A non-close-packed silica ring nanoarray and its preparation method

A technology of silica and nano-arrays, which is applied in the field of non-close-packed silica ring nano-arrays and its preparation, can solve the problems of poor mechanical strength and firmness of nanoparticles, high equipment requirements, complex processes, etc., and achieve mechanical strength And the effects of high firmness, low equipment requirements, and simple preparation process

Active Publication Date: 2021-07-23
HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, SiO can be assembled by electrostatic self-assembly 2 Nanoparticles are assembled on different optical devices as solar anti-reflection coatings, but the mechanical strength and firmness of this electrostatic self-assembled nanoparticles are poor; or they can be directly deposited on silicon dioxide by electron beam etching or laser etching. Build a microarray structure on a substrate, but this process is complex, costly, and requires high equipment
In addition, it was found through investigation that SiO has not been constructed in the prior art 2 Therefore, it is urgent to provide a preparation method with simple process, low cost and low equipment requirements to prepare SiO with high mechanical strength and firmness. 2 ring nanoarray

Method used

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  • A non-close-packed silica ring nanoarray and its preparation method
  • A non-close-packed silica ring nanoarray and its preparation method
  • A non-close-packed silica ring nanoarray and its preparation method

Examples

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preparation example Construction

[0024] A method for preparing a non-close-packed silica ring nanoarray may comprise the following steps:

[0025] Step A, cleaning the quartz slices, drying the cleaned clean quartz slices, and then placing them in an ultraviolet ozone cleaner for 10-40 minutes of irradiation, so as to prepare clean quartz slices with a hydrophilic surface.

[0026] Step B, using a gas-liquid interface self-assembly method to prepare a tightly arranged single-layer polystyrene colloidal sphere array on the surface of the clean quartz sheet with a hydrophilic surface.

[0027] Step C, using the single-layer polystyrene colloidal sphere array on the quartz substrate as a template, and depositing a layer of silver film on the surface of the template by magnetron sputtering deposition method.

[0028] Step D, put the single-layer polystyrene colloidal ball array with the silver film deposited on the surface into a muffle furnace for heat treatment, set it for 170 minutes to increase from room temp...

Embodiment approach

[0031] (1) The cleaning of the quartz sheet includes: putting the quartz sheet into a cleaning container, adding acetone, alcohol and deionized water with a volume ratio of 1:1:1, covering with plastic wrap, and ultrasonic cleaning for 45 minutes; Then pour out the waste liquid in the cleaning container, and add concentrated sulfuric acid and hydrogen peroxide with a volume ratio of 3:1, and ultrasonically clean it for 30 minutes after standing for 8 hours; then pour out the waste liquid in the cleaning container, and add a volume ratio of 3:1:1 deionized water, ammonia water and hydrogen peroxide, covered with plastic wrap, ultrasonically cleaned for 30 minutes; finally washed repeatedly with deionized water to obtain a clean quartz plate after cleaning.

[0032](2) Using the gas-liquid interface self-assembly method to prepare a tightly arranged single-layer polystyrene colloidal sphere array on the surface of the clean quartz sheet with a hydrophilic surface, comprising: tak...

Embodiment 1

[0040] Such as Figure 4 As shown, a method for preparing a non-close-packed silica ring nanoarray may comprise the following steps:

[0041] Step a, put the glass piece and quartz piece into a beaker, add acetone, alcohol and deionized water with a volume ratio of 1:1:1, cover with plastic wrap, and ultrasonically clean for 45 minutes; then pour the waste liquid in the beaker and add concentrated sulfuric acid and hydrogen peroxide with a volume ratio of 3:1, and then ultrasonically clean it for 30 minutes after standing for 8 hours; pour out the waste liquid in the beaker, and add deionized water with a volume ratio of 3:1:1, Ammonia and hydrogen peroxide, covered with plastic wrap, ultrasonically cleaned for 30 minutes; finally, washed repeatedly with deionized water to obtain clean glass sheets and clean quartz sheets after cleaning. An oven is used to dry the cleaned clean glass sheet and clean quartz sheet, and then placed in an ultraviolet ozone cleaning machine for 30...

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PUM

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Abstract

The invention discloses a non-close-packed silicon dioxide ring nano-array and a preparation method thereof, comprising: cleaning the quartz sheet, drying the cleaned quartz sheet, and then placing it in an ultraviolet ozone cleaning machine for irradiation. Then, a clean quartz sheet with a hydrophilic surface was prepared; a tightly arranged array of single-layer polystyrene colloidal balls was prepared on the surface of the clean quartz sheet by using the gas-liquid interface self-assembly method; the single-layer polystyrene colloidal array on the quartz sheet The ball array is a template, and a layer of silver film is deposited on the surface of the template by magnetron sputtering deposition method; the single-layer polystyrene colloidal ball array with the silver film deposited on the surface is heat-treated to obtain a silver nanometer on the quartz substrate. Particle arrays; the silver nanoparticle arrays on the quartz substrate were soaked in nitric acid to remove the silver nanoparticles, thereby making non-close-packed silica ring nanoarrays. The invention not only has high mechanical strength and firmness of the nanometer array, but also has simple preparation process, low cost and low requirements for equipment.

Description

technical field [0001] The invention relates to the field of silicon dioxide nanometer materials, in particular to a non-close-packed silicon dioxide ring nanoarray and a preparation method thereof. Background technique [0002] In the past ten years, nanomaterials have been widely used in production and life. From the perspective of nanodevices, nanoscale volumes not only facilitate the integration with existing technologies, but also exhibit many unique and excellent new physical properties. Arranging nanoparticles in a specific way can form an ordered nanostructure array, which is one of the important solutions for constructing nanodevices. Controllable two-dimensional nanostructure arrays and micropatterns are very important for the manufacture of micro-nano optoelectronic devices, sensors and biological devices. Chips are important. [0003] SiO 2 Nanomaterials have superior optical properties, and their array structures have been widely used in the field of optics. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C23/00
CPCC03C23/00C03C23/0075
Inventor 刘广强徐望胜张鹏蔡伟平
Owner HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
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