A method for comprehensive utilization of arsenic-containing smoke and dust and harmless disposal of arsenic
An arsenic fume and arsenic precipitation technology, applied in the metallurgical field, can solve the problems of untreated sodium arsenate, low recovery rate of valuable metals, unrecovered metals, etc. effect of the problem
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Embodiment 1
[0061] Taking arsenic-containing soot from a lead-zinc smelter in China as an example, the main components of the raw material are Pb 1.57%, As 48.56%, Sn 0.51%, Sb 21.24%, Zn 0.73%, Te 0.35%, Se 0.25%, and the following steps are used deal with:
[0062] (1) Oxygen pressure water immersion: Weigh a certain quality of high arsenic and antimony fumes into the reactor, the control conditions are liquid-solid volume mass ratio 10:1, stirring speed 300r / min, leaching temperature 160°C, oxygen partial pressure 2Mpa, The leaching time is 2 hours. After the leaching is completed, the slurry is removed and separated by filtration to obtain the leaching solution and leaching residue;
[0063] After testing: the leaching rate of arsenic is 68.64%, the concentration of each element in the leach solution is 709.60ppm Pb, 31.02ppm Se, 1.26g / L Sb, 123.28ppm Te, and 33.33g / L As.
[0064] (2) Regulate growth method to fix arsenic: adjust the pH value of the leachate obtained in step (1) to 2...
Embodiment 2
[0071] Taking arsenic-containing soot from a lead-zinc smelter in China as an example, the main components of the raw material are Pb 6.88%, As 36.51%, Sn 1.11%, Sb 29.77%, Zn 0.54%, Te 0.24%, Se 0.05%, and the following steps are used deal with:
[0072] (1) Oxygen pressure water immersion: Weigh a certain quality of high arsenic and antimony fumes into the reactor, the control conditions are liquid-solid volume mass ratio 20:1, stirring speed 300r / min, leaching temperature 160°C, oxygen partial pressure 0.5Mpa , the leaching time is 2h, after the leaching is completed, the slurry is removed and separated by filtration to obtain the leaching solution and leaching residue;
[0073] After testing: the arsenic leaching rate is 72.68%, and the concentration of each element in the leach solution is 515.20ppm Pb, 31.56ppm Se, 0.88g / L Sb, 122.26ppm Te, and 13.27g / L As.
[0074] (2) Distributed crystallization method for arsenic fixation: adjust the initial pH value of the leaching ...
Embodiment 3
[0081] Taking arsenic-containing soot from a lead-zinc smelter in China as an example, the main components of the raw material are Pb 5.46%, As 30.29%, Sn 0.98%, Sb 29.58%, Zn 0.68%, Te 0.26%, Se 0.07%, and the following steps are used deal with:
[0082] (1) Oxygen pressure water immersion: Weigh a certain quality of high arsenic and antimony fume in the reaction kettle, the control conditions are liquid-solid volume mass ratio 10:1, stirring speed 300r / min, leaching temperature 200℃, oxygen partial pressure 2.5Mpa , the leaching time is 4h, after the leaching is finished, remove the slurry, filter and separate, and obtain the leaching solution and leaching residue;
[0083] After testing: the arsenic leaching rate is 62.75%, and the concentration of each element in the leach solution is Pb 956.35ppm, Se 18.91ppm, Sb 0.93g / L, Te 144.92ppm, As 19.01g / L.
[0084] (2) Fixing arsenic in the leach solution: using the lime arsenic precipitation method, adjust the pH value of the l...
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