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Method for separating high flux and low pollution membrane with biomimetic spiral membrane

A membrane separation and spiral membrane technology, applied in the field of membrane separation, can solve the problems of rigid membrane module structure, increase material consumption, difficult to master, etc., so as to improve mass transfer and separation efficiency, increase energy consumption and material consumption, and reduce concentration difference. The effect of polarization

Inactive Publication Date: 2010-04-28
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Not conducive to the use of flow field disturbance
[0005] (2) Add suspended fillers, such as organic materials, activated carbon or organic-inorganic composite fillers, to form dynamic membranes and control membrane fouling to slow down and inhibit the decline in membrane flux, which is usually used in flat membranes. (P Bai, X Chen, J Wang, Development of high flux, low air scoured and less backwashed Dynamic filter to realize low cost membrane bioreactor-a pilot scaledemonstration in sewage treatment., 5th IWA specialized membrane technology conference for water and wastewater treatment. IWA Membrane Beture conference2 and exhibition , ID074) This approach increases material consumption
[0006] (3) Study new anti-pollution membrane materials, such as antibacterial / improving hydrophilicity, reducing the adsorption and deposition of pollutants; anchoring / designing materials with comb-like molecular structures on the surface; increasing surface negative charges; this method focuses on chemical reactions and material modification (Fangang Meng, So-Ryong Chae, Anja Drews, Matthias Kraume, Hang-Sik Shin, Fenglin Yang, Recent advances in membrane bioreactors (MBRs): Membrane fouling and membrane material, Water Research, Volume 43, Issue 6 , April 2009, 1489-1512) This method also increases the cost and consumption of chemical processing materials
[0007] (4) Optimizing membrane separation operating conditions, adjusting the size of sludge particles, such as adding cationic polymers or ions to water, changing the properties of sludge, biological macromolecules, especially EPS (granulation), and reducing adsorption and Sedimentation (B, Siembida, P Cornel, S Krause, B Zimmerman, Studies on fouling and its prevention in MBR.5th IWA specialized membrane technology conference for water and wastewater treatment. IWA Membrane conference and exhibition, 2009Beijing. Abstract Book, ID584.) The operation and adjustment of the method is complicated, cannot be changed according to the specific situation, time-consuming and difficult to master
Using the elasticity and structural resilience of the material itself, the response to the disturbance of airflow and water flow in water produces horizontal and vertical vibrations, which solves the problem of membrane module structure stiffness, increases the filling area, reduces pollution, increases flux, and saves energy. At present, there is no other research report on this kind of membrane separator

Method used

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  • Method for separating high flux and low pollution membrane with biomimetic spiral membrane
  • Method for separating high flux and low pollution membrane with biomimetic spiral membrane
  • Method for separating high flux and low pollution membrane with biomimetic spiral membrane

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A flat plastic pad is cut into a fishbone-like or comb-like support structure on both sides, with a large degree of free torsion, and the surface is covered with a microfiltration or ultrafiltration membrane separation material, sealed, and flows out of the water pipe. Flat membranes with different length and width ratios of 5:1 are spirally twisted so that the relative angle between the upper edge and the lower edge of the membrane module is 90 degrees, and fixed in the membrane separation device through the outside. The membrane module can also use thermal deformation to rotate the supporting plastic into a bionic helical structure, keep the shape when heated, and fix the shape after cooling. The outlet pipe of the membrane module can be connected to a vacuum pressure gauge and a suction pump. An aeration device that can control the gas flow is installed at the bottom of the membrane separation device, and a simulated particle suspension prepared with kaolin is added. ...

Embodiment 2

[0026] In the biomimetic spiral membrane module prepared by the same method as in Example 1, the angle between the upper edge and the lower edge is 180 degrees. Under the same device and conditions, its flux is also higher than ordinary flat membrane, 15% higher in a period of time. And the flux drops off more slowly.

Embodiment 3

[0028] A row of quasi-flat membranes consisting of 10 bundles of 10 PP hollow fiber membranes fixed at the upper and lower ends are twisted and braided with soft fibers or hollow fibers outside the membrane filament bundles that are approximately parallel to each other. , showing a looser bondage. In the same way as in Example 1, the row of membrane filaments is rotated and twisted, and arranged in a bionic helical shape in space, when the upper and lower ends are at an angle of 90 degrees. The flux decay curve of this membrane has the same characteristics as that of Example 1.

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Abstract

The invention relates to a method for separating a high flux and low pollution membrane with a biomimetic spiral membrane, belonging to the technical field of membrane separation. The method aims to establish the efficient membrane separation components by using a biomimetic principle, lighten concentration difference polarization and membrane pollution, improve the membrane flux and reduce energy consumption. The invention is characterized in that flat membranes and hollow fibre parallel arrangement membrane components keep the characteristics of the biomimetic spiral membrane structure in space through the outside fixing method, the inside support structure and shape maintaining method or the combination of the two methods, and the distribution, the interaction and the change mode of membrane and the flow field in membrane separation are changed. The vibration and swing of the membranes are caused by the washing and the disturbing of the flow. The invention has the effect and advantages that under the premises that the material consumption and the energy consumption are not increased in the membrane separating process, mass transfer is strengthened, membrane pollution is lightened, and dynamic membrane operating effect is favorable. The method has obvious social and economic benefits and has wide application prospect in the fields of chemical industry separation, water treatment, medicine separation and the like.

Description

technical field [0001] The invention belongs to the technical field of membrane separation. The invention relates to a high-throughput and low-contamination membrane separation method using a bionic spiral membrane. Specifically, it involves the use of a simple and easy bionic spiral membrane structure, which changes the traditional fluid flow field distribution and membrane surface interaction and disturbance mode, improves the sensitivity of the membrane module to fluid disturbances such as water and gas, and generates membrane vibration and swing. Reduce concentration polarization in membrane separation, reduce membrane fouling, and improve membrane separation efficiency and flux. Reduce membrane separation energy consumption. Background technique [0002] Membrane separation process is an efficient separation operation, which has been widely used in many industries in recent years. The bottleneck problem that restricts the further improvement of efficiency of membrane...

Claims

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Application Information

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IPC IPC(8): B01D65/08B01D63/02B01D63/08C02F1/44
Inventor 柳丽芬徐晓静赵传起杨凤林于心瑞
Owner DALIAN UNIV OF TECH
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