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PTC thermistor base material and preparation method thereof

A thermistor and base material technology, which is applied in the field of PTC thermistor base material and its preparation, can solve the problems of limiting the application range of PTC materials, wide room temperature resistance distribution, and limiting the application range, etc., to increase dispersion and compatibility , reduced mechanical properties, good electrical conductivity

Active Publication Date: 2016-10-12
ANHUI NINGGUO TIANCHENG ELECTRICAL APPLIANCES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, many PTC thermistors use polymer material HDPE, but its melting point is only about 130°C, which limits the application range of PTC materials.
At the same time, the current organic PTC materials mainly use graphite and carbon black as conductive fillers, which mainly have problems such as wide room temperature resistance distribution, low PTC strength, and low stability.
[0004] Chinese patent CN 104861273 A discloses a "composite material for thermistor and its preparation method and application", which uses HDPE as the main matrix, and uses specific proportions of titanium diboride, carbon fiber and multi-walled carbon nanotubes As a conductive filler, the material has good comprehensive performance in terms of room temperature conductivity, PTC strength and stability, but due to the influence of the melting point of HDPE itself, its application range is limited

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A PTC thermistor base material, consisting of the following raw materials in parts by weight: 65 parts of HDPE, 18 parts of PET, 4 parts of EEA, 28 parts of silver-plated copper powder, 6 parts of carbon fiber, 1 part of graphene, and 6 parts of palygorskite powder , 4 parts of basalt fiber, 3 parts of wollastonite, 2 parts of mica powder, 3 parts of dicumyl peroxide, 7 parts of nano filler, 4 parts of silane coupling agent, 2.5 parts of amine antioxidant, organic silicon flame retardant 3 copies. The nano filler is a mixture of nano silicon dioxide, nano calcium carbonate and nano titanium dioxide.

[0021] The preparation method of PTC thermistor base material specifically comprises the following steps:

[0022] (1) Weighing: take each raw material in proportion;

[0023] (2) Premixing: silver-plated copper powder, carbon fiber, graphene, palygorskite powder, basalt fiber, wollastonite, mica powder, dicumyl peroxide, nano filler, silane coupling agent, amine anti- ...

Embodiment 2

[0026] A PTC thermistor base material is characterized in that it consists of the following raw materials in parts by weight: 70 parts of HDPE, 15 parts of PET, 5 parts of EEA, 25 parts of silver-plated copper powder, 8 parts of carbon fiber, 0.8 part of graphene, slope 6 parts of gorgorite powder, 3 parts of basalt fiber, 4 parts of wollastonite, 2 parts of mica powder, 3 parts of dicumyl peroxide, 5 parts of nano filler, 5 parts of titanate coupling agent, 2 parts of phenolic antioxidant parts, 4 parts of silicone flame retardant. The nano filler is a mixture of nano silicon dioxide, nano calcium carbonate and nano titanium dioxide.

[0027] The preparation method of PTC thermistor base material specifically comprises the following steps:

[0028] (1) Weighing: take each raw material in proportion;

[0029] (2) Premixing: silver-plated copper powder, carbon fiber, graphene, palygorskite powder, basalt fiber, wollastonite, mica powder, dicumyl peroxide, nano filler, titanat...

Embodiment 3

[0032] A PTC thermistor base material is characterized in that it consists of the following raw materials in parts by weight: 60 parts of HDPE, 20 parts of PET, 3 parts of EEA, 30 parts of silver-plated copper powder, 4 parts of carbon fiber, 1 part of graphene, slope 5 parts of gargoyle powder, 5 parts of basalt fiber, 3 parts of wollastonite, 3 parts of mica powder, 2 parts of dicumyl peroxide, 8 parts of nano filler, 3 parts of silane coupling agent, 3 parts of phenolic antioxidant, 2 parts of silicone flame retardant. The nano filler is a mixture of nano silicon dioxide, nano calcium carbonate and nano titanium dioxide.

[0033] The preparation method of PTC thermistor base material specifically comprises the following steps:

[0034] (1) Weighing: take each raw material in proportion;

[0035] (2) Premixing: silver-plated copper powder, carbon fiber, graphene, palygorskite powder, basalt fiber, wollastonite, mica powder, dicumyl peroxide, nano filler, silane coupling ag...

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PUM

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Abstract

The invention belongs to the field of a high-molecular material, and more specifically relates to a PTC thermistor base material and a preparation method thereof. The PTC thermistor base material comprises the following raw materials in parts by weight: 60-70 parts of HDPE, 15-20 parts of PET, 3-5 parts of EEA, 25-30 parts of silver-plated copper powder, 4-8 parts of carbon fiber, 0.8-1 part of graphene, 5-6 parts of palygorskite powder, 3-5 parts of basalt fiber, 3-4 parts of wollastonite, 2-3 parts of mica powder, 2-3 parts of dicumyl peroxide, 5-8 parts of a nano filling material, 3-5 parts of a coupling agent, 2-3 parts of an anti-oxidant, and 2-4 parts of an organosilicon fire retardant. The preparation method comprises the steps of weighing, premixing and mixing. The PCT thermistor has low room-temperature resistivity, high heat resistance, high stability and high intensity, and excellent comprehensive property.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a PTC thermistor substrate and a preparation method thereof. Background technique [0002] PTC (positive temperature coefficient) is a positive temperature coefficient thermosensitive material, which has the characteristic that the resistivity increases with the increase of temperature. PTC elements can be composed of ceramics or organic polymers doped with conductive particles such as graphite or carbon black. The conductive particles allow the flow of electric current at low temperatures due to their contact with each other, but by heating the polymer matrix expands so that the contact of the particles becomes loose and eventually the current flow is blocked or even no longer possible. Today, PTC thermistors are widely used in heaters. [0003] At present, many PTC thermistors use polymer material HDPE, but its melting point is only about 130°C, which limits the a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L67/02C08L23/08C08K13/06C08K9/02C08K3/08C08K7/06C08K7/10C08K3/34
CPCC08K2201/001C08K2201/011C08K2201/014C08L23/06C08L2201/02C08L2201/08C08L2205/03C08L2205/08C08L2207/066C08L67/02C08L23/0869C08K13/06C08K9/02C08K2003/085C08K7/06C08K7/10C08K3/34
Inventor 汪洋陈启志李国春肖美玲
Owner ANHUI NINGGUO TIANCHENG ELECTRICAL APPLIANCES
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