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A kind of refractory wastewater treatment process

A technology for wastewater treatment and treatment process, applied in water/sewage treatment, water/sewage multi-stage treatment, biological water/sewage treatment, etc. Larger and other problems, to achieve the effect of recycling, reducing treatment costs, efficient and stable treatment

Active Publication Date: 2022-04-19
GUANGZHOU EP ENVIROMENTAL ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the above-mentioned technical scheme, there are mainly the following disadvantages: 1. ozone is mainly realized by producing high-energy molecules such as hydroxyl radicals with OH in the printing and dyeing wastewater, but this reaction is greatly affected by the mass transfer effect of the gas-liquid phase, and the ozone in the wastewater Some macromolecular pollutants may hinder the contact of gas-liquid phase, so the treatment efficiency of this technical scheme is easily affected by the quality of wastewater; The overall removal effect is not stable, and may affect the effect of subsequent micro-electrolysis treatment; ③This technical solution requires continuous power supply to provide stable ozone input, and the system lacks a recycling energy system, resulting in increased energy consumption and treatment costs

Method used

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  • A kind of refractory wastewater treatment process
  • A kind of refractory wastewater treatment process
  • A kind of refractory wastewater treatment process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Example 1, refractory wastewater treatment system

[0046] Schematic diagram of the structure of the processing system of the present invention as follows Figure 1 Shown, it comprises a modulation cell connected sequentially through the pipeline, DBD plasma reactor 1, iron carbon microelectrolytic reactor 2, static sinking system 3, photocatalytic fuel cell system 4 and nanofiltration - reverse osmosis dual membrane system 5.

[0047] Wherein, the DBD plasma reactor is provided in the upper part of the water distribution layer, the water distribution layer is provided with a water distribution hole 101, the waste water through the water distribution layer after the water distribution hole into the middle of the plasma reaction area; the plasma reaction area is provided with a plurality of sets of high and low pressure electrode pairs separated by a separator plate, forming a plurality of plasma reaction partitions; the spacing of the high and low pressure electrode pairs i...

Embodiment 2

[0052] Example 2, refractory wastewater treatment process

[0053] Follow the above system Figure 2 The process processes the wastewater with the following steps:

[0054] S1, add sulfuric acid to the wastewater to adjust the pH to 4;

[0055] S2, the wastewater using low-temperature plasma method for treatment, DBD plasma reactor working atmosphere for air, inlet air flow control of 2L / min, discharge voltage control of 20kv, treatment 30min;

[0056] S3, the effluent of process S2 for iron carbon microelectrolysis reaction, the iron-carbon microelectrolysis reactor in the iron-carbon micro-electrolysis reactor weight ratio of iron-based materials and carbon-based materials is 4:1;

[0057] S4, the effluent of process S3 is quietly treated, and the iron-carbon filler in the effluent is separated;

[0058] S5, the effluent of process S4 is passed into the photocatalytic fuel cell system for treatment, and the organic pollutants in the wastewater are degraded as raw materials for p...

Embodiment 3

[0060] Example 3, refractory wastewater treatment process

[0061] The difference between Example THREE and Embodiment II is that step S1 adjusts the pH to 7, and the remaining parameters are the same as Example TWO.

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Abstract

The invention discloses a treatment process for refractory wastewater. The invention creatively adopts a combination process of low-temperature plasma and iron-carbon micro-electrolysis technology, and strengthens the subsequent micro-electrolysis treatment effect through the treatment of low-temperature plasma. The two produce a synergistic increase. Combined with photocatalytic battery system treatment, a variety of organic pollutants in refractory wastewater can be effectively degraded, and the treatment is efficient and stable. At the same time, energy recycling is realized, which offsets the energy consumption of the previous process, and the whole system is more energy-saving. , low operating cost. The treatment process has a low dosage of chemical agents. In the whole system, except for some refractory parts before low-temperature plasma treatment that need to adjust the pH of the wastewater, other process stages do not need additional treatment chemicals, which reduces the treatment cost and does not produce secondary pollution. , more environmentally friendly.

Description

Technical field [0001] The present invention belongs to the field of wastewater treatment technology, specifically relates to a refractory wastewater treatment process. Background [0002] Refractory wastewater mainly contains a large number of organic pollutants with low biochemical degree, difficult to biodegrade, and half-life of 3 to 6 months, such as polychlorinated biphenyls, polycyclic aromatic hydrocarbons, halogenated hydrocarbons, phenols, anilines and nitrobenzenes, dyes, surfactants, polymer monomers, etc. [0003] At present, the refractory wastewater treatment process mainly includes physical method, chemical method and biological method. Among them, physical methods include adsorption, membrane separation, coagulation, sand filtration and other technologies, and chemical methods mainly include microelectrolysis, chemical precipitation, redox, persulfate and Fenton. Biological methods include aerobic-anaerobic methods, membrane bioreactors (MBRs), and microbial imm...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10C02F9/14C02F101/30
CPCC02F9/00C02F1/66C02F1/30C02F1/46104C02F2001/007C02F1/441C02F1/442C02F1/42C02F1/04C02F1/4693C02F3/1268C02F2101/30Y02A20/131
Inventor 周文栋陈益成谢永新李锐敬徐波干仕伟曹姝文杨炜雯刘晓永许嘉辉叶冠生赵晓东何世幸鲁坚伟
Owner GUANGZHOU EP ENVIROMENTAL ENG