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A kind of high dropping point anti-corrosion sealing wax for bridge cable and anchor head and preparation method thereof

A high dropping point, sealing wax technology, applied in wax coatings, coatings, anti-corrosion coatings, etc., can solve the problems of plasticizer migration, high adhesion, corrosion-resistant sealing wax oil separation, etc., to achieve enhanced adhesion and Flexibility, enhanced high temperature resistance, good strength and toughness effects

Active Publication Date: 2021-08-10
LIUZHOU OVM STRUCTURE INSPECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the vibration of the cable, the polyurethane foaming agent is easily destroyed and has a certain degree of water absorption, so that the entire anchor head component is in a humid environment for a long time; non-vulcanized sealant products are prone to plasticizer migration during use , so that its service life is shortened; anti-corrosion grease has good anti-rust performance, but the stability of anti-corrosion grease is not good, especially in summer, it is easy to separate oil, which not only weakens the protective effect, but also causes oil pollution to bridge components; anti-rust wax The antirust effect is good, but most of the antirust waxes on the market are used for ordinary steel or automobiles. This type of wax is used on bridge cables and anchor heads, and there are certain problems, such as steel under high temperature environment. The net oil content is relatively high, and it is easy to cause leakage due to oil separation; the shrinkage rate is too large, it is easy to shrink and sag during the cooling process, and it must be filled twice before it can be completely filled; the solvent-based wax is poured into the cableway pipe for a long time. The solvent contained in it cannot be volatilized and solidified, and the volume shrinkage becomes smaller after the solvent volatilizes and solidifies, so that some metal components are directly exposed to the corrosive environment
In addition, during the vibration process of the cable, the hardness of the wax is too large or the adhesion is poor, it is easy to separate it from the steel strand, forming a hole in the center of the cable, and even causing the wax to crack, and finally the expected protective effect cannot be achieved.
[0003] In order to solve the above-mentioned problems in the prior art, the invention patent with the patent publication number of CN105542490A provides a kind of anti-corrosion sealing wax suitable for bridge cable and anchor head anticorrosion and its preparation method. The anti-corrosion sealing wax is mainly composed of microcrystalline wax As a base material, it has the characteristics of low shrinkage, high adhesion, and long corrosion resistance period, but the disadvantage is that the product has poor temperature resistance, the highest dropping point is only 92 ℃, and the scope of use is limited.
In summer, the temperature in the tropics is high, the sunshine time is long, and the sun directly shines on the bridge deck and the cables. Due to the strong heat absorption and conductivity of concrete and steel, the local temperature can be as high as 90°C, which makes the corrosion-resistant sealing wax prone to decomposition at this temperature for a long time. Oil phenomenon, limited geographical range of use
In addition, due to the particularity of the construction process of the bridge cable and anchor head protection project, the wax is melted first, and then transported to the anchor head filling point several meters away with a high-pressure pump, and then poured into the pipeline several meters deep. In order to reduce the shrinkage of the wax in the technology, inorganic fillers are added, so that if the wax is heated and melted during construction and poured for a long time, the filler will sink. If the construction personnel do not stir before spraying, the quality of the product will be affected. And cause blockage to the spraying equipment; In addition, during the pouring process, the wax is easy to cool down when it is cooled, and the bubbles generated during the pouring process cannot be completely eliminated.
Wax foam floating on the surface, reducing the intended protective effect

Method used

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  • A kind of high dropping point anti-corrosion sealing wax for bridge cable and anchor head and preparation method thereof
  • A kind of high dropping point anti-corrosion sealing wax for bridge cable and anchor head and preparation method thereof

Examples

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Effect test

Embodiment 1

[0047] A kind of high dropping point anti-corrosion sealing wax for bridge cables and anchor heads and its production method Ⅰ:

[0048] The high drop point corrosion-resistant sealing wax for bridge cables and anchor heads is a mixture composed of the following components. In the mixture, the proportion of each component material is calculated as follows in parts by weight:

[0049] 50 parts by weight of oxidized polyethylene wax,

[0050] Candelilla wax 10 parts by weight,

[0051] 7 parts by weight of oleic acid,

[0052] Polyolefin resin——15 parts by weight, including 10 parts by weight of polyethylene and 5 parts by weight of polyvinyl chloride;

[0053] Compatilizer——4 parts by weight of ethylene bisoleic acid amide,

[0054] Vaseline 5 parts by weight,

[0055] Liquid rubber——12 parts by weight, including 5 parts by weight of nitrile rubber, and 7 parts by weight of butyl rubber;

[0056] Antioxidant——2,6 di-tert-butyl-p-cresol 3 parts by weight,

[0057] Defoamer...

Embodiment 2

[0063] A kind of high dropping point anti-corrosion sealing wax for bridge cables and anchor heads and its production method II:

[0064] The high drop point corrosion-resistant sealing wax for bridge cables and anchor heads is a mixture composed of the following components. In the mixture, the proportion of each component material is calculated as follows in parts by weight:

[0065] 60 parts by weight of oxidized polyethylene wax,

[0066] Candelilla wax 13 parts by weight,

[0067] 8 parts by weight of oleic acid,

[0068] Polyolefin resin—10 parts by weight of polypropylene;

[0069] Compatilizer-5 parts by weight, including 2 parts by weight of ethylene bis stearamide, 3 parts by weight of ethyl 3-ethoxy propionate;

[0070] 10 parts by weight of petroleum jelly;

[0071] Liquid rubber—7 parts by weight of EPDM;

[0072] Antioxidant -- 4 parts by weight, including 2 parts by weight of N-phenyl-a-naphthylamine, 2 parts by weight of zinc dialkyldithiophosphate;

[007...

Embodiment 3

[0079] A high drop point corrosion-resistant sealing wax for bridge cables and anchor heads and its production method III:

[0080] The high drop point corrosion-resistant sealing wax for bridge cables and anchor heads is a mixture composed of the following components. In the mixture, the proportion of each component material is calculated as follows in parts by weight:

[0081] 35 parts by weight of oxidized polyethylene wax,

[0082] Candelilla wax 19 parts by weight,

[0083] 10 parts by weight of oleic acid,

[0084] Polyolefin resin——35 parts by weight of amorphous polyalpha-olefin,

[0085] Compatilizer-7 parts by weight, including 3 parts by weight of polyvinyl alcohol, 4 parts by weight of sorbitan monooleate;

[0086] Vaseline 5 parts by weight,

[0087] Liquid rubber——20 parts by weight of styrene-butadiene rubber,

[0088] Antioxidant——Tetrakis [β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester 2 parts by weight,

[0089] Defoamer---1...

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Abstract

A high drop point corrosion-resistant sealing wax for bridge cables and anchor heads is a mixture composed of the following components. In the mixture, the content of each component material is calculated in parts by weight: 35-60 parts by weight of oxidized polyethylene wax , 8-22 parts by weight of candelilla wax, 4-12 parts by weight of oleic acid, 10-35 parts by weight of polyolefin resin, 2-7 parts by weight of compatibilizer, 5-15 parts by weight of vaseline, 3-20 parts by weight of liquid rubber 2-6 parts by weight of antioxidant, 1-5 parts by weight of defoamer, and 4-15 parts by weight of rust inhibitor. The preparation method is: put the above-mentioned components in sequence in a heating container, keep a certain temperature and stir to make it. The high-dropping point corrosion-resistant sealing wax for bridge cables and anchor heads has the characteristics of good defoaming, high dropping point, high temperature resistance, strong sealing, low shrinkage, high adhesion, good weather resistance and long corrosion resistance period; It has long-term protection for bridge anchor heads, cables and other steel products and prolongs their service life.

Description

technical field [0001] The invention relates to an anti-corrosion and anti-corrosion sealing material and a preparation method thereof, in particular to a high drop point anti-corrosion sealing wax suitable for anti-corrosion of bridge cables and anchor heads and a preparation method thereof. Background technique [0002] As the core component of the bridge, the cable is affected by wind and rain vibration, load vibration, and aging of the sealing material, and the waterproof measures are prone to failure, so that the lower cable guide and the lower anchor head are easy to enter water, resulting in metal corrosion. The most common disease, and also the most serious disease, is the main reason leading to early replacement of cables or even broken cables across bridges, which has brought huge economic losses to the society. At present, in order to solve this problem, the industry mainly pours soft or easy-to-clean anti-corrosion materials into the anchor head, such as polyuret...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D123/30C09D191/06C09D123/06C09D127/06C09D5/08C09D7/48C09D7/63C08L23/30C08L91/06C08L23/06C08L27/06C08L83/04C08K5/13
CPCC08L23/30C08L2201/08C08L2205/02C08L2205/025C08L2205/035C09D5/08C09D123/30C09D7/48C09D7/63C08L91/06C08L23/06C08L27/06C08L83/04C08K5/13
Inventor 袁友庞忠华陈竞杨立中杨赓王晓琳赵泽文韦福堂周庠天李居泽区锡祥陆绍辉
Owner LIUZHOU OVM STRUCTURE INSPECTION TECH
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