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Zero discharge treatment method for saline wastewater

A technology of saline wastewater and its treatment method, which is applied in the zero discharge treatment of high saline wastewater in the coal chemical industry and in the field of zero discharge treatment of saline wastewater, which can solve problems such as high cost, inability to achieve zero discharge, and ineffective integration of functions. Achieve the effects of low cost, long operation cycle and improved recovery rate

Active Publication Date: 2020-05-19
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This method combines membrane technologies such as nanofiltration, frequent electrode reversal electrodialysis, and reverse osmosis, but the effects of different membrane technologies have not been effectively integrated, and pretreatment requires advanced treatment such as ion exchange, which is costly; Sodium chloride crystallization and sodium sulfate crystallization, but after analysis and testing, if this method needs to ensure the purity of the crystallized salt, a certain amount of high-concentration saline wastewater needs to be discharged, and zero discharge cannot be achieved, and the salt recovery rate needs further improvement. improve

Method used

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  • Zero discharge treatment method for saline wastewater
  • Zero discharge treatment method for saline wastewater
  • Zero discharge treatment method for saline wastewater

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Experimental program
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Effect test

Embodiment 1

[0051] The average concentration of each pollutant in a high-salt industrial wastewater is: COD is 70 mg / L, total hardness (calculated as CaCO 3 Calculated) is 800 mg / L, total alkalinity (as CaCO 3 (calculated) is 300 mg / L, silicon dioxide is 30 mg / L, and TDS is 4500 mg / L, among which, the concentration of nitrate ion is 60 mg / L, the concentration of chloride ion is 680 mg / L, and the concentration of sulfate ion is 1100 mg / L, the pH value is 7.5. Such as figure 1 As shown, using the zero-discharge treatment process for coal chemical industry saline wastewater includes the following steps:

[0052] (1) The salty wastewater enters the high-density clarifier. According to the water quality of the saline wastewater, calcium hydroxide is added at 1.5 g / L in the reaction zone of the high-density clarifier to maintain the pH value at 10.5-11.0, and then add 2.2 g / L sodium carbonate, then add 50mg / L PFS for coagulation and 4 mg / L PAM to aid coagulation. After fully coagulating in ...

Embodiment 2

[0061] The average concentration of each pollutant in a high-salt industrial wastewater is: COD is 68 mg / L, total hardness (calculated as CaCO 3 Calculated) is 1000 mg / L, total alkalinity (as CaCO 3 (calculated) is 500 mg / L, silicon dioxide is 30 mg / L, and TDS is 5000 mg / L, among which, the concentration of nitrate ion is 70 mg / L, the concentration of chloride ion is 700 mg / L, and the concentration of sulfate ion is 1000 mg / L. mg / L, the pH value is 7.8.

[0062] Such as figure 1 As shown, using the zero-discharge treatment process for coal chemical industry saline wastewater includes the following steps:

[0063] (1) The saline wastewater enters the high-density clarifier. According to the water quality of the saline wastewater, 1.8 g / L sodium hydroxide is added to the reaction zone of the high-density clarifier to maintain the pH value at 11.0-11.5, and then add 2.0 g / L sodium carbonate, then add 100mg / L PFS for coagulation and 10 mg / L PAM to aid coagulation. After fully ...

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Abstract

The invention relates to a zero-discharge treatment method for salt-containing wastewater. The method comprises the following steps: (1) pretreatment; (2) reverse osmosis treatment; (3) biochemical treatment; (4) electrodialytic concentration; and (5) cyclic crystallization. Compared with the prior art, the zero-discharge treatment method for salt-containing wastewater provided by the invention achieves zero discharge or almost zero discharge of coal chemical wastewater, improves the recovery rate of salt, can recover high-quality sodium sulfate, mirabilite and sodium chloride and realizes comprehensive utilization of crystalline salt; a membrane treatment unit is stable in process, long in operation cycle and low in cost; and the method has good economical performance.

Description

technical field [0001] The invention belongs to the technical field of environmental protection, and in particular relates to a zero-discharge treatment method for saline wastewater, in particular to a zero-discharge treatment method for high-salt wastewater in the coal chemical industry. Background technique [0002] Coal chemical industry is a process in which coal is used as raw material and converted into gas, liquid, solid fuel and chemicals through chemical processing. Coal chemical industry mainly includes coal gasification, liquefaction, dry distillation, tar processing and calcium carbide acetylene chemical industry. Coal chemical projects consume a lot of water and generate a lot of wastewater. However, most of the coal chemical projects in my country are distributed in the northwest region where water resources are scarce and sewage receiving bodies are lacking. With the continuous adjustment of national environmental protection policies, the waste water of coal...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C01D3/06C01D5/00
CPCC01D3/06C01D5/00C02F1/001C02F1/04C02F1/441C02F1/444C02F1/4693C02F1/52C02F1/725C02F1/78C02F3/00C02F9/00C02F2305/06
Inventor 陈明翔高会杰孙丹凤郭志华赵胜楠郭宏山
Owner CHINA PETROLEUM & CHEM CORP