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Adhesive for flame-retardant glass wool and preparation method of adhesive

A technology of adhesive and glass wool, applied in the direction of adhesive types, polyether adhesives, polymer adhesive additives, etc., can solve the problems affecting the flame retardancy of glass wool, achieve strong rigidity, improve resistance Combustibility, good toughness effect

Inactive Publication Date: 2019-01-11
苏州华龙化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Glass wool needs adhesives to be bonded during the preparation process. Although glass wool has certain flame-retardant properties, most of the adhesives are based on rubber, plastics and other polymer materials. Therefore When applied to the production process of glass wool, it will inevitably affect the flame retardant performance of glass wool. Therefore, it has important application value to provide a high flame retardant adhesive applied to glass wool to improve the flame retardant performance of glass wool

Method used

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  • Adhesive for flame-retardant glass wool and preparation method of adhesive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A flame-retardant adhesive for glass wool, prepared from the following raw materials in parts by weight: 60 parts of acrylonitrile-butadiene-styrene copolymer, 42 parts of polyarylether ether nitrile, 24 parts of phenolic resin, three 12 parts of ethylene propylene rubber, 9 parts of diethyl aminomalonate, 13 parts of inorganic flame retardant filler, 5 parts of epoxy soybean oil, 10 parts of alumina fiber, 4.5 parts of cosolvent, 6 parts of dimethylaminopropylamine, ten parts 12 parts of bromodiphenylethane, 22 parts of n-butanol.

[0019] The co-solvent is ethylene glycol butyl ether acetate and N,N-dimethylacetamide with a volume ratio of 5:2.

[0020] The inorganic flame retardant filler is white carbon black, kaolin, zinc borate and ammonium tripolyphosphate with a mass ratio of 3:2:5:7.

[0021] The preparation method of adhesive of the present invention comprises the following steps:

[0022] (1) Put acrylonitrile-butadiene-styrene copolymer, polyarylether ethe...

Embodiment 2

[0027] A flame-retardant adhesive for glass wool, prepared from the following raw materials in parts by weight: 50 parts of acrylonitrile-butadiene-styrene copolymer, 35 parts of polyarylether ether nitrile, 18 parts of phenolic resin, three 8 parts of ethylene propylene rubber, 6 parts of diethyl aminomalonate, 9 parts of inorganic flame retardant filler, 3 parts of epoxy soybean oil, 6 parts of alumina fiber, 3 parts of cosolvent, 4 parts of dimethylaminopropylamine, ten parts 7 parts of bromodiphenylethane, 15 parts of n-butanol.

[0028] The co-solvent is ethylene glycol butyl ether acetate and N,N-dimethylacetamide with a volume ratio of 5:1.

[0029] The inorganic flame retardant filler is white carbon black, kaolin, zinc borate and ammonium tripolyphosphate with a mass ratio of 2:1:4:5.

[0030] The preparation method of adhesive of the present invention comprises the following steps:

[0031] (1) Put acrylonitrile-butadiene-styrene copolymer, polyarylether ether nitr...

Embodiment 3

[0036] A flame-retardant adhesive for glass wool, prepared from the following raw materials in parts by weight: 55 parts of acrylonitrile-butadiene-styrene copolymer, 40 parts of polyarylether ether nitrile, 20 parts of phenolic resin, three 10 parts of ethylene propylene rubber, 8 parts of diethyl aminomalonate, 12 parts of inorganic flame retardant filler, 4 parts of epoxy soybean oil, 8 parts of alumina fiber, 4 parts of cosolvent, 5 parts of dimethylaminopropylamine, ten parts Bromodiphenylethane 10 parts, n-butanol 20 parts.

[0037] The co-solvent is ethylene glycol butyl ether acetate and N,N-dimethylacetamide with a volume ratio of 5:1.5.

[0038] The inorganic flame retardant filler is white carbon black, kaolin, zinc borate and ammonium tripolyphosphate with a mass ratio of 3:1:5:6.

[0039] The preparation method of adhesive of the present invention comprises the following steps:

[0040] (1) Put acrylonitrile-butadiene-styrene copolymer, polyarylether ether nitri...

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Abstract

The invention provides an adhesive for flame-retardant glass wool and a preparation method of the adhesive. The adhesive contains the following raw materials in parts by weight: 50-70 parts of an acrylonitrile-butadiene-styrene copolymer, 35-50 parts of polyarylene ether nitrile, 18-30 parts of phenolic resin, 8-15 parts of ethylene-propylene-diene monomer, 6-12 parts of diethyl aminomalonate hydrochloride, 9-16 parts of an inorganic flame-retardant filler, 3-8 parts of epoxidized soybean oil, 6-13 parts of alumina fibers, 3-6 parts of a cosolvent, 4-8 parts of dimethylaminopropylamine, 7-16 parts of decabrominated dipheny ethane and 15-30 parts of n-butyl alcohol. The adhesive has good mechanical strength and flame retardance and further has good noninflammability due to a relatively highlimit oxygen index, added polyarylene ether nitrile and phenolic resin have great importance to the mechanical strength and flame retardance of the adhesive, and meanwhile, added alumina as a supportcarrier for a nano-filler has great importance to the flame retardance of the adhesive.

Description

technical field [0001] The invention belongs to the technical field of adhesives, and in particular relates to an adhesive for flame-retardant glass wool and a preparation method thereof. Background technique [0002] Glass wool belongs to a category of glass fibers and is a man-made inorganic fiber. Glass wool is a material made of molten glass fibrosis to form a cotton-like material. Its chemical composition belongs to glass and is an inorganic fiber. It has the advantages of good molding, small bulk density, low thermal conductivity, thermal insulation, good sound absorption performance, corrosion resistance, and stable chemical properties. In 1840, Britain first discovered that molten slag could be blown into fibers, and began to produce slag wool. In 1880, through research on the properties and uses of slag wool, Germany and the United States began to produce slag wool, and then it was used and produced in other countries. From 1930 to 1950, large-scale production an...

Claims

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Application Information

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IPC IPC(8): C09J155/02C09J171/10C09J161/06C09J11/04C09J11/08
CPCC09J155/02C08K2003/2227C08K2003/387C08K2201/011C08L2201/02C08L2201/08C08L2205/035C09J11/04C09J11/08C08L71/00C08L61/06C08L23/16C08L91/00C08K13/02C08K3/36C08K3/346C08K3/38C08K3/22
Inventor 吴建平
Owner 苏州华龙化工有限公司
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