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Method for treating silicate slag from wastewater treatment

A wastewater treatment and disposal method technology, applied in the direction of solid waste removal, etc., can solve the problems of high safety landfill cost, high landfill cost, and ecological risks, so as to eliminate instability, reduce content, and facilitate subsequent utilization Effect

Active Publication Date: 2009-07-15
BAOSHAN IRON & STEEL CO LTD
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  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0003] Organic matter (TOC, COD), NH in wastewater 3 -N is mainly removed by adsorption; P is removed by adsorption or calcium phosphate; metals and heavy metal elements in wastewater can be removed by adsorption, or by soluble silicic acid or silicic acid chemical produced by silicate industrial waste under the action of wastewater Fixed removal; therefore, organic matter, heavy metals, metals, P, NH are adsorbed or chemically fixed in this type of sludge 3 Pollutants such as -N need to be properly treated and disposed of; in order to prevent the sludge generated from wastewater treatment from becoming a new source of pollution, it is necessary to find a safe disposal or utilization method for it. The general disposal or utilization methods are: a. landfill, but its landfill cost is high, and the cost of safe landfill is higher; b, as a building material, such as as a brick-making raw material, but it has an ecological risk; as in the Chinese patent CN1175927, the modified fly ash is used as The slag produced by adsorbent treatment of waste water is used as a raw material for making bricks. Chinese patent CN1760138A uses fly ash as an adsorbent to treat mine wastewater and concentrates the fly ash slag produced after the mine wastewater is used as a building material; but the disposal of the above-mentioned patent slag The use of technology has its limitations, and it can only target the sludge generated by wastewater treatment of a specific nature, and there are ecological risks in the final disposal and utilization as building materials

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  • Method for treating silicate slag from wastewater treatment

Examples

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Embodiment 1

[0029] Such as figure 1 As shown, a certain active purple printing and dyeing industrial wastewater, raw water COD1650mg / l, chroma 480, pretreatment with molten iron desiliconization slag (120 mesh) as adsorbent, dosage 100kg per ton of water, adsorption reaction time 30min, precipitation 30min , effluent COD476mg / l, chromaticity 120; the desiliconization slag sludge in the sedimentation tank is concentrated, dehydrated, air-dried and crushed (particle size is less than 3cm), and then transported to the converter steelmaking slagging process, and the desiliconization slag sludge is added to the molten converter Steel slag is processed in the slag ladle at the end of tapping. As a conditioner for steel slag, it is added to the high-temperature molten converter steel slag after tapping at a ratio of 10%. After a period of fusion reaction, the water in the drum slag treatment process After quenching and granulation treatment, it becomes granular steel slag material, and the free ...

Embodiment 2

[0034] Such as figure 1As shown, a certain chromium-containing wastewater, the main pollutant Cr(III) in raw water is 245mg / L, is treated with ironworks blast furnace slag as an adsorbent, the dosage is 8.5kg per ton of water, the adsorption reaction time is 30min, the precipitation is 30min, and the effluent Cr(III) is 0.46mg / L, and the treated wastewater meets the requirements of relevant discharge standards; the blast furnace slag sludge in the sedimentation tank is concentrated, dehydrated, air-dried and crushed (particle size is less than 3cm), and then transported to the converter steelmaking slag removal process, high The slag slag is added to the molten converter steel slag in the slag ladle at the end of tapping. As a conditioner for steel slag, it is added to the high-temperature molten converter steel slag after tapping at a ratio of 1%. After a period of fusion reaction , through the water quenching and granulation treatment of the drum slag treatment process, it b...

Embodiment 3

[0038] Such as figure 1 As shown, in the first step, a sintering desulfurization wastewater is neutralized with milk of lime to pH 9.0 to remove heavy metals such as Zn, Cu, Cr, Ni, etc., and in the second step, the fly ash discharged from the power plant is used to treat the organic matter, ammonia nitrogen, and Pb in the wastewater. , Cd and adsorption treatment, raw water TOC21.6mg / L, NH 3 -N64mg / L, Pb18mg / L, Cd3.47mg / L, add fly ash at a rate of 15g per liter of wastewater, adsorption reaction for 30min, effluent TOC5.8mg / L, NH 3 -N17mg / L Pb0.35mg / L, Cd0.12mg / L, the fly ash sludge in the sedimentation tank is concentrated, dehydrated, air-dried and crushed (particle size is less than 3cm), and then transported to the converter steelmaking slag process, the fly ash slag The mud is added to the molten converter steel slag and carried out in the slag ladle at the end of tapping. As a conditioner for steel slag, it is added to the high-temperature molten converter steel slag a...

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Abstract

The invention discloses a method for processing silicate slag generated after waste water processing, which is mainly characterized in that after the silicate slag generated after the waste slag of fly ash, blast furnace slag and the like in the silicate industry is used as an absorbing agent for processing printing, drug manufacturing, coking, paper making, heavy metal, nitrogen-phosphorous, oil-containing, desulfuring, living and the like waste water is dried and pulverized, the silicate slag is used as a modifying agent according to the proportion of 1 percent to 10 percent to be added into high-temperature melting steel slag. The high-temperature melting steel slag after steel production is used for harmlessly processing the silicate slag generated after waster water treatment, and the similar silicate slag is used as the modifying agent of the steel slag. Silicon or aluminum acidic compound existing in the silicate slag is used for regulating the alkali degree of the steel slag, the content of free calcium oxide in the steel slag is reduced, and the instability of the volume of the steel slag is eliminated.

Description

technical field [0001] The invention belongs to the technical field of solid waste treatment, in particular to a treatment method for silicate slag generated after wastewater treatment. Background technique [0002] Silicate industrial waste residues such as fly ash and blast furnace slag have a wide range of sources and are cheap. Because these silicate waste residues are rich in various active components such as silicon oxide, aluminum, and iron, and have a porous structure, they can be chemically It can adsorb various pollutants through physical and chemical methods, and has the ability of neutralization and coagulation; it can effectively remove organic matter (TOC, COD), chroma, heavy metals, phosphorus and other chemical substances in certain industrial wastewater; thus, In recent years, fly ash, blast furnace slag and other silicate slags have been widely used in printing and dyeing, oily, pharmaceutical, papermaking, coking, heavy metal, nitrogen and phosphorus waste...

Claims

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Application Information

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IPC IPC(8): C04B5/06B09B3/00
Inventor 王如意陈荣欢石洪志顾德仁石磊
Owner BAOSHAN IRON & STEEL CO LTD