A preparation method of highly ordered mesoporous carbon-coated magnetic nanoparticles

A magnetic nanoparticle, highly ordered technology, applied in the fields of nanotechnology, nanotechnology, nanotechnology, etc. for materials and surface science, can solve the problems of pore occupancy, magnetic nanoparticle exposure, etc., and achieve efficient separation and preparation steps Simple, exposure-avoiding effects

Active Publication Date: 2016-11-30
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to provide a method for preparing highly ordered mesoporous carbon-coated magnetic nanoparticles to solve the problem that the pores of the existing magnetic mesoporous carbon materials are occupied by magnetic nanoparticles and the magnetic nanoparticles are exposed to the pores.

Method used

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  • A preparation method of highly ordered mesoporous carbon-coated magnetic nanoparticles
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  • A preparation method of highly ordered mesoporous carbon-coated magnetic nanoparticles

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Embodiment 1

[0034] (1) Preparation of iron ferric oxide nanoparticles with polyacrylic acid on the surface: dissolve ferric chloride, sodium acetate, and sodium acrylate with a molar ratio of 1:10:10 in a mixed solvent of ethylene glycol and diethylene glycol , transferred to a hydrothermal reaction kettle after stirring, and hydrothermally reacted for 12 hours to obtain ferroferric oxide magnetic nanoparticles;

[0035] (2) Disperse ferroferric oxide magnetic nanoparticles in deionized water, add cetyltrimethylammonium bromide (CTAB), the mass ratio of ferroferric oxide magnetic nanoparticles to CTAB is 3:7, stir After a certain period of time, add polyether F127 (PEO 106 PPOs 70 PEOs 106 ), the mass ratio of F127 and ferroferrogen tetroxide magnetic nanoparticles is 5, and the ferroferrogen tetroxide magnetic nanoparticle solution whose surface is coated with CTAB surface active organic template agent is obtained by stirring;

[0036] (3) Preparation of carbon source prepolymer: phen...

Embodiment 2

[0040] (1) Preparation of iron ferric oxide nanoparticles with oleic acid on the surface: iron triacetylacetonate, ethylene glycol, oleic acid, and oleylamine are mixed in a certain proportion, and after dissolving, transfer to a hydrothermal reaction kettle and heat up to 200 ℃, hydrothermal reaction for 3 hours, and ferroferric oxide magnetic nanoparticles were prepared;

[0041] (2) Get the above-mentioned iron ferric oxide nanoparticles and disperse them in chloroform, add F127 aqueous solution, stir for a certain period of time, heat up and volatilize to remove chloroform, and obtain the iron ferric oxide nano particle solution of surface-coated surfactant;

[0042] (3) Preparation of carbon source precursor: phenol and formaldehyde are used as raw materials, and NaOH is used as a catalyst. The molar ratio of phenol and formaldehyde is 1:3. React at 70°C for 30 minutes to obtain a carbon source precursor solution.

[0043] (4) Mix the iron ferric oxide nanoparticle solut...

Embodiment 3

[0046] (1) Preparation of iron ferric oxide nanoparticles modified with octylamine on the surface: iron triacetylacetonate was added to a mixed solvent of octylamine and alcohol, transferred to a hydrothermal reaction kettle, heated to 240°C, and hydrothermally reacted for 2 hours to prepare Obtain ferroferric oxide magnetic nanoparticles;

[0047] (2) Get the above-mentioned iron ferric oxide nanoparticles and disperse them in chloroform, add F127 aqueous solution, stir for a certain period of time, heat up and volatilize to remove chloroform, and obtain the iron ferric oxide nano particle solution of surface-coated surfactant;

[0048] (3) Preparation of carbon source precursor: Resorcinol and formaldehyde are used as raw materials, and ammonia water is used as a catalyst. The molar ratio of resorcinol and formaldehyde is 1:2. React at 35°C for 30 minutes to obtain a carbon source precursor solution.

[0049] (4) Mix the iron ferric oxide nanoparticle solution and the carbo...

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Abstract

A method for preparing highly ordered mesoporous carbon-coated magnetic nanoparticles. The method uses magnetic nanoparticles as the core, and uses electrostatic or hydrophobic interactions to fully coat the organic template agent on the outer layer of the magnetic core. Through the formation of mesoporous The organic polymer precursor of the porous carbon and the self-assembly coating of the organic template on the surface of the magnetic core are carbonized at a high temperature to form a highly ordered mesoporous carbon-coated magnetic nanomaterial; the highly ordered mesoporous carbon coating prepared by the present invention The coated magnetic nanoparticles can be applied to bioseparation, drug delivery, nuclear magnetic resonance imaging, catalysis and other fields.

Description

technical field [0001] The invention belongs to the field of mesoporous composite materials, and in particular relates to a preparation method of highly ordered mesoporous carbon-coated magnetic nanoparticles. Background technique [0002] Mesoporous carbon materials have attracted extensive attention due to their highly ordered and regular mesoporous channel structure, continuously adjustable pore size, high specific surface area and pore volume, excellent stability and biocompatibility. Magnetic nanoparticles have excellent magnetic orientation, which can quickly realize positioning, guidance and separation. Mesoporous carbon-coated magnetic materials have the characteristics of good mesoporous carbon material properties and easy external magnetic field control, and have superior applications in the fields of magnetically targeted drug delivery, magnetic hyperthermia, rapid biological separation, nuclear magnetic resonance imaging, and catalysis. prospect. [0003] At pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/01B82Y30/00
Inventor 吴仁安徐桂菊刘荣张宇
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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