Method for preparation of phenolic compound by direct hydrogenolysis of lignin
A technology of phenolic compounds and lignin, applied in the preparation of organic compounds, chemical instruments and methods, organic chemistry, etc., can solve the problems of harsh equipment requirements, low yield of phenols, high price, etc., and achieve mild equipment requirements, No need for high temperature and high pressure, easy to operate
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Embodiment 1
[0012] Weigh 1g of lignin and 0.05g of palladium chloride catalyst in an autoclave, add 10mL of methanol, ultrasonicate, and mix well. 200 ° C hydrogenolysis reaction 3h. After centrifugation and cyclohexane extraction to separate the supernatant, the product was analyzed by GC-MS, the conversion rate of lignin was 58%, and the selectivity of phenols was 89%. Phenols are mainly 4-propyl guaiacol, 4-propyl syringyl alcohol, 4-propyl phenol, propylene guaiacol, syringyl alcohol, propylene phenol phenolic compounds; other products are dimerization body compound.
[0013] Quantitative analysis of the internal standard: use durene as the internal standard, and its quality is constant. According to the ratio of the peak area of the phenolic component to the peak area of durene, the mass of the phenolic component in the product can be obtained, thereby obtaining the conversion rate of lignin. The selectivity of phenols is calculated by the following formula.
[0014] The form...
Embodiment 2
[0017] Weigh 1g of lignin and 0.1g of ammonium tungstate catalyst in an autoclave, add 10mL of methanol, ultrasonicate, and mix well. 200 ° C hydrogenolysis reaction 3h. Centrifuge, extract and separate the supernatant with cyclohexane, the product is analyzed by GC-MS, the conversion rate of lignin is 59%, and the selectivity of phenols is 92%. The lignin conversion rate and the selectivity of phenols are the same as in Example 1.
Embodiment 3
[0019] Weigh 1g of lignin and 0.1g of palladium chloride catalyst in an autoclave, add 10mL of ethylene glycol, ultrasonicate, and mix well. 200 ° C hydrogenolysis reaction 3h. Centrifuge, extract and separate the supernatant with cyclohexane, the product is analyzed by GC-MS, the conversion rate of lignin is 51%, and the selectivity of phenols is 87%. The lignin conversion rate and the selectivity of phenols are the same as in Example 1.
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