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A kind of mineral waste refractory material and its preparation process

A refractory material and a preparation process technology, applied in the field of refractory materials, can solve the problems of reducing the service life of refractory materials, poor mechanical toughness, increasing the damage rate of refractory products, etc., achieving easy large-scale production, simple preparation method, and solving environmental pollution. and waste of resources

Active Publication Date: 2019-05-21
CHANGXING MENGYOU REFRACTORIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The poor mechanical toughness of inorganic non-metallic materials is a common problem in inorganic non-metallic materials and materials. As refractory materials that belong to inorganic non-metallic materials, their mechanical toughness is also poor. However, its poor mechanical toughness also affects its thermal shock resistance at high temperatures. Due to the large temperature difference between rapid cooling and rapid heating and use, refractory materials are prone to cracking and peeling under the action of thermal expansion and contraction. The situation that affects the integrity of refractory materials reduces the service life of refractory materials; at the same time, for those refractory products that need to be moved frequently, their poor mechanical toughness will greatly increase the damage rate of refractory products and affect their daily use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A mineral waste refractory material is prepared from the following raw materials in parts by weight: 50 parts of coal gangue, 120 parts of red mud, 10 parts of magnesium oxide, 4 parts of manganese oxide, 5 parts of titanium oxide, 2 parts of niobium pentoxide, and 15 parts of tough fiber; coal gangue is high-silicon coal gangue with a silicon oxide content of 48wt% and an alumina content of 13wt%; red mud is high-alumina red mud with an alumina content of 26wt% and a silica content of 12wt% , the calcium oxide content is 25wt%;

[0031] Wherein, the toughening fiber is a modified zirconia fiber, which is obtained through the following steps: 50 parts by weight of zirconia, after adding 3 parts by weight of calcium oxide and 1 part by weight of sodium oxide, and 400 parts by molar ratio of 1:1 The sodium chloride and potassium chloride compound salts were mixed and ground for 12 hours with absolute ethanol as the grinding medium, dried and calcined at 850°C for 6 hours,...

Embodiment 2

[0038]A mineral waste refractory material is prepared from the following raw materials in parts by weight: 50 parts of coal gangue, 130 parts of red mud, 13 parts of magnesium oxide, 5 parts of manganese oxide, 5.5 parts of titanium oxide, 3 parts of niobium pentoxide, and 17 parts of tough fiber; coal gangue is high-silicon coal gangue with a silicon oxide content of 49wt% and an alumina content of 14wt%; red mud is high-alumina red mud with an alumina content of 27wt% and a silica content of 13wt% , the calcium oxide content is 26wt%;

[0039] Wherein, the toughening fiber is a modified zirconia fiber, which is obtained through the following steps: 50 parts by weight of zirconia, after adding 3 parts by weight of calcium oxide and 1 part by weight of sodium oxide, and 400 parts by molar ratio of 1:1 The sodium chloride and potassium chloride compound salts were mixed and ground for 12 hours with absolute ethanol as the grinding medium, dried and calcined at 850°C for 6 hours...

Embodiment 3

[0046] A mineral waste refractory material is prepared from the following raw materials in parts by weight: 50 parts of coal gangue, 140 parts of red mud, 15 parts of magnesium oxide, 6 parts of manganese oxide, 6 parts of titanium oxide, 4 parts of niobium pentoxide, and 20 parts of tough fiber; coal gangue is high-silicon coal gangue with a silicon oxide content of 50wt% and an alumina content of 15wt%; red mud is high-alumina red mud with an alumina content of 28wt% and a silica content of 14wt% , the calcium oxide content is 27wt%;

[0047] Wherein, the toughening fiber is a modified zirconia fiber, which is obtained through the following steps: 50 parts by weight of zirconia, after adding 3 parts by weight of calcium oxide and 1 part by weight of sodium oxide, and 400 parts by molar ratio of 1:1 The sodium chloride and potassium chloride compound salts were mixed and ground for 12 hours with absolute ethanol as the grinding medium, dried and calcined at 850°C for 6 hours,...

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Abstract

The invention discloses a minerals waste refractory material and a preparation technology thereof. The refractory material is prepared from the following raw materials: gangue, red mud, magnesium oxide, manganese oxide, titanium oxide, niobium pentoxide, reinforcement fiber and the like. The preparation technology comprises the following steps: mixing the above raw materials, ball-milling in anhydrous ethanol and carrying out ball-mill mixing, drying the raw materials, dry-pressing to prepare a green body of the refractory material, sintering, and naturally cooling to room temperature after sintering. Thus, the minerals waste refractory material is prepared. By using minerals waste gangue and red mud as the raw materials and by fully utilizing residual waste obtained after processing of mineral resources, the problems of environment pollution and resource wastage caused by minerals waste are solved. As modified zirconia fiber is utilized for toughening treatment of the refractory material, the prepared refractory material has good mechanical toughness and excellent thermal shock resistance. The preparation method of the refractory material is simple and is easy for large-scale production by existing equipment.

Description

technical field [0001] The invention relates to the technical field of refractory materials, in particular to a mineral waste refractory material and a preparation process thereof. Background technique [0002] In the traditional sense, refractory materials refer to inorganic non-metallic materials with a refractoriness of not less than 1580 °C. And parts of the material, and can withstand the corresponding physical and chemical changes and mechanical action. [0003] Most refractory materials are made of natural ores (such as refractory clay, silica, magnesite, dolomite), and some industrial raw materials and synthetic raw materials (such as industrial alumina, silicon carbide, synthetic mullite, Synthetic spinel, etc.) are also increasing, so there are many types of refractory materials. According to the mineral composition, refractories can be divided into silica, aluminum silicate, magnesia, dolomite, olivine, spinel, carbonaceous, zirconium-containing refractories and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66C04B35/48C04B35/622
CPCC04B35/62204C04B35/6225C04B35/66C04B2235/3206C04B2235/3232C04B2235/3251C04B2235/3262C04B2235/96
Inventor 佘玉明
Owner CHANGXING MENGYOU REFRACTORIES