Cement-based composite material used for 3D printing as well as preparation method and application thereof

A composite material and 3D printing technology, which is applied in the field of building materials, can solve problems such as slow condensation, low toughness, and difficult molding, and achieve the effects of low long-term strength, long service life, and guaranteed safety

Active Publication Date: 2016-07-06
CHINA BUILDING MATERIALS ACAD
View PDF7 Cites 47 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Building materials generally use cement as the cementitious material. During the production process, cement usually undergoes a high temperature of more than 1400 degrees Celsius. When it is used, it needs to undergo a chemical reaction with water to solidify and form strength. The hydration process is particularly long and the setting speed is slow. , it is difficult to achieve the requirements of 3D printing fused deposition forming, which limits the 3D printing of cement-based materials like metal materials or polymer materials; secondly, cement-based materials are not easy to form after adding water and cement paste is a brittle material, The hardened slurry has poor resistance to external load impact and low toughness, which will cause the mechanical properties of 3D printed cement-based materials to fail to meet the needs of building materials
[0004] At present, there are relatively few studies and reports on 3D printing cement-based materials. The 3D printing cement-based materials disclosed in the four patent documents with application numbers of 201410554607.4, 201510225639.4, 201510375110.0 and 201510228281.0 all have the disadvantage of easy generation of air bubbles during the printing process, which seriously affects The appearance of cement products is improved; in addition, the above-mentioned patent documents all use alkaline accelerators, which are highly corrosive, and the strength of cement printed products is poor in the later stage.
These limit the application of 3D printing technology in the production of cement products

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Cement-based composite material used for 3D printing as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0071] A preparation method for a cement-based composite material for 3D printing, comprising the steps of:

[0072] Step 1: Prepare composite cementitious material: Mix 10kg P.I. type Portland cement, 30kg steel slag powder and 60kg sulphoaluminate cement evenly, wherein the steel slag powder is obtained by mixing 20kg slag and 10kg steel slag; The prepared composite gel material is ready for use.

[0073] Step 2: Preparation of anti-carbonation agent: Use a paint disperser to fully mix 0.75kg of chlorine partial emulsion and 6.75kg of styrene-acrylic emulsion for use.

[0074] Step 3: Prepare 3D printing fiber cement composite material, weigh 1.5kg shrinkage inhibitor (alkyl polyoxyethylene ether), 330kg aggregate (ceramsite), 5kg fiber reinforced material (basalt fiber), 7.5kg liquid alkali-free speed Coagulant, 6kg retarder (sucrose), 1kg thickener (polyethylene oxide), 1kg plasticizer (melamine formaldehyde sulfonate), 0.25kg defoamer (corn oil), 0.25kg water reducer (po...

Embodiment 2

[0092] The preparation method of this example is the same as that of Example 1, except that the types and contents of specific raw materials are different. The cement-based composite material for 3D printing prepared in this example consists of the following components:

[0093] P.I. type Portland cement 48kg; silica fume 28.8kg; slag powder 43.2kg; sulphoaluminate cement 120kg; alkyl polyoxyethylene ether: 6kg; Expanded perlite (particle size≤5mm): 290kg; carbon fiber: 2kg; polyvinyl alcohol fiber: 1kg; polypropylene alcohol fiber: 3kg; liquid alkali-free accelerator: 10kg; sucrose: 5kg; sorbitol: 3kg; maltitol : 5kg; salicylic acid: 1kg; methylcellulose: 1kg; montmorillonite 1kg; glycerin: 2kg; polyoxyethylene oxypropylene glycerin: 0.5kg; Naphthalene-based water-reducer: 0.5kg; polycarboxylate-based water-reducer: 0.4kg; water: 110kg.

[0094] The liquid alkali-free quick-setting agent is composed of the following components in terms of weight percentage: polyaluminum sulfat...

Embodiment 3

[0106] The preparation method of this example is the same as that of Example 1, except that the types and contents of specific raw materials are different. The cement-based composite material for 3D printing prepared in this example consists of the following components:

[0107] P.I. Portland cement 11kg; fly ash 5.5kg; metakaolin 5.5kg; sulphoaluminate cement 198kg; alkyl polyoxyethylene ether: 4kg; chlorine partial emulsion 5.5kg; diameter≤5mm): 320kg; natural sand: 320kg; glass fiber: 5kg; liquid alkali-free accelerator: 13kg; sucrose: 12kg; methyl cellulose: 0.3kg; glycerin: 3kg; Naphthalene-based water reducer: 1kg; water: 90kg.

[0108] The liquid alkali-free quick-setting agent is composed of the following components in terms of weight percentage: polyaluminum sulfate: 40%; magnesium sulfate: 10%; alcohol amine: 15% of the weight of the polyaluminum sulfate; inorganic acid: 2%; Agent: 3%; the balance is water.

[0109] The follow-up test of this embodiment is carried ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
viscosityaaaaaaaaaa
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to view more

Abstract

The invention discloses a cement-based composite material used for 3D printing as well as a preparation method and application thereof, and belongs to the field of building materials. The cemented-based composite material comprises the following components in percentage by weight: 19-25% of a composite gel material, 0.2-0.6% of a shrinkage inhibitor, 1-2% of an anti-carbonization agent, 57-66% of aggregates, 0.3-1.1% of fiber-reinforced materials, 0.9-1.8% of a liquid alkali-free accelerating agent, 0.8-1.7% of a retarder, 0.02-2% of a thickening agent, 0.2-0.4% of a plastic retaining agent, 0.04-0.09% of a defoaming agent, 0.04-0.2% of a water reducer and 5-14% of water. A cement product printed by the cement-based composite material has no holes and pitted surface in appearance.

Description

technical field [0001] The invention relates to the technical field of building materials, in particular to a cement-based composite material for 3D printing and its preparation method and application. Background technique [0002] The existing 3D printing technology is a technology based on digital model files, using powdered metal or plastic-based adhesive materials to construct objects by layer-by-layer printing. Traditional 3D printing technologies are all Used in the field of metal and polymer materials. Now, 3D printing technology has begun to try to be used in the construction of houses. Compared with traditional construction technology, 3D printing construction technology can produce complex and diverse buildings without using templates, which reduces construction costs; reduces labor input and reduces costs; reduces waste of materials and saves costs; processing speed is faster than traditional The industry is fast. [0003] Building materials generally use cemen...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/06C04B7/02C04B14/46C04B18/02C04B18/14C04B24/08C04B24/10C04B24/22C04B24/26C04B24/28C04B24/32C04B14/02C04B14/04C04B14/18C04B14/38C04B16/06C04B24/02C04B24/38C04B24/42C04B14/10C04B14/42C04B18/08C04B103/12C04B103/30
CPCB33Y70/00C04B28/065C04B40/0039C04B2103/12C04B2111/00181C04B7/02C04B18/142C04B24/2682C04B24/26C04B24/32C04B18/023C04B14/46C04B24/10C04B24/281C04B24/223C04B24/08C04B2103/302C04B22/148C04B22/142C04B24/122C04B18/146C04B14/02C04B14/185C04B14/386C04B16/0641C04B16/0616C04B24/02C04B24/383C04B14/041C04B24/42C04B18/08C04B14/106C04B14/06C04B14/42C04B28/04Y02W30/91C04B14/104C04B14/38C04B16/0633C04B24/04C04B24/2647C04B2103/30
Inventor 王振地姚燕王玲
Owner CHINA BUILDING MATERIALS ACAD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products