Y-doped Mg alloy and preparation method thereof

A technology of magnesium alloy and alloy powder, applied in the field of yttrium-doped magnesium alloy and its preparation, can solve the problems of stress corrosion cracking, low strength and ductility, affecting the application effect and service life of magnesium-lithium alloy, etc. The effect of body sticking cans

Inactive Publication Date: 2020-05-22
QINGHAI UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Because the conventional powder metallurgy method is affected by its complex process, high cost or poor quality of the billet, the powder metallurgy process system is not perfect, so in order to obtain high-performance magnesium-yttrium alloys, it is necessary to optimize the powder metallurgy process of magnesium-yttrium alloys. technology for systematic research
[0004] (2) It is difficult to have both low-density and high-strength properties of magnesium alloys: the strength and ductility of Mg-Zn-Zr alloys are low, and alloying elements are generally added to increase the strength of the alloy, but this method is in While improving the strength, it is often at the expense of the excellent plasticity and toughness of the alloy
[0005] (3) The tension/compression yield symmetry of magnesium yttrium alloy is poor: general magnesium alloy is used as a structural material, and during use, high tensile yield strength and low compressive yield strength limit the general application of magnesium yttrium alloy
[0006] (4) Poor corrosion resistance of magnesium yttrium all

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  • Y-doped Mg alloy and preparation method thereof
  • Y-doped Mg alloy and preparation method thereof
  • Y-doped Mg alloy and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0043] Magnesium alloy doped with yttrium, composed of Mg, Zn, Zr and Y; the mass of each component in 100g magnesium alloy is Zn: 4.9g; Zr: 0.16g; Y: 2.9g; the balance is Mg and unavoidable impurities .

[0044] Preparation:

[0045] (1) Preparation of alloy powder: first weigh 97.1gMg-4.9wt.%Zn-0.16wt.%Zr powder and 2.9gY powder (purity is 99.9%, nano-scale particle size) into a mechanical ball mill jar, then add 0.05g ethanol , then add 1g of zinc stearate, evacuate to a vacuum of 1Pa, then pass in argon for 10s, add 2kg of stainless steel balls with a particle size of 5mm, then adjust the revolution speed to 150r / min, first rotate forward for 15min, and then stop for 20min , then reversed for 15 minutes, paused for 20 minutes, and circulated ball milled for 10 hours to obtain alloy powder;

[0046] (2) Sintering: Use a vacuum hot-pressing sintering furnace for high-temperature pressureless sintering. First, put the alloy powder obtained in step (1) into the mold, then in...

Embodiment 2

[0049] Magnesium alloy doped with yttrium, composed of Mg, Zn, Zr and Y; the mass of each component in 100g magnesium alloy is Zn: 5.5g; Zr: 0.19g; Y: 3.2g; the balance is Mg and unavoidable impurities .

[0050] Preparation:

[0051] (1) Preparation of alloy powder: first weigh 96.8gMg-5.5wt.%Zn-0.19wt.%Zr powder and 3.2gY powder (purity is 99.9%, nano-scale particle size) into a mechanical ball mill jar, then add 0.15g ethanol , then add 2g of zinc stearate, vacuumize to a vacuum degree of 2Pa, then pass in argon for 15s, add 2kg of stainless steel balls with a particle size of 8mm, then adjust the revolution speed to 260r / min, first rotate forward for 20min, and then stop for 30min , then reversed for 20 minutes, paused for 30 minutes, and circulated ball milled for 14 hours to obtain alloy powder;

[0052] (2) Sintering: Use a vacuum hot-pressing sintering furnace for high-temperature pressureless sintering. First, put the alloy powder obtained in step (1) into the mold,...

Embodiment 3

[0055] The magnesium alloy doped with yttrium is composed of Mg, Zn, Zr and Y; the mass of each component in 100g magnesium alloy is Zn: 5.1g; Zr: 0.18g; Y: 3g; the balance is Mg and unavoidable impurities.

[0056] Preparation:

[0057] (1) Preparation of alloy powder: first weigh 97gMg-5.1wt.%Zn-0.18wt.%Zr powder and 3gY powder (purity is 99.9%, nano-scale particle size) and put it into a mechanical ball mill jar, then add 0.1g ethanol, and then Add 2g of zinc stearate, evacuate to a vacuum degree of 1Pa, then pass in argon gas for 12s, add 2kg of stainless steel balls with a particle size of 10mm, then adjust the revolution speed to 200r / min, first rotate forward for 20min, pause for 25min, and then Reverse for 20 minutes, stop for 25 minutes, and circulate the ball mill for 12 hours to obtain alloy powder;

[0058] (2) Sintering: Use a vacuum hot-pressing sintering furnace for high-temperature pressureless sintering. First, put the alloy powder obtained in step (1) into t...

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Abstract

The invention discloses a Y-doped Mg alloy. The Y-doped Mg alloy is composed of Mg, Zn, Zr and Y and comprises, by mass, 4.9-5.5% of Zn, 0.16-0.19% of Zr, 2.9-3.2% of Y, and the balance Mg and inevitable impurities. A preparation method of the Y-doped Mg alloy comprises the steps of (1) preparation of alloy powder, specifically, adding ethyl alcohol to Mg-Zn-Zr powder and Y powder, adding zinc stearate, conducting vacuum pumping, and conducting ball milling to obtain the alloy powder; (2) sintering, specifically, feeding the alloy powder into a vacuum hot pressing sintering furnace, and conducting vacuum pumping, heating sintering and cooling to obtain an alloy billet; and (3) hot extrusion, specifically, conducting heat preservation, feeding the alloy billet into an extrusion die for extrusion and then obtaining the Y-doped Mg alloy. According to the Y-doped Mg alloy and the preparation method thereof, the rare earth element Y is subjected to solid solution to go into a Mg base body to promote formation of an alloy double-peak crystal structure, grain refinement, generation of high-melting-point hard phases and the like. On the premise of ensuring the strength, the toughness and plastic formability of the Mg alloy are improved, and a certain reference basis is provided for actual application of the Y-doped Mg alloy.

Description

technical field [0001] The invention relates to the technical field of alloy smelting, in particular to a magnesium alloy doped with yttrium and a preparation method thereof. Background technique [0002] Only by developing and applying lightweight and high-strength materials to realize the lightweight of industrial fields, aerospace and automobile manufacturing industries can we further realize the social needs of green environmental protection, energy saving and emission reduction. The Mg-Y alloy with light weight and high strength can significantly reduce its weight when used as a structural part, but the existing Mg-Y alloys are not widely used in the industrial field because the alloy itself has some defects: [0003] (1) Powder metallurgy process and technology: Magnesium is a metal element with very active chemical properties. When the temperature reaches a certain value, it can be combined with O 2 Chemical reactions occur, and even explosions may occur, so it is ve...

Claims

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Application Information

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IPC IPC(8): C22C23/04C22C1/04B22F9/04B22F3/10B22F3/20
CPCB22F3/1007B22F3/20B22F9/04B22F2003/208B22F2009/041B22F2009/042B22F2009/043B22F2998/10C22C1/0408C22C23/04
Inventor 王金辉赵磊张磊朱云鹏
Owner QINGHAI UNIVERSITY
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