Preparing method of ozone heterogeneous oxidation solid catalyst

Abstract

The invention relates to a preparing method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical field of environmental protection and chemical catalysts. The method comprises the steps that perlite, albite, magnesia spinel, peridotite, coal ash and coal gangue serve as carriers, and after broaching is conducted on the carriers with lithium hypochlorite double (acetylacetone) beryllium, a surfactant N-decylalkyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium chloride is added to be subjected to activating treatment under the effect of ultrasonic wave; a hydrothermal reaction is conducted on the carriers, compound mineralizing agent borax and potassium sulphate, catalytic active auxiliary precursors tricyclopentadiene promethium, tris (4,4,4,4-trifluoro-1-(2-thiophene)-1,3-butandione) europium, tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato) dysprosium (III) and erbiumtrisbistrimethylsilylamide, catalytic active central precursors cobalt gluconate, cupric glutamate and gold potassium chloride and dipotassium hexachloroosmate in a hydrothermal reactor under the effect of an emulgator tetradecyl dimethyl benzyl ammonium chloride, and after moisture is removed through drying, the ozone heterogeneous oxidation solid catalyst is obtained through firing in a muffle furnace.

Description

Technical field [0001] The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, belonging to the technical field of environmental protection and chemical catalysts. Background technique [0002] Ozone oxidation technology takes advantage of the strong ability of ozone to oxidize and decompose many organic pollutants, and is widely used in wastewater treatment. Ozone catalytic oxidation technology is divided into homogeneous catalytic oxidation of ozone and heterogeneous catalytic oxidation of ozone. In homogeneous catalytic oxidation of ozone, the catalyst is difficult to separate and recycle and reuse, and the low utilization rate of ozone leads to higher water treatment operating costs and removal of organic pollutants. The low rate and easy to cause secondary pollution of water make its application limited; the ozone heterogeneous catalytic oxidation technology has catalysts that are easy to separate and recover and can be reused, hi...

AI Technical Summary

Problems solved by technology

[0004] In view of the problems of low catalyst adsorption, poor anti-toxicity and easy loss of catalytic activity in the current preparation method of ozone heterogeneous oxidation solid catalyst, a multi-component porous carrier was developed to enhance the adsorption of the catalyst through pore expansion and surface activation. Rare earth metal organic compounds as precursors of catalytic active additives, common transition metal organic compounds and noble metal compounds as precursors of catalytic active centers and multi-component porous carriers through hydrothermal reaction and high temperature calcination to prepare ozone heterogeneous oxidation containing multiple metals The preparation method of solid catalyst to improve the anti-toxicity and catalytic activity of the catalyst is characterized in that component A and deionized water are added into a sealable reactor and stirred to prepare an aqueous solution, and the weight concentration of component A is controlled to be 2% to 6%. After the preparation is completed, add component B under stirring, raise the temperature to 35°C-50°C, continue to stir for 3h-6h, filter, and dry the reaction product at 102°C-106°C to obtain a modified carrier for pore expansion; pore expansion Put the modified carrier into the ultrasonic reactor, add the aqueous solution prepared by C component and deionized water, the weight concentration of C component is 3%~8%, stir and mix evenly, control the ultrasonic power density to 0.3~0.8W / m 3 , frequency 20kHz ~ 30kHz, 40 ℃ ~ 55 ℃, ultrasonic vibration 2h ~ 5h, the ultrasonic surface activation carrier mixture is obtained; the ultrasonic surface activation carrier mixture is transferred to the hydrothermal reaction kettle, and then add D component and deionized water to prepare The aqueous solution, the weight concentration of D component is 40% ~ 55%, by weight, the weight ratio of D component deionized aqueous solution: ultrasonic surface activation carrier mixture = 1: (1.5 ~ 2), control temperature 120 ℃ ~ 180°C, the hydrothermal reaction time is 8h~16h, and then dried to obtain fine particles; the fine particles are burned in a muffle furnace at 600°C~950°C for 3h~8h to obtain a solid catalyst for ozone heterogeneous oxidation