Assistant composition for improving compatibility of pesticide preparation and concentrated fertilizer as well as preparation method and application of assistant composition
A technology for pesticide formulations and compatible additives, which is applied in fertilizer mixtures, botanical equipment and methods, applications, etc., can solve problems such as poor stability and homogeneity, and achieve improved dispersibility, improved utilization, and short production cycles. Effect
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[0053] The preparation method of compatible auxiliary agent used in the present invention is:
[0054] (1) Add reaction monomer A, reaction monomer C, and chain transfer agent into double-distilled water and isopropanol to prepare a certain proportion of the solution, stir and heat to reflux at 60-90°C to obtain a mixed solution; Add reaction monomer B and initiator solution dropwise in the middle, and the dropping time is 1-4h; The mass ratio of the three reaction monomers A, B, and C is (1~5):(1~3):(2~ 8); the sum of the mass of the reaction monomer A, the reaction monomer B and the reaction monomer C is the total mass of the monomer, and the consumption of the chain transfer agent is 0.5~10% of the total mass of the monomer, and the initiator The dosage is 2-16% of the total monomer mass;
[0055] Wherein, the reactive monomer A is an alkoxylate of allyl alcohol, an alkoxylate of methallyl alcohol, an alkoxylate of prenyl alcohol, and an alkoxylate of 4-hydroxybutyl vinyl ...
Embodiment 1
[0063] Get the following mass of material: allyl alcohol alkoxylate (n1=1, n2=2, n3=1, R 1 , R 3 , R 11 for H, R 2 for CH 3 ) 30g, maleic anhydride monoesterification ethoxylated soybean oleylamine (m=1, R 10 for C 18 h 33 ) 50g, isopropanol double-distilled water (20% isopropanol content) 540 and 3-mercaptopropionic acid 3g are added in the reaction kettle, stirred and warmed up to about 75-80°C for 0.5-1 hour; within 2.5 hours to the above Add 20g of styrene and 5g of initiator ammonium persulfate / sodium bisulfite dropwise into the solution, keep the temperature for 4h to react the product, add pH regulator NaOH to the reaction kettle, adjust the pH to 8.8, and then feed in methyl chloride at 70-80°C 5.8g, heat preservation at 75-80°C for 1.5-2h, release isopropanol; make a high molecular polymer sample with a solid content of 20% to improve the compatibility of pesticide preparations and concentrated fertilizers, record as Example 1. Compatible auxiliary agent sample...
Embodiment 2
[0070] Get the following mass of material: allyl alcohol alkoxylate (n1=5, n2=8, n3=10, R 1 , R 3 , R 11 for H, R 2 for CH 3 ) 10g, maleic anhydride monoesterification ethoxylated cocoylamine (m=1, R 10 for C 12 h 23 ) 80g, isopropanol double distilled water (isopropanol content is 25%) 510g and dodecyl mercaptan 6g are added in the reaction kettle, stir and heat up to about 75-80 ℃ and keep warm for 0.5-1 hour; Add 10g of styrene and 10g of initiator potassium persulfate / sodium bisulfite dropwise to the above solution, keep the product for 4 hours, add pH regulator NaOH to the reaction kettle, adjust the pH to 7.9, and then feed chlorine at 70-80°C 11g of methane, heat preservation at 75-80°C for 1.5-2h, release isopropanol; make a high molecular polymer sample with a solid content of 20% to improve the compatibility of pesticide preparations and concentrated fertilizers, record as Example 2. Compatible auxiliary agent sample in the present embodiment, its structural f...
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Abstract
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