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A kind of nicraly high temperature sintering zta particle reinforced steel matrix composite material and preparation method thereof

A composite material and particle reinforced technology, applied in metal material coating technology, metal processing equipment, transportation and packaging, etc., can solve the problem of poor thermal shock resistance of composite materials, affecting the large-scale application of wear parts, low bonding strength problems, to achieve the effect of enhancing interface bonding, improving room temperature and high temperature strength, and improving thermal stability

Active Publication Date: 2022-02-11
XI AN JIAOTONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the research on WC particle-reinforced iron-based composite materials is relatively extensive, mainly because of the high hardness of WC particles, which can endow the composite material with excellent wear resistance, and its good wettability with high-temperature molten iron is helpful for the composite material. preparation, but the application of WC reinforced ceramics has the following fatal problems: firstly, the price of WC is expensive, and the linear expansion coefficient of WC (3.8×10 -6 K -1 ) and steel materials (9.2~16.9×10 -6 K -1 ) has a large difference, the interface between the particles and the iron matrix is ​​prone to cracks due to thermal stress during the preparation process and heat treatment of the composite material, and the thermal shock resistance of the composite material is poor
Due to the poor binding between ZTA particles and iron base, the high chromium cast iron prepared by casting infiltration method is simply mechanically combined with ZTA, and the bonding strength is low, which seriously affects the wear-resistant parts under harsh actual working conditions. Scale application

Method used

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  • A kind of nicraly high temperature sintering zta particle reinforced steel matrix composite material and preparation method thereof
  • A kind of nicraly high temperature sintering zta particle reinforced steel matrix composite material and preparation method thereof

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preparation example Construction

[0035] A method for preparing NiCrAlY high-temperature sintered ZTA particle-reinforced steel-based composite material of the present invention comprises the following steps:

[0036] S1. After drying, ZTA and SiO with a particle size of 4.7-5.5 mm 2Put the particles into a ball mill for low-speed ball milling. The ball milling speed is 75-200r / min, and the ball-milling time is 20-40min, so that the surface of the ZTA particles is slightly roughened. Filter the ZTA particles with a 10-40 mesh screen and wash them with alcohol;

[0037] Before the ball milling treatment, the ZTA particles are soaked in acetone for 20-35 minutes, pickled, then cleaned with acetone by ultrasonic wave for 10-15 minutes, rinsed with deionized water, and dried in a drying oven.

[0038] S2, wet mixing NiCrAlY powder and absolute ethanol to obtain mixed powder The mass ratio of NiCrAlY powder and absolute ethanol is (16~20):1, and the binder is made of boric acid and SiO 2 The powder is mixed accord...

Embodiment 1

[0046] 1) First, soak ZTA in acetone for 20 minutes, pickle the ZTA particles, then clean them with acetone for 10 minutes by ultrasonic waves, wash them with deionized water, and dry the treated ZTA particles in a vacuum drying oven;

[0047] 2) Secondly, the dried ZTA and 4.7mm SiO 2 Put the small particles into a 75r / min planetary ball mill for 20 minutes of low-speed ball milling, and then filter the ZTA particles with a 10-mesh sieve;

[0048] 3) Subsequently, wet mix NiCrAlY powder with absolute ethanol to obtain mixed powder. The mass ratio of NiCrAlY powder to absolute ethanol is 16:1, and the binder is made of boric acid and SiO 2 The powder is mixed at a mass ratio of 1:8, 4ml of binder is added to every 100g of ZTA mixture, the mass percentage of NiCrAlY powder and ZTA particles is 15%, the mixed ZTA particles are poured into a honeycomb mold and dried in vacuum

[0049] 4) Heating the honeycomb mold in a low-temperature heat treatment furnace for curing and shapin...

Embodiment 2

[0054] 1) First, soak ZTA in acetone for 25 minutes, pickle the ZTA particles, then clean them with acetone for 10 minutes by ultrasonic waves, wash them with deionized water, and dry the treated ZTA particles in a vacuum drying oven;

[0055] 2) Secondly, the dried ZTA and 4.8mm SiO 2 Put the small particles into a 100r / min planetary ball mill for 20 minutes of low-speed ball milling, and then filter the ZTA particles with a 25-mesh sieve;

[0056] 3) Subsequently, wet mix NiCrAlY powder with absolute ethanol to obtain mixed powder. The mass ratio of NiCrAlY powder to absolute ethanol is 17:1, and the binder is made of boric acid and SiO 2 The powder is mixed at a mass ratio of 1:8, 4.5ml of binder is added to every 100g of ZTA mixture, the mass percentage of NiCrAlY powder and ZTA particles is 20%, the mixed ZTA particles are poured into a honeycomb mold and then vacuum-baked Dry

[0057] 4) Heat the honeycomb mold in a low-temperature heat treatment furnace to cure and sh...

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Abstract

The invention discloses a NiCrAlY high-temperature sintered ZTA particle-reinforced iron-based composite material and a preparation method thereof. The surface of the ZTA particle is micro-roughened, and the thermal stability of the ceramic coating is improved by adding an active element Y, and Cr and Al are resistant to O elements. The adsorption capacity can greatly improve the wettability of Ni and ceramic particles, so that the interface bonding is transformed from simple mechanical bonding to metallurgical bonding, with high bonding and impact strength, which meets the working conditions under high load conditions. Binder is finalized and dried to obtain a prefabricated body with a honeycomb structure, and then the honeycomb prefabricated body is heat-treated to improve its bonding strength; it is put into a sand box to cast molten metal, and after cooling, a ZTA reinforcement with high wear resistance is obtained Steel matrix composites. The wear-resistant composite material prepared by adopting the technology of the invention not only has high impact and wear resistance, but also ensures service safety under harsh working conditions.

Description

technical field [0001] The invention belongs to the technical field of preparation of wear-resistant materials, and in particular relates to a NiCrAlY high-temperature sintered ZTA particle-reinforced iron-based composite material and a preparation method thereof. Background technique [0002] Large-scale composite materials are necessary equipment for crushing materials such as minerals and building materials in mining, metallurgy, cement, electric power and other industries, and composite materials are the most consuming wear parts in these devices. Only in the cement and electric power industries, the annual consumption of large-scale composite materials in my country is as high as 800,000 tons, causing huge economic losses. At present, due to the poor performance stability, wear resistance and short service life of domestic large-scale composite materials, it has become a key factor restricting the crushing efficiency in mines, so most of the domestic large-scale composi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C33/02B22F3/11C23C14/18C23C14/32B22D23/04
CPCC22C33/0242B22F3/11C23C14/18C23C14/325B22D23/04B22F1/17
Inventor 高义民亦雨奇李烨飞李聪李博赵四勇牛瑞霞
Owner XI AN JIAOTONG UNIV
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