Reaction for preparing hydroxyacetone by selectively dewatering natural glycerol and catalyst
A natural glycerin and catalyst technology, applied in the direction of molecular sieve catalysts, physical/chemical process catalysts, carbon-based compound preparation, etc., can solve the problems of easy muddy active components, easy loss, etc.
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[0011] Examples 1 to 5:
[0012]Weigh 15 g of H-ZSM-5 raw powder with a silicon-to-aluminum ratio of 25, 50, 75, 100, and 360, calcined at 550°C for 3 hours, and cooled to room temperature to prepare H-ZSM-5(X) catalyst. After tableting and granulation, it is used for glycerol dehydration to produce acrolein.
[0013] The selective dehydration reaction of glycerol with 20% glycerol aqueous solution as raw material, LHSV is 0.15h -1 , The dehydration reaction temperature is 300°C. The results of the reaction are shown in Table 1.
[0014] Table 1 Reaction results of Examples 1 to 5
[0015]
[0016] a : Including by-products such as formaldehyde, acetaldehyde, acetic acid, benzene and phenol.
Example
[0017] Examples 6-10:
[0018] Weigh 10g of H-ZSM-5 raw powder with a silicon-to-aluminum ratio of 75, and use 0.2mol / L metal salt solution to boil and reflux under acidic conditions for 3 times, each time is 4h, each time the amount of solution added is 80mL, exchange After washing with deionized water, drying at 110°C, and roasting in a muffle furnace at 600°C for 3 hours, M-ZSM-5(75) can be prepared. The content of the active metal component in the prepared catalyst was 1.0 wt%. After tableting and granulation, it is used for glycerol dehydration to produce acrolein. The reaction process and conditions are the same as in Example 1. The reaction results are shown in Table 2
[0019] Table 2 Reaction results of Examples 6-10
[0020]
[0021] a : Including by-products such as formaldehyde, acetaldehyde, acetic acid, benzene and phenol.
Example
[0022] Examples 11-15:
[0023] Accurately weigh 28.8g 33.3% silica sol, 12g NaOH particles, 6.6g Al 2 (SO 4 ) 3 18H 2 O powder and 192g H 2 O, transfer the silica sol into a three-necked flask, add NaOH solution, heat to clear and add Al 2 (SO 4 ) 3 The solution is stirred at constant boiling for 2 hours, cooled to room temperature, and adjusted to pH 6.5 to obtain amorphous silica-alumina gel; weigh 10g of H-ZSM-5 raw powder with a silica-to-aluminum ratio of 75, and add 8g of amorphous silica-alumina gel After mixing, use 0.2mol / L metal salt solution for reflux exchange under boiling conditions for 4h, add 100mL of solution, wash with deionized water after exchange, dry at 110℃, and put it in 600℃ muffle furnace The M-ZSM-5(75) / SA catalyst can be prepared after calcination for 3h. The content of amorphous silicon and aluminum in the prepared catalyst is 16% by weight, and the content of metal is 1.5% by weight.
[0024] The reaction process and reaction conditions are the same ...
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