Method for preparing branched polyhydroxyethyl methacrylate by inverse emulsion polymerization at room temperature
A technology of branched poly(hydroxyethyl methacrylate) and inverse emulsion polymerization, which is applied in chemical instruments and methods, preparation of organic compounds, preparation of carboxylic acid amides, etc. Long time and other problems, to achieve the effect of simple and stable reaction system, high monomer conversion rate and short reaction time
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Embodiment 1
[0025] Hydroxyethyl methacrylate (10.4112g, 0.0800mol) was added into water (31.2336g, 300wt% hydroxyethyl methacrylate) to dissolve, and an aqueous solution of hydroxyethyl methacrylate (25wt%) was configured. The aqueous solution of hydroxyethyl methacrylate was added to a mixture of toluene (41.6448g, 400wt% hydroxyethyl methacrylate), Span85 (2.0822g, 5wt% toluene), Tween80 (2.0822g, 5wt% toluene), reducing agent single MPAEMA (0.2320g, 0.0010mol) in a reaction flask, stirred evenly and evacuated oxygen, then added the oxidant BPO (0.2422g, 0.0010mol), placed in a water bath at 25°C for 8 hours, measured methacrylic acid The conversion rate of hydroxyethyl ester was 94.3%. Demulsify with tetrahydrofuran, wash with water three times and then dry, then purify three times and then dry to obtain polymer. The polymer is analyzed by dynamic and static light scattering and Ubbelohde viscometer, the results are as follows: absolute weight average molecular weight M w.MALLS =2442...
Embodiment 2
[0030] Hydroxyethyl methacrylate (13.0140g, 0.1000mol) was added into water (39.0420g, 300wt% hydroxyethyl methacrylate) to dissolve, and an aqueous solution of hydroxyethyl methacrylate (25wt%) was configured. The aqueous solution of hydroxyethyl methacrylate was added to a mixture of toluene (52.0560g, 400wt% hydroxyethyl methacrylate), Span85 (2.6028g, 5wt% toluene), Tween80 (2.6028g, 5wt% toluene), reducing agent single MPAEMA (0.2320g, 0.0010mol) in a reaction flask, stirred evenly and evacuated oxygen, then added the oxidant BPO (0.2422g, 0.0010mol), placed in a water bath at 25°C for 8 hours, measured methacrylic acid The conversion rate of hydroxyethyl ester was 93.7%. Demulsify with tetrahydrofuran, wash with water three times and then dry, then purify three times and then dry to obtain polymer. The polymer is analyzed by dynamic and static light scattering and Ubbelohde viscometer, the results are as follows: absolute weight average molecular weight M w.MALLS =2083...
Embodiment 3
[0033]Hydroxyethyl methacrylate (15.6168g, 0.1200mol) was added into water (46.8504g, 300wt% hydroxyethyl methacrylate) to dissolve, and an aqueous solution of hydroxyethyl methacrylate (25wt%) was configured. The aqueous solution of hydroxyethyl methacrylate was added to a mixture of toluene (62.4672g, 400wt% hydroxyethyl methacrylate), Span85 (3.1234g, 5wt% toluene), Tween80 (3.1234g, 5wt% toluene), reducing agent single MPAEMA (0.2320g, 0.0010mol) in a reaction flask, stirred evenly and evacuated oxygen, then added the oxidant BPO (0.2422g, 0.0010mol), placed in a water bath at 25°C for 8 hours, measured methacrylic acid The conversion rate of hydroxyethyl ester was 94.5%. Demulsify with tetrahydrofuran, wash with water three times and then dry, then purify three times and then dry to obtain polymer. The polymer is analyzed by dynamic and static light scattering and Ubbelohde viscometer, the results are as follows: absolute weight average molecular weight M w.MALLS =16710...
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