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A kind of perovskite quantum dot solar cell and preparation method thereof

A technology of solar cells and quantum dots, applied in the field of solar cells, can solve the problems of inability to completely remove long-chain insulating ligands, inability to completely remove long-chain ligands, humidity and temperature sensitivity, etc., so as to improve photoelectric conversion efficiency and promote electric charge. The effect of transmitting and maintaining stability

Active Publication Date: 2022-05-17
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CsPbI prepared by precursor method 3 Polycrystalline thin film solar cells compared to CsPbI 3 Quantum dot solar cells have more advantages in open-circuit voltage, but have obvious disadvantages in short-circuit current. This is because the long-chain insulating ligands cannot be completely removed in the traditional ligand treatment process, resulting in poor charge transport performance. Difference
[0006] At present, reports on perovskite quantum dot solar cells are still very rare, mainly because perovskite quantum dots are sensitive to humidity and temperature during the synthesis process, the repeatability is relatively poor, and the preparation process is relatively complicated.
In the process of processing the light-absorbing layer of perovskite quantum dots, the long-chain ligands cannot be completely removed, resulting in a large number of long-chain ligands still existing in the light-absorbing layer, which greatly affects its transmission performance and makes its short-circuit current density Much lower than the corresponding polycrystalline thin film device

Method used

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  • A kind of perovskite quantum dot solar cell and preparation method thereof
  • A kind of perovskite quantum dot solar cell and preparation method thereof
  • A kind of perovskite quantum dot solar cell and preparation method thereof

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Embodiment 1

[0031] This embodiment provides a kind of perovskite quantum dot solar cell, the structure is as follows figure 1 As shown, an electron transport layer 2, a perovskite quantum dot light-absorbing layer 3, a hole transport layer 4 and a metal electrode 5 are sequentially prepared on a conductive glass substrate 1; the specific steps of preparation are as follows:

[0032] Step 1: Use detergent, deionized water, acetone and isopropanol to ultrasonically wash the FTO conductive substrate 1 in sequence; prepare a titanium oxide film with a thickness of 40 nm on the cleaned FTO by chemical bath deposition, and obtain Electron transport layer 2, and annealed at 200°C for 30 minutes;

[0033] Step 2: FTO / TiO 2 Substrate is transferred in the glove box, and the atmosphere of glove box is dry air; The CsPbI of 70mg / mL 3 Quantum dots spin-coated in n-octane solution on FTO / TiO 2 On the substrate, the spin-coating speed is 2000rpm, and then the prepared CsPbI 3 The quantum dot film i...

Embodiment 2

[0038] This embodiment provides a kind of perovskite quantum dot solar cell, the structure is as follows figure 1 As shown, the preparation of the battery includes the following steps: sequentially preparing an electron transport layer 2 , a perovskite quantum dot light-absorbing layer 3 , a hole transport layer 4 and a metal electrode 5 on a conductive glass substrate 1 . Its preparation method and concrete steps are as follows:

[0039] Step 1: Use detergent, deionized water, acetone and isopropanol to ultrasonically wash the FTO conductive substrate 1 in sequence; prepare a titanium oxide film with a thickness of 40 nm on the cleaned FTO by chemical bath deposition, and obtain Electron transport layer 2, and annealed at 200°C for 30 minutes;

[0040] Step 2: FTO / TiO 2 Substrate is transferred in the glove box, and the atmosphere of glove box is dry air; The CsPbI of 70mg / mL 3 Quantum dots spin-coated in n-octane solution on FTO / TiO 2 On the substrate, the spin-coating s...

Embodiment 3

[0045] This embodiment provides a kind of perovskite quantum dot solar cell, the structure is as follows figure 1 As shown, the preparation of the battery includes the following steps: sequentially preparing an electron transport layer 2 , a perovskite quantum dot light-absorbing layer 3 , a hole transport layer 4 and a metal electrode 5 on a conductive glass substrate 1 . Its preparation method and concrete steps are as follows:

[0046] Step 1: Use detergent, deionized water, acetone and isopropanol to ultrasonically wash the FTO conductive substrate 1 in sequence; prepare a titanium oxide film with a thickness of 40 nm on the cleaned FTO by chemical bath deposition, and obtain Electron transport layer 2, and annealed at 200°C for 30 minutes;

[0047] Step 2: FTO / TiO 2 Substrate is transferred in the glove box, and the atmosphere of glove box is dry air; The CsPbI of 70mg / mL 3 Quantum dots spin-coated in n-octane solution on FTO / TiO 2 On the substrate, the spin-coating s...

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Abstract

The invention relates to a perovskite quantum dot solar cell and a preparation method thereof. Organic amines are used to treat the light-absorbing layer of perovskite quantum dot solar cells to obtain high-performance perovskite quantum dot solar cells. The material of the light-absorbing layer of the perovskite quantum dot solar cell provided by the invention is ABX 3 , A is cesium Cs + , FA + ,CH(NH 2 ) 2 + or methylamine MA + ,CH 3 NH 3 + , B is Pb 2+ or Sn 2+ , X is Cl ‑ ,Br ‑ or I ‑ Quantum dots were treated with organic amines. The invention utilizes organic amines to treat the light-absorbing layer of perovskite quantum dots, effectively removes the long-chain insulating ligands in the light-absorbing layer, thereby increasing the charge transport performance of the light-absorbing layer, reducing the charge recombination effect of the light-absorbing layer, thereby improving the performance of the battery. photoelectric conversion efficiency. The perovskite quantum dot battery provided by the invention has the characteristics of excellent efficiency, good stability, easy preparation and the like.

Description

technical field [0001] The invention belongs to the field of solar cells, and in particular relates to a method for improving the performance of perovskite quantum dot solar cells by utilizing organic amines and the solar cells thereof. Background technique [0002] Metal halide perovskite materials have the advantages of high light absorption coefficient, low exciton binding energy, bipolar transport effect, and micron-scale diffusion length. In the past ten years, the photoelectric conversion efficiency has increased rapidly from 3.9% at the beginning to 25.2%, which has attracted widespread attention. In addition, compared with the crystalline silicon solar cells that have been commercially used at present, the perovskite solar cells can be prepared by the whole solution method, the process is simple and the battery cost is low. [0003] However, the light-absorbing layer materials used in high-efficiency perovskite solar cells are all organic or organic-inorganic hybrid...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/42H01L51/44H01L51/46H01L51/48
CPCH10K71/00H10K71/12H10K85/00H10K30/10H10K30/80Y02P70/50
Inventor 马万里王耀袁建宇
Owner SUZHOU UNIV