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Preparation method of regenerated denitration catalyst by using aged vanadium-based catalyst and rare earth

A denitration catalyst and catalyst technology, applied in physical/chemical process catalysts, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of vanadium-based catalysts, such as the use effect and service life of difficult catalysts , to reduce the risk of environmental pollution, high activity, long life effect

Pending Publication Date: 2021-02-19
XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to overcome the deficiencies of the above-mentioned prior art, the object of the present invention is to provide a method for preparing a denitrification catalyst regenerated from an aging vanadium-based catalyst and rare earth, thereby solving the problem of difficult disposal of the vanadium-based catalyst after it is discarded and the use effect of the catalyst after regeneration. The problem of longevity

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Inject 100 parts by mass of deionized water into the reaction kettle, turn on stirring and temperature control until the water temperature reaches 30 ° C, add 0.01 g of alkaline water and stir evenly; at this temperature, and under stirring conditions, add 0.1 g of citric acid to the 10ml of silica sol was stirred evenly; then 8g of cerium nitrate and 2g of lanthanum nitrate were added in sequence, and stirred evenly; then 0.1g of sodium dodecyl sulfonate and 50g of aged vanadium-based catalyst nanopowder were added, and the mixture was stirred evenly; then 5g of cordierite was added and stirred evenly ; Add 20g of titanium dioxide and stir evenly; then add 10g of aged vanadium-based catalyst nano-powder to obtain a uniformly stirred slurry;

[0030] Natural aging in the reactor for 1 hour;

[0031] The aged slurry is continuously heated and stirred in the evaporation pond to evaporate the liquid until the slurry is agglomerated and the surface is cracked to obtain a dr...

Embodiment 2

[0034] Inject 100 parts by mass of deionized water into the reaction kettle, start stirring and temperature control until the water temperature reaches 40 ° C, add 0.01 g of ammonia water and stir evenly; at this temperature, and under stirring conditions, 0.01 g of nitric acid, 5 g of nitric acid are added to the reaction kettle. The silicon powder was stirred evenly; then 9g of cerium nitrate and 3g of lanthanum nitrate were added in sequence, and the mixture was evenly stirred; then 0.1g of sodium dodecyl sulfonate and 60g of aged vanadium-based catalyst nano-powder were added, and the mixture was stirred evenly; 5g of clay was added and the mixture was evenly stirred; Add 20g of titanium dioxide and stir evenly; then add 20g of aged vanadium-based catalyst nano-powder to obtain a uniformly stirred slurry;

[0035] Natural aging in the reactor for 2 hours;

[0036] The aged slurry is continuously heated and stirred in the evaporation pond to evaporate the liquid until the s...

Embodiment 3

[0039] Inject 100 parts by mass of deionized water into the reaction kettle, start stirring and temperature control until the water temperature reaches 40 ° C, add 0.02 g of ammonia water and stir evenly; at this temperature, and under stirring conditions, add 0.01 g of nitric acid, 5 g of nitric acid to the reaction kettle The silicon powder was stirred evenly; 11g of cerium carbonate and 4g of lanthanum carbonate were added in sequence, and the mixture was stirred evenly; then 0.5g of sodium dodecyl sulfonate and 70g of aged vanadium-based catalyst nanopowder were added, and the mixture was stirred evenly; 5g of clay was added and the mixture was stirred evenly; Add 30g of titanium dioxide and stir evenly; then add 20g of aged vanadium-based catalyst nano-powder to obtain a uniformly stirred slurry;

[0040] Natural aging in the reactor for 5 hours;

[0041] The aged slurry is continuously heated and stirred in the evaporation pond to evaporate the liquid until the slurry is...

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PUM

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Abstract

The invention discloses a preparation method of a regenerated denitration catalyst by using an aged vanadium-based catalyst and rare earth. According to the preparation method, on the basis of the aged vanadium-based catalyst, lanthanum oxide, cerium oxide, niobium oxide and the like are introduced to jointly modify the aged vanadium-based catalyst, so that the synergistic effect among the lanthanum oxide, the cerium oxide, the niobium oxide and vanadium oxide is found, the activity of the aged vanadium-based catalyst is improved, and the use temperature range of the catalyst is widened. The viscosity is introduced to replace part of TiO2, so that the activity and the mechanical strength of the catalyst are further improved, and the service life of the catalyst is prolonged.

Description

technical field [0001] The invention relates to the technical fields of environmental protection and catalysts, in particular to a preparation method of an aged vanadium-based catalyst and a rare earth-regenerated denitration catalyst. Background technique [0002] Nitrogen oxides (NOx) mainly include N 2 O, NO, NO 2 , N 2 O 3 , N 2 O 4 and N 2 O 5 , is the main pollutant causing air pollution, among which are mainly NO, NO 2 and N 2 O. Although NO is not very toxic, it is slowly oxidized to NO in the air 2 , the toxicity is 5 times that of NO. NO 2 Has a strong stimulating effect on the respiratory system: when NO 2 After entering the human body, it will cause adverse symptoms such as cough, asthma, chest pain, and emphysema. In addition, NO 2 It can also react with water in the atmosphere to generate nitric acid, which is one of the main sources of acid rain. N 2 O is a gas with a greenhouse effect. Although its content is very low in the atmosphere, its s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/22B01J23/30B01J23/28B01D53/86B01D53/56
CPCB01J23/22B01J23/30B01J23/28B01D53/8628B01D2257/402B01D2257/404Y02C20/10
Inventor 杨厂葛成敏王娜叶长飞
Owner XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY