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Printing adhesive of stone paper wallpaper and preparation method of printing adhesive

A technology of adhesive and stone paper, which is applied in the fields of dyeing, textiles and papermaking, can solve the problems that affect the printing effect, the printing adhesive is difficult to meet the application requirements, and the adhesive production technology has not been disclosed. Effects of improving stain resistance, improving wet and dry rub resistance, improving hardness and surface slipperiness

Active Publication Date: 2013-07-24
LIAONING FIXED STAR FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And because the stone paper contains a certain proportion of high molecular polymer, the surface is relatively smooth, which will affect the printing effect
[0004] Stone paper wallpaper is used for interior decoration. It has high requirements for the environmental performance of printing adhesives, bonding fastness, color fastness, stain resistance and dry and wet rubbing resistance, and printing often requires unevenness. sense, ordinary printing adhesives are difficult to meet its application requirements
[0005] There is no disclosure of adhesive production technology for stone paper wallpaper printing

Method used

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  • Printing adhesive of stone paper wallpaper and preparation method of printing adhesive

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Raw material ratio: fatty alcohol polyoxyethylene ether (Pingping plus O-25) 2 . 3 grams, sodium lauryl sulfate 2 . 8 grams, methyl acrylate 26 grams, ethyl acrylate 67 grams, glycidyl methacrylate 4 . 5 grams, vinyl acetate 12 grams, methyl methacrylate 14 grams, acrylic acid 3 . 3 g, ethylene urea ethoxy methacrylate 4 . 2 g, ammonium persulfate 1 . 2 g, sodium bisulfite 0 . 6 grams, 178 grams of deionized water;

[0036] Process method:

[0037] 1) Mix all the monomers, namely 26 grams of methyl acrylate, 67 grams of ethyl acrylate, and 4 grams of glycidyl methacrylate . 5 grams, vinyl acetate 12 grams, methyl methacrylate 14 grams, acrylic acid 3 . 3 g, ethylene urea ethoxy methacrylate 4 . Add 2 grams into the mixing tank and stir well;

[0038] 2) Add 52 grams of deionized water, fatty alcohol polyoxyethylene ether (Pingping plus O-25) 0 . 7 grams, sodium lauryl sulfate 0 . 7 grams, fully stirred to dissolve;

[0039] 3) Ammonium persulfate 1 . 2 ...

Embodiment 2

[0047] Raw material ratio: fatty alcohol polyoxyethylene ether (Pingping plus O-25) 2 . 5 grams, sodium lauryl sulfate 2 . 6 grams, methyl acrylate 28 grams, ethyl acrylate 65 grams, glycidyl methacrylate 4 . 3 grams, vinyl acetate 14 grams, methyl methacrylate 12 grams, acrylic acid 3 . 9 g, ethylene urea ethoxy methacrylate 4 . 5 g, ammonium persulfate 1 . 3 g, sodium bisulfite 0 . 65 grams, 182 grams of deionized water.

[0048] Process method:

[0049] 1) Mix all the monomers, namely 28 grams of methyl acrylate, 65 grams of ethyl acrylate, and 4 grams of glycidyl methacrylate. 3 grams, vinyl acetate 14 grams, methyl methacrylate 12 grams, acrylic acid 3 . 9 g, ethylene urea ethoxy methacrylate 4 . Add 5 grams into the mixing tank and stir well;

[0050] 2) Add 55 grams of deionized water, fatty alcohol polyoxyethylene ether (Pingping plus O-25) into the reaction kettle . 8 grams, sodium lauryl sulfate 0 . 6 grams are fully stirred and dissolved;

[0051] 3) ...

Embodiment 3

[0059] Raw material ratio: fatty alcohol polyoxyethylene ether (Pingping plus O-25) 2 . 9 grams, sodium lauryl sulfate 2 . 2 grams, methyl acrylate 27 grams, ethyl acrylate 66 grams, glycidyl methacrylate 4 . 7 grams, vinyl acetate 13 grams, methyl methacrylate 13 grams, acrylic acid 4 . 8 g, ethylene urea ethoxy methacrylate 4 . 6 g, ammonium persulfate 1 . 4 g, sodium bisulfite 0 . 7 grams, 185 grams of deionized water.

[0060] Process method:

[0061] 1) Mix all the monomers, namely 27 grams of methyl acrylate, 66 grams of ethyl acrylate, and 4 grams of glycidyl methacrylate . 7 grams, vinyl acetate 13 grams, methyl methacrylate 13 grams, acrylic acid 4 . 8 g, ethylene urea ethoxy methacrylate 4 . Add 6 grams into the mixing tank and stir well;

[0062] 2) Add 58 grams of deionized water, fatty alcohol polyoxyethylene ether (Pingping plus O-25) 0 . 7 grams, sodium lauryl sulfate 0 . 8 grams are fully stirred and dissolved;

[0063] 3) Ammonium persulfate 1 ...

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Abstract

The invention relates to a printing adhesive of stone paper wallpaper and a preparation method of the printing adhesive. The printing adhesive is a polymer emulsion which is prepared by carrying out emulsion polymerization on fatty alcohol-polyoxyethylene ether (PeregalO-25), lauryl sodium sulfate, methyl acrylate, ethyl acrylate, epoxypropyl methacrylate, vinyl acetate, methyl methacrylate, acrylic acid, 1-(2-Methacryloyloxyethyl)-2-imidazolidinone, ammonium persulfate, sodium hydrogen sulfite and deionized water. The printing adhesive has the advantages of good environmental friendliness property, high adhesion fastness, good color fastness, contamination resistance as well as dry wiping and wet wiping resistance.

Description

Technical field [0001] The present invention involves a stone paper wallpaper printing adhesive and its preparation method. It is a lotion of an acrylic polymer, which is suitable for stamps of stone paper wallpapers. Background technique [0002] Stone paper is the abbreviation of environmentally friendly stone paper of inorganic powder. It is to extract calcium carbonate in limestone to make ultra -fine powder, and then add some polymer polymers and other additives to make mother grains.The characteristics of the modification are treated with a polymer to squeeze out and blow the forming process.The production of this kind of paper does not require wood, the production process does not require water, and no harmful substances such as acid and strong alkali are added. The problem of pollution in the traditional papermaking process is fundamentally eliminated. The cost is 20-30%lower than that of traditional paper.A low cost, wide -use, environmentally friendly product, and using...

Claims

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Application Information

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IPC IPC(8): D06P1/52C08F220/14C08F220/18C08F218/08C08F220/32C08F220/06C08F220/36C08F2/26C08F2/30
Inventor 孙继昌高凯王冠中李秀颖仇凯
Owner LIAONING FIXED STAR FINE CHEM
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