goal coal and the coke powder. The raw material of the filtering and absorbing material of the invention is cheap and easy to get; the preparing method is also very simple; and the invention is applicable to large batch production.

Description

technical field [0001] The invention belongs to a material processing method, and in particular relates to a preparation method for processing coal into filter and adsorption materials for treating industrial waste water and urban sewage. Background technique [0002] At present, most urban sewage and industrial wastewater (especially industrial wastewater with large discharge volume) are treated by biochemical, anaerobic, aerobic, activated sludge, chemical agents and other methods. The above methods occupy a large area and consume high power , A large amount of sludge is produced during the treatment process, and it cannot treat wastewater that is difficult to biochemically such as high salt, high acid, and high COD content. At present, there are many kinds of solid adsorbents used in water treatment, such as activated carbon, charcoal, bentonite, diatomaceous earth, calcium carbonate, slag, coke powder, slag, etc. The above-mentioned adsorbents are either high in producti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30B01D39/06
CPCC02F1/283B01J20/20B01J20/3021B01J20/3078
Inventor 张大伟
Owner 张大伟
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