Preparation method of sphere-like fast ion conducting material of modified calcium lithium titanate
An ion conductor, calcium lithium titanate technology, applied in the field of preparation of spherical fast ion conductor material modified calcium lithium titanate, can solve the problems of inhibiting development, ion conductivity can not meet the practical requirements, etc., to achieve conductivity Effect of improvement, excellent rate and cycle performance, and excellent electrochemical performance
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Embodiment 1
[0026] Using the nitrate solution of lithium nitrate, calcium nitrate, n-butyl titanate and cerium oxide as raw materials, according to Li 0.1-z Ce 0.1 Ca 0.8 Ti z o 3 The stoichiometric ratio is mixed in the aqueous solution of ethanol; finally, the complexing agent acetylacetone is added according to 3 times of the theoretical amount, stirred and hydrolyzed for 6 hours at 40°C to obtain a uniform solution, sol or suspension, and then spray-dried. The wind temperature is 120°C, the outlet air temperature is 98°C, and finally in the air atmosphere at 600°C, 700°C, 800°C, and 900°C for 6 hours to obtain the modified calcium lithium titanate-like spherical fast ion conductor material Li 0.1-z Ce 0.1 Ca 0.8 Ti z o 3 , the resulting product was prepared into an all-solid electrolyte and then assembled into a button battery to investigate its battery performance in the voltage range of 2.75-4.25V. Charge and discharge at different rates, the first discharge specific capacit...
Embodiment 2
[0030] Using the nitrate solution of lithium acetate, calcium acetate, n-butyl titanate and cerium oxide as raw materials, according to Li 0.1-z Ce 0.1 Ca 0.8 Ti z o 3 The stoichiometric ratio is mixed in the aqueous solution of ethanol, and then the complexing agent acetylacetone is added according to 3 times the theoretical amount, stirred and hydrolyzed for 6 hours at 40°C to obtain a uniform solution, sol or suspension, and then spray-dried. The wind temperature is 120°C, the outlet air temperature is 98°C, and finally the temperature is kept at 700°C in the air atmosphere for 2 hours, 6 hours, 8 hours and 10 hours respectively, and the modified calcium lithium titanate-like spherical fast ion conductor material Li 0.1-z Ce 0.1 Ca 0.8 Ti z o 3 , the resulting product was prepared into an all-solid electrolyte and then assembled into a button battery to investigate its battery performance in the voltage range of 2.75-4.25V. Charge and discharge at different rates, t...
Embodiment 3
[0035] Using the nitrate solution of lithium oxalate, calcium oxalate, n-butyl titanate and cerium oxide as raw materials, according to Li 0.1-z Y x Ca 0.9-x Ti z o 3 (wherein x=0.05, 0.10, 0.40 and 0.80) the stoichiometric ratio is mixed in the aqueous solution of ethanol, then add the complexing agent acetylacetone by 3 times of the theoretical amount, stir and hydrolyze for 6 hours at 40°C to obtain a uniform solution, The sol or suspension is then spray-dried, the air inlet temperature is 120°C, the air outlet temperature is 98°C, and finally the temperature is kept at 700°C for 6 hours in the air atmosphere to obtain the modified calcium lithium titanate spherical fast ion conductor material Li 0.1-z Y x Ca 0.9-x Ti z o 3 , the resulting product was prepared into an all-solid electrolyte and then assembled into a button battery to investigate its battery performance in the voltage range of 2.75-4.25V. Charge and discharge at different rates, the first discharge sp...
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