Fireproof adhesive, preparation method thereof and composite fireproof glass containing fireproof adhesive

A technology of fireproof glass and fireproof glue, applied in the field of fireproof glue, can solve the problems of UV radiation resistance, high temperature resistance, poor hardness and cold flow resistance, poor UV radiation resistance and high temperature resistance, and complex production process. and other problems, to achieve the effect of preventing heat conduction and radiation, good process control, and maintaining integrity

Active Publication Date: 2021-04-30
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Organic grouting composite fireproof glass has better low temperature resistance, but poor ultraviolet radiation resistance, high temperature resistance, hardness and cold flow resistance
Inorganic composite fireproof glass is divided into inorganic air-drying composite fireproof glass and inorganic grouting composite fireproof glass. Among them, air-drying composite fireproof glass is also better in low temperature resistance, and its hardness and cold flow resistance are particularly outstanding, but it also has the same UV radiation resistance and durability. The high temperature performance is relatively poor, it is difficult to apply to complex and harsh environments such as outdoors, and the production process is complicated, and microbubbles are prone to be generated during the production process, which affects the appearance quality; while the inorganic grouting composite fireproof glass has ultraviolet radiation resistance and high temperature resistance. Very excellent, hardness and rheological performance are worse than organic grouting composite fireproof glass, although the low temperature resistance is not as good as organic grouting composite fireproof glass and inorganic air board composite fireproof glass, but it is much higher than the national standard requirements, and after recent years of development , low temperature performance is greatly improved

Method used

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  • Fireproof adhesive, preparation method thereof and composite fireproof glass containing fireproof adhesive
  • Fireproof adhesive, preparation method thereof and composite fireproof glass containing fireproof adhesive
  • Fireproof adhesive, preparation method thereof and composite fireproof glass containing fireproof adhesive

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preparation example Construction

[0075] One embodiment of the present invention also proposes a preparation method of fireproof glue, which specifically includes the following steps:

[0076] Add char-forming agent, char-forming aid, heat-resistant stabilizer, anti-condensation agent, ion fixative, storage stabilizer, defoamer and cross-linking agent in sequence to the nano-silica sol, stir while adding, and stir evenly After that, the first solution is obtained;

[0077] Add the water glass solution to the first solution, or add the first solution to the potassium water glass solution, transfer to a vacuum stirring tank, control the temperature of the system within 60°C, preferably 20-60°C, and stir for 30-60min, Then degassing under a vacuum lower than -0.096MPa for 30-40min, after depressurization, filter the solution with a 150-200 mesh screen to obtain a fireproof glue;

[0078] Among them, the raw materials in this method are the same as those of the above-mentioned fireproof glue. Specifically, in par...

Embodiment 1

[0122] A kind of fireproof glue, it is made of following raw material by weight: 25 parts of nano-silica sols with a mass concentration of 50%, 58 kg of potassium water glass solution with a mass concentration of 45%, 0.5 kg of sucrose, dihydrogen phosphate Potassium 0.1kg, boric acid 0.3kg, glycerol 15kg, starch 0.05kg, sodium polyphosphate 0.4kg, polyether modified silicone 0.5kg and sodium fluorosilicate 0.15kg.

[0123] The preparation method of the fireproof glue specifically includes the following steps: sequentially adding a char-forming agent, a char-forming aid, a heat-resistant stabilizer, an anti-condensation agent, an ion-fixing agent, a storage stabilizer, a defoamer and Cross-linking agent, stir evenly to obtain the first solution; mix potassium water glass solution with the first solution, stir at 40°C for 50 minutes, degas under -0.08MPa vacuum for 40 minutes, use 160-180 mesh sieve The net is filtered to obtain fireproof glue.

[0124] The method for preparin...

Embodiment 2

[0138] A kind of fireproof glue, by weight, it is made of the following raw materials: mass concentration is 48% nano-silica sol 23kg, mass concentration is 60kg of sodium water glass solution of 42%, fructose 0.3kg, potassium hydrogen phosphate 0.2 kg, borax 0.5kg, ethylene glycol 10kg, zinc oxide 0.1kg, potassium polyphosphate 0.5kg, polyoxyethylene polyoxypropylene pentaerythritol ether 0.2kg and aluminum fluoride 0.3kg.

[0139] The preparation method of the fireproof glue specifically includes the following steps: sequentially adding a char-forming agent, a char-forming aid, a heat-resistant stabilizer, an anti-condensation agent, an ion-fixing agent, a storage stabilizer, a defoamer and Cross-linking agent, stir evenly to obtain the first solution; mix potassium water glass solution with the first solution, stir at 60°C for 30 minutes, degas under -0.06MPa vacuum for 30 minutes, use 150-170 mesh sieve The net is filtered to obtain fireproof glue.

[0140] Adopt the same...

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Abstract

The invention relates to a fireproof adhesive, a preparation method of the fireproof adhesive and composite fireproof glass containing the fireproof adhesive. The fireproof adhesive includes the following raw materials: 20 to 30 parts of nano silicon dioxide sol, 50 to 65 parts of a water glass solution, 0.5 to 1.0 part of a charring agent, 0.1 to 0.3 part of a charring auxiliary agent, 0.3 to 0.8 part of a heat-resistant stabilizer, 10 to 20 parts of an anti-condensing agent, 0.05 to 0.1 part of an ion fixing agent, 0.3 to 0.5 part of a storage stabilizer, 0.1 to 0.5 part of a defoaming agent and 0.15 to 0.3 part of a cross-linking agent; wherein the moisture content of the inorganic transparent fireproof adhesive is 30-50%. The water content of the transparent fireproof glue is as low as 30-50%, and the fire resistance of the composite fireproof glass is effectively improved; meanwhile, certain flowing performance is ensured, so that pouring is facilitated. Heat insulation composite fireproof glass and non-heat-insulation type composite fireproof glass prepared from the transparent fireproof adhesive both have the characteristics of good appearance quality, good weather resistance, high visible light transmittance, excellent cold flow resistance and the like.

Description

technical field [0001] The invention relates to the technical field of fireproof glue, in particular to a fireproof glue, a preparation method thereof and a composite fireproof glass containing the fireproof glue. Background technique [0002] In addition to some properties of ordinary glass, fire-resistant glass also has the properties of controlling fire spread, smoke insulation and heat insulation, which provides valuable rescue time for effective rescue in the event of fire, and minimizes the loss of personnel, property, and buildings. property loss. Fire-resistant glass can protect escape and rescue personnel from heat radiation and minimize the destructive power of fire. Due to the recent frequent fires in some well-known large buildings at home and abroad, people are paying more and more attention to the R&D, production and use effects of composite fire-resistant glass. [0003] The earliest research on composite fireproof glass is organic grouting composite firepro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J1/02C09J1/00C09J11/04C09J11/06C09J11/08E06B3/67E06B3/677E06B3/663
CPCC09J1/02C09J1/00C09J11/04C09J11/06C09J11/08E06B3/6715E06B3/677E06B3/66328E06B3/66333E06B2003/66338E06B2003/6638Y02B80/22Y02A30/249
Inventor 徐磊张凡王晋珍陈玮朱治国穆元春李要辉徐志伟祖成奎
Owner CHINA BUILDING MATERIALS ACAD
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