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Harmless treatment method of waste burning fly ash

A technology for waste incineration fly ash and harmless treatment, applied in the field of environmental pollution control, can solve the problems of high consumption, high operating cost, large energy consumption, etc., and achieve the effects of speeding up the reaction rate, increasing the contact area, and high energy utilization rate

Active Publication Date: 2015-01-21
TIANJIN CHENGJIAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the method of landfilling incineration fly ash after cement solidification is widely used in China. The main disadvantages of this method are: (1) It must use a high cement / fly ash ratio, consume a large amount of cement, increase volume and quality seriously, and cannot To achieve the reduction requirements of waste treatment; (2), cement solidification requires sufficient operating time; (3), cement solidification is mainly aimed at stabilizing heavy metals in fly ash, and cannot decompose or stabilize dioxins in fly ash, is another Achilles' heel
(4) Heavy metals such as Zn, Pb, and Cd with excessive leachability in fly ash mainly depend on maintaining a relatively stable chemical state in the alkaline environment provided by cement, and are physically stable in the solidified body. After the cement solidifies, the heavy metals will eventually Accumulated in the environment, its long-term stability cannot be guaranteed, and complete harmlessness cannot be achieved
(5) The stabilized products are useless and non-renewable resources, and the resource utilization of incineration fly ash cannot be realized
The traditional melting method needs to heat the fly ash from an external high temperature (≥1400°C) to the molten state, which consumes a lot of energy and high operating costs; in addition, for the electric melting furnace, the high chlorine and high carbon in the fly ash will bring Erosion of refractory materials and burning of graphite electrodes and other adverse effects; fuel-type melting furnaces need to rely on a large amount of auxiliary fuel and air to maintain high temperature, which will produce a large amount of flue gas containing volatile heavy metals, and complex exhaust gas purification facilities need to be equipped after the kiln

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] The chemical composition of municipal solid waste incineration is shown in Table 1, and the heat loss rate of fly ash, heavy metals, dioxins and chlorine content are shown in Table 2. Put the waste incineration fly ash and silicon carbide powder into a mixer at a mass ratio of 20:1 to fully mix, then add deionized water for granulation molding, put the molded particles into a graphite crucible, and add embedded carbon powder ( Particle size≤250μm), put the graphite crucible into an industrial microwave oven for powder fusion. The working frequency of the microwave sintering furnace is 2.45GHz, the power of the microwave oven is 5kW, the heating time is 5 minutes, and the slag is obtained by cooling in the crucible The slag and buried powder are separated by sieving. After separation, the microwave couplant is reserved as buried powder. The concentration of dioxins in the slag is reduced to 0.021ng TEQ / g after testing. The heavy metal leaching toxicity test results of the ...

Embodiment 2

[0024] The waste incineration fly ash is the same as in Example 1. Put the waste incineration fly ash and the carbon powder into a mixer at a mass ratio of 10:1 to fully mix, then add deionized water for granulation and shape, and put the shaped particles into a graphite crucible , And add embedded ferroferric oxide powder (particle size ≤300μm), put the graphite crucible into an industrial microwave oven for powder fusion, the working frequency of the microwave sintering furnace is 0.915GHz, the power of the microwave oven is 30kW, and the heating time is 8 Minutes, the slag is obtained in the crucible after cooling, and the slag is separated from the buried powder by sieving. After separation, the microwave couplant is reserved as buried powder for later use. The concentration of dioxins in the molten slag is reduced to 0.025ng TEQ / g after the separation. The heavy metal leaching toxicity test results of the slag are shown in Table 4. The hazardous concentration in the leachin...

Embodiment 3

[0028] The waste incineration fly ash is the same as in Example 1. Put the waste incineration fly ash and the ferroferric oxide powder in a mixer at a mass ratio of 5:1 to fully mix, then add deionized water to granulate and shape, and put the molded particles into Graphite crucible, and add embedded ferroferric oxide powder (particle size ≤200μm), put the crucible into an industrial microwave oven for embedding powder melting, the working frequency of the microwave sintering furnace is 2.45GHz, the power of the microwave oven is 300kW, heating After 15 minutes, the molten slag is obtained in the crucible after cooling. The molten slag and the buried powder are separated by a sieve. After separation, the microwave coupling agent is reserved as buried powder for later use. The concentration of dioxins in the molten slag is reduced to 0.018ng TEQ / g. The test results of heavy metal leaching toxicity of molten slag are shown in Table 5. The hazardous concentration in the leaching so...

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Abstract

The invention discloses a harmless treatment method of waste burning fly ash. The method comprises the following steps: 1, fully mixing the waste burning fly ash with a small amount of a microwave coupling agent, adding a proper amount of water, and carrying out granulation molding through a molding machine; 2, embedding the above molded particles with the microwave coupling agent; 3, sending the powder embedded molded particles into an industrial microwave oven, carrying out microwave melting, and screening molten slag and the microwave coupling agent for separation; and 4, returning the separated microwave coupling to be used as embedding powder. The fly ash is internally and externally heated and rapidly molten due to the wave absorption characteristic of the microwave coupling agent and substances in the fly ash, so dioxins in the fly ash are completely decomposed, and most heavy metals are cured; and the separated microwave coupling agent can be recycled. The method overcomes the disadvantages of large energy consumption and low thermal efficiency of traditional melting modes.

Description

Technical field [0001] The present invention involves a method of environmental pollution control, which specializes in a harmless treatment method of waste incineration flying ash. Background technique [0002] Domestic waste incineration power generation technology has the dual benefits of environmental protection and energy, and has become the development direction of urban waste treatment.my country's waste incineration power generation has developed rapidly in recent years. After incineration, it will generate about 3 to 5 % of the fly ash. These incineration flying ash contains a considerable amount of toxic substances such as two evil English and heavy metals. The cumulative effect of the organism will eventually be taken by the human body through the food chain to endanger human survival and health through the food chain.In accordance with the State Administration of Environmental Protection, waste incineration ash is a hazardous waste and must be treated.At present, the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B32/00A62D3/40A62D101/08A62D101/28
CPCY02W30/82
Inventor 刘汉桥孙磊魏国侠徐仙
Owner TIANJIN CHENGJIAN UNIV
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