A high-efficiency flame-retardant and antibacterial functional masterbatch for direct injection molding of polypropylene and its preparation method

A technology of injection molding and functional masterbatch, which is applied in the field of high-efficiency flame-retardant and antibacterial functional masterbatch and its preparation. Problems such as damage, interference with modification effect, etc., to ensure flame retardant and antibacterial modification effects, reduce the probability of mutual contact, and solve the effect of mutual loss of modification performance

Active Publication Date: 2021-10-01
江苏万纳普新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the processing process, the strong shearing effect of the twin-screw will lead to ion adsorption and even chemical reaction between the silver and zinc ions and the brominated flame retardant, which interferes with the modification effect of the two, resulting in its Mutual loss of antibacterial and flame retardant performance, or even complete failure
This typical phenomenon of mutual loss of additive modification performance seriously affects the modification effect of brominated flame retardants and silver-loaded zinc inorganic antibacterial agents.

Method used

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  • A high-efficiency flame-retardant and antibacterial functional masterbatch for direct injection molding of polypropylene and its preparation method

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Experimental program
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Effect test

Embodiment 1

[0029] A high-efficiency flame-retardant and antibacterial functional masterbatch for polypropylene direct injection molding, which is composed of two masterbatches, A and B, and the mass ratio of raw materials for the A masterbatch is as follows:

[0030] Silver loaded zinc zeolite antimicrobial agent 10.0kg Barium sulfate 40.0 kg Glass fiber powder 30.0 kg Sodium ion crosslinked ethylene–acrylic acid copolymer elastic ionomer 18.0 kg stearic acid 1.0 g Ethylene bis stearamide 1.0 g

[0031] The mass ratio of the raw materials of the B masterbatch is as follows:

[0032] Octabromo-S ether 70.0 kg Antimony trioxide 15.0 kg Atactic polypropylene 13.0kg PTFE powder 1.0 kg stearic acid 500.0 g Ethylene bis stearamide 500.0 g

[0033] The preparation method of A masterbatch is as follows: Weigh all raw materials according to the above mass ratio requirements, put them into a high-speed...

Embodiment 2

[0036] A high-efficiency flame-retardant and antibacterial functional masterbatch for polypropylene direct injection molding, which is composed of two masterbatches, A and B, and the mass ratio of raw materials for the A masterbatch is as follows:

[0037] Silver-loaded zinc porous glass antibacterial agent 7.0 kg Barium sulfate 40.0 kg talcum powder 23.0 kg Zinc ion crosslinked ethylene–acrylic acid copolymer elastic ionomer 28.0 kg Oleamide 1.5 kg polyethylene wax 500.0 g

[0038] The mass ratio of the raw materials of the B masterbatch is as follows:

[0039] Decabromodiphenylethane 50.0 kg Octabromoether 10.0kg Antimony trioxide 16.5 kg Zinc borate 7.0 kg Atactic polypropylene 14.0kg PTFE powder 1.5 kg Oleamide 500.0 g polyethylene wax 500.0 g

[0040] The preparation method of A masterbatch is as follows: Weigh all raw materials according to the above mass rati...

Embodiment 3

[0043] A high-efficiency flame-retardant and antibacterial functional masterbatch for polypropylene direct injection molding, which is composed of two masterbatches, A and B, and the mass ratio of raw materials for the A masterbatch is as follows:

[0044] Silver-loaded zinc porous zirconium phosphate antibacterial agent 6.0 kg Barium sulfate 40.0 kg calcium carbonate 14.0kg Calcium ion crosslinked ethylene–acrylic acid copolymer elastic ionomer 38.0kg Zinc stearate 1.5 kg Polydimethylsiloxane 500.0 g

[0045] The mass ratio of the raw materials of the B masterbatch is as follows:

[0046] Octabromoether 30.0 kg Octabromo-S ether 30.0 kg Antimony trioxide 20.0kg Atactic polypropylene 18.0 kg PTFE powder 1.0 kg Zinc stearate 500.0 g Polydimethylsiloxane 500.0 g

[0047] The preparation method of A masterbatch is as follows: Weigh all raw materials according to the above mas...

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Abstract

The invention belongs to the technical field of plastic modification and processing, and in particular relates to a high-efficiency flame-retardant and antibacterial functional masterbatch which can be directly applied to injection molding processing of polypropylene products and a preparation method thereof; the functional masterbatch consists of two kinds of masterbatches A and B Combined, the mass percentage of A masterbatch is as follows: silver-loaded zinc inorganic antibacterial agent 6.0~10.0 wt.%, filler 50.0~70.0 wt.%, elastic ionomer 18.0~38.0wt.%, dispersant 0.5~ 1.0 wt.%, lubricant 0.5~0.1 wt.%; compared with the traditional plastic functional masterbatch, the functional masterbatch prepared by the present invention avoids the strong direct impact of the silver-loaded zinc inorganic antibacterial agent and the brominated flame retardant on the twin-screw. Under the action of shearing, the interaction between silver, zinc ions and bromide ions leads to mutual loss of modification performance, which significantly improves the modification performance of the two; the masterbatch is easy to disperse and process, and can be simply mixed with polypropylene resin according to the ratio After injection molding, and achieved excellent modification effect.

Description

technical field [0001] The invention belongs to the technical field of plastic modification and processing, and in particular relates to a high-efficiency flame-retardant and antibacterial functional masterbatch which can be directly applied to injection molding processing of polypropylene products and a preparation method thereof. Background technique [0002] Using twin-screw extruder to implement melt blending is a traditional method for plastic modification. Using the high-efficiency and excellent mixing performance of co-rotating twin-screw extruders, thermoplastics and various modified additives can be continuously melt-blended and extruded After granulation, the prepared modified special material will be used again for injection or extrusion processing to form various products. This technical route not only effectively improves the physical and mechanical properties of plastic products such as strength, toughness, stiffness, creep resistance, and flexure resistance, b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L23/12C08L27/18C08K9/12C08K3/08C08J3/22
CPCC08J3/226C08J2423/08C08J2423/12C08J2427/18C08K9/12C08K2003/0806C08K2003/0893
Inventor 李翰卿汪晓东孙艳军邱小龙蔡文鹏
Owner 江苏万纳普新材料科技有限公司
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