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Electro-deposition preparation method for Fe-Co soft magnetic film

A soft magnetic thin film and electrodeposition technology, applied in the application of magnetic film to substrate, magnetic layer, electrolytic inorganic material coating, etc., can solve the problems of harsh conditions, complicated operation, huge equipment cost, etc., and achieve mild and reliable reaction conditions control, high preparation efficiency and low cost

Inactive Publication Date: 2012-07-11
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these materials can meet the performance of soft magnetic, but there are defects in use, the cost is high, and it is not easy to make a film with a thickness of less than 20 microns. In addition, some equipment is huge, expensive, complicated to operate, and harsh conditions

Method used

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  • Electro-deposition preparation method for Fe-Co soft magnetic film
  • Electro-deposition preparation method for Fe-Co soft magnetic film
  • Electro-deposition preparation method for Fe-Co soft magnetic film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Electrodeposition preparation of iron-cobalt alloy soft magnetic thin film:

[0042] 1. Carry out mechanical pretreatment on the deposition matrix material: rough grinding with sandpaper to remove burrs, oxide layers, etc. on the surface of the sample, and reduce the surface roughness;

[0043] 2. Pre-treatment of the copper substrate sample:

[0044] Alkaline cleaning and pickling are carried out sequentially on the copper substrate samples. The components of the alkaline cleaning solution for degreasing and rust removal of the substrate are: sodium hydroxide 35g / L, sodium dihydrogen phosphate 8g / L; the temperature of the alkaline cleaning for degreasing and rust removal is controlled at 50°C, and the time is controlled at 8 minutes;

[0045] The sample is electropolished, and the formula of the solute in the electropolishing solution is: citric acid 20g / L, ammonium citrate 46g / L;

[0046] The process parameters of the electrolytic polishing are as follows: the elect...

Embodiment 2

[0060] Electrodeposition preparation of iron-cobalt alloy soft magnetic thin film:

[0061] 1. Carry out mechanical pretreatment on the deposition matrix material: rough grinding with sandpaper to remove burrs, oxide layers, etc. on the surface of the sample, and reduce the surface roughness;

[0062] 2. Pretreatment of the sample copper sheet:

[0063] Alkaline cleaning and acid cleaning are performed on the samples in turn. The components of the alkaline cleaning solution for degreasing and rust removal of the substrate are: sodium hydroxide 35g / L, sodium dihydrogen phosphate 8g / L; the temperature of the alkaline cleaning for degreasing and rust removal is controlled at 50°C, and the time is controlled at 8 minutes;

[0064] The sample is electropolished, and the formula of the solute in the electropolishing solution is: citric acid 20g / L, ammonium citrate 46g / L;

[0065] The process parameters of the electrolytic polishing are as follows: the electrolytic polishing anode ...

Embodiment 3

[0078] Electrodeposition preparation of iron-cobalt alloy soft magnetic thin film:

[0079] 1. Carry out mechanical pretreatment on the deposition matrix material: rough grinding with sandpaper to remove burrs, oxide layers, etc. on the surface of the sample, and reduce the surface roughness;

[0080] 2. Pretreatment of the sample copper sheet:

[0081] The samples were sequentially washed with alkali and acid. The components of the alkaline cleaning solution for degreasing and rust removal of the substrate are: sodium hydroxide 35g / L, sodium dihydrogen phosphate 8g / L; the temperature of the alkaline cleaning for degreasing and rust removal is controlled at 50°C, and the time is controlled at 8 minutes;

[0082] The sample is electropolished, and the formula of the solute in the electropolishing solution is: citric acid 20g / L, ammonium citrate 46g / L;

[0083] The process parameters of the electrolytic polishing are as follows: the electrolytic polishing anode is a copper she...

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Abstract

The invention relates to an electro-deposition preparation method for a Fe-Co soft magnetic film, which belongs to the field of the magnetically soft alloy. The electro-deposition preparation method for a Fe-Co soft magnetic film comprises the following steps: taking a graphite plate as an anode and a copper sheet as a cathode; taking Fe sulfate and CO sulfate as main salts; after a substrate is pretreated, putting the substrate into electroplate liquid, of which the pH is regulated to 1-5 and of which the temperature is controlled to room temperature-60 DEG C; and under the condition of constant-temperature electromagnetic stirring, current is provided by a direct-current stabilized power supply for electroplating, wherein the thickness of an electroplating layer is controlled by electroplating application temperature and time. The preparation technology for the Fe-Co soft magnetic film is simple and has the advantages of being low in cost, moderate and controllable in reaction conditions, high in preparation efficiency.

Description

technical field [0001] The invention relates to a preparation method of a soft magnetic thin film, in particular to an electrodeposition preparation method of an iron-cobalt soft magnetic thin film, belonging to the field of soft magnetic alloys. Background technique [0002] With the continuous development of miniaturization and high frequency of electronic equipment, high frequency soft magnetic materials used in electromagnetic devices have become a very active research field. The magnetic thin film is the most active field in the development of new high-tech new materials. Magnetic functional materials with a thickness ranging from several nanometers to tens of microns are called magnetic thin film materials. Figure of Merit for Magnetic Thin Films. [0003] Traditional soft magnetic materials include silicon steel sheet, permalloy, electrical soft iron, and emerging amorphous and nanocrystalline alloy strips in recent years, but these materials have some disadvantages...

Claims

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Application Information

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IPC IPC(8): H01F10/16H01F41/14C25D9/04
Inventor 陆伟何晨冲王岗严彪
Owner TONGJI UNIV