A kind of antiglare cured film and preparation method thereof

A hardened film and anti-glare technology, which is applied in coatings, polyester coatings, polyurea/polyurethane coatings, etc., can solve problems that affect product order and appearance, cleaning work, and solar power generation effects, and achieve excellent anti-glare properties , avoid shrinkage cavity, good anti-glare performance and surface texture effect

Active Publication Date: 2022-05-03
HEFEI LUCKY SCI & TECH IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the advancement of production technology, people have higher and higher requirements for the performance and quality of anti-glare hardened film products. In addition to the basic performance requirements, some special properties are also required for the outermost hardened film, such as photovoltaic The anti-glare hardened film for power generation paper in the industry needs to have high light transmittance to better receive solar radiation, high hardness and high wear resistance to better protect devices, and anti-adhesive and release properties on the surface of the hardened film. There are also higher requirements to prevent dust, advertising stickers and other adhesive products from adhering to the film surface, which will affect the ability of the product to receive solar radiation, thereby affecting the effect of solar power generation
And for the anti-glare hardened film used on the outermost layer, if there are foreign objects on the surface of the product or other adhesive products are maliciously pasted by others, it will seriously affect the neatness and appearance of the product, and have a great impact on the follow-up cleaning work, making it difficult to satisfy downstream customers for a long time. Customer's requirements

Method used

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  • A kind of antiglare cured film and preparation method thereof
  • A kind of antiglare cured film and preparation method thereof
  • A kind of antiglare cured film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Hardened layer coating solution preparation: 20g modified bisphenol A epoxy acrylate (Changxing Technology, trade name: 6231A-80), 3g polyether modified dimethyl siloxane (Bick Chemical Company, trade name: BYK-3550), 1g 1-hydroxycyclohexyl phenyl ketone (Double Bond Chemical Co., Ltd., trade name: Doublecure 184), 6g nano silicon dioxide (Nanjing Tianxing New Material Co., Ltd., trade name: TDS-A2 ), 70g butanone was placed in a stirring pot, and stirred evenly to obtain a hardened layer coating liquid.

[0049] Anti-glare hardening solution preparation: 36g aliphatic polyurethane hexaacrylate (Changxing Technology, trade name: 6149-100), 20g tridecyl acrylate (Sartomer, trade name: SR489D), 30g silica particles ( Evonik, trade name: ACEMATT3600) was placed in the container, and after stirring at a high speed, 10 g of organomodified polysiloxane (Tiger Auxiliaries, trade name: Tech-2037D), 4 g of 2,4,6-trimethylbenzene Formyl-diphenylphosphine oxide (Double Bond Chemi...

Embodiment 2

[0055] Hardened layer coating solution preparation: 29g modified hexafunctional epoxy acrylate (Changxing Technology, trade name: DR-G908), 0.05g OH group-containing polyether modified silicone (Bick Chemical Company, trade name: BYK -377), 1.55g 2-hydroxyl-2-methyl-1-phenyl-1-acetone (Double Bond Chemical Co., Ltd., trade name: Doublecure 173), 20g nano silicon dioxide (Nanjing Tianxing New Material Co., Ltd. company, trade name: TDS-C10), 49.4 methyl isobutyl ketone is placed in a stirring pot, and stirred evenly to obtain a hardened layer coating liquid.

[0056] Anti-glare hardening solution preparation: 45g aliphatic polyurethane acrylate (Double Bond Chemical, trade name: Doublemer588), 37g aliphatic polyurethane acrylate (Haohui New Materials, trade name: CR90442), 2g PMMA particles (Soken Chemical, trade name Name: MR-10HG) is placed in the container, after stirring at a high speed, add 6g polyether modified silicone containing OH groups (Byk Chemical Company, trade na...

Embodiment 3

[0062] Hardened layer coating solution preparation: 35g fatty acid modified polyester acrylate (Evergreen Technology, trade name: 6313-100), 1.5g polyether modified silicone (Byk Chemical Company, trade name: BYK-325), 1.5 g of 1-hydroxycyclohexyl phenyl ketone (Double Bond Chemical Co., Ltd., trade name: Doublecure 184), 62 g of propylene glycol monomethyl ether were placed in a stirring pot, and stirred evenly to prepare a hardened layer coating liquid.

[0063] Antiglare hardening solution preparation: 35g aliphatic hexaacrylate (Double Bond Chemicals, trade name: Doublecure 571), 11g cyclohexane dimethanol diacrylate (Sartomer, trade name: CD406), 50g PMMA particles (Comprehensive Research Chemical, trade name: MR-7GC4) is placed in the container, after high-speed stirring is uniform, add 0.5g organomodified polysiloxane (Tiger Auxiliaries, trade name: Tech-2750), 3.5g 2-hydroxyl-2-formazan Base-1-phenyl-1-acetone (Double Bond Chemical Co., Ltd., trade name: Doublecure 173...

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Abstract

The invention relates to an anti-glare hardened film and a preparation method thereof. The hardened film comprises a silicone oil layer, an anti-glare hardened layer, a base material layer, and a hardened layer from top to bottom, wherein the thickness D1 of the silicone oil layer is the same as the anti-glare hardened layer. The average peak-to-valley depth Rz of the hardened layer is Rz-D1≥0.2 μm, and the water contact angle of the anti-glare hardened layer and the water contact angle of the silicone oil layer are 20°≤water contact angle of the silicone oil layer-water contact angle of the anti-glare hardened layer≤50 °. The hardened surface of the present invention is coated with a high-hardness anti-glare hardening solution and a silicone oil layer, so that the coating has excellent adhesive performance, and the coating has excellent anti-glare properties, high hardness, high wear resistance, and low release The characteristics of high release force can ensure that the product has good visual effect and scratch resistance, and at the same time, low release force can prevent others from arbitrarily pasting foreign objects on the film surface. The invention avoids the scratches caused by coating and winding, reduces the disadvantages such as scratches caused in the subsequent transportation and storage process, and better improves the apparent quality of the product.

Description

technical field [0001] The invention relates to the technical field of thin films, in particular to an antiglare cured film. Background technique [0002] Hardened film is a high-performance film product obtained by surface hardening treatment on an ordinary optical film support. This product has good optical properties and excellent wear resistance and scratch resistance. It is widely used in liquid crystal displays, touch panels, mobile phones, computers, handwriting tablets and industrial displays, and can also be used in protective films and other industries. At present, there are many kinds of hardened film products on the market. The common ones are transparent hardened film, anti-glare hardened film, Newton ring placed hardened film, anti-fouling and anti-fingerprint hardened film, anti-blue light hardened film, anti-fog hardened film, anti-static hardened film or with Other hardened film products with special functions. The anti-glare hardened film currently on the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/04C08J7/046C09D183/07C09D183/05C09D133/04C09D175/14C09D167/06C09D163/10C09D7/61C09D4/02C09D4/06C08L67/02C08L33/12
CPCC08J7/042C09D183/04C09D133/04C09D175/14C09D163/10C09D167/06C09D7/61C09D4/06C08J2367/02C08J2333/12C08J2483/07C08J2483/05C08J2433/04C08J2463/10C08J2467/06C08J2475/14C08K2201/011C08L2205/025C08L2205/03C08L83/04C08L83/12C08K3/36C08L75/14C08L33/12
Inventor 徐倩倩韩捷胡鑫万金龙王巧刘玉磊李恒
Owner HEFEI LUCKY SCI & TECH IND
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