Processing method of cellulosic fiber product with photothermal effect

A technology of cellulose fiber and photothermal effect, applied in fiber treatment, plant fiber, biochemical fiber treatment, etc., can solve the problems of restricting the development of self-heating fiber products, lack of nano-copper sulfide, etc.

Active Publication Date: 2021-07-06
JIANGNAN UNIV
View PDF6 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are many preparation methods of nano-copper sulfide, but most of them are carried out under the extreme conditions of high temperature and high pressure. ...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039](1) Fiber-grafted vinyl: soak the pure cotton knitted fabric in the methacrylic anhydride solution to introduce vinyl on the cotton fibers; among them, methacrylic anhydride 3g / L, temperature 0°C, pH 7, treatment 6 hours;

[0040] (2) Network template construction on the fiber surface: After the sample treated in step (1) was washed with water, it was immersed in a mixed solution of acrylic acid, N,N-methylenebisacrylamide, horseradish peroxidase and acetylacetone , add hydrogen peroxide under the protection of nitrogen to initiate the graft polymerization of vinyl monomers in the solution on the surface of cotton fibers, and form carboxyl-containing network templates on the surface of cotton fibers after washing with water; among them, acrylic acid 6g / L, N,N-methylene Base bisacrylamide 0.6g / L, horseradish peroxidase 2U / mL, acetylacetone 3g / L, H 2 o 2 1.5g / L, temperature 35℃, pH 6.5, treatment for 3 hours;

[0041] (3) In-situ deposition of nano-copper sulfide: imme...

Embodiment 2

[0050] (1) Grafting vinyl to fibers: dip the Tencel woven fabric in a solution of alkenyl succinic anhydride to introduce vinyl on the fibers; among them, alkenyl succinic anhydride 6g / L, temperature 4°C, pH 8, treatment 12 Hour;

[0051] (2) Network template construction on the fiber surface: After the sample treated in step (1) was washed with water, it was immersed in a mixed solution of acrylic acid, N,N-methylenebisacrylamide, horseradish peroxidase and acetylacetone , add hydrogen peroxide under the protection of nitrogen to initiate the graft polymerization of vinyl monomers in the solution on the surface of Tencel fibers, and form carboxyl-containing network templates on the surface of fibers after washing with water; among them, acrylic acid 15g / L, N,N-methylene Base bisacrylamide 2g / L, horseradish peroxidase 10U / mL, acetylacetone 5g / L, H 2 o 2 3g / L, temperature 40℃, pH 7.5, treatment for 6 hours;

[0052] (3) In-situ deposition of nano-copper sulfide: immerse the...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a processing method of a cellulosic fiber product with a photothermal effect, and belongs to the technical field of functional textile processing. The method comprises the following steps: firstly, introducing vinyl on a cellulose fiber product, and then catalyzing graft polymerization of acrylic acid and N,N-methylene bisacrylamide on a fiber by virtue of horse radish peroxidase, so as to form a net-shaped template containing carboxyl on the surface of the fiber; and then soaking the cellulose fiber product in a copper ammonia solution, and adding sodium sulfide to promote in-situ deposition on the surface of the fiber to form nano copper sulfide particles, so as to obtain the cellulose fiber product with the photothermal effect. According to the a processing method, the illumination self-heating cellulose fiber product is prepared by an adhesive-free method, and meanwhile, an illumination rapid sterilization function is endowed to the cellulose fiber product; and therefore, the cellulose fiber obtains the relatively high photothermal effect, and the application performance of the cellulose fiber product is improved.

Description

technical field [0001] The invention relates to a method for processing cellulose fiber products with photothermal effects, belonging to the technical field of functional textile processing. Background technique [0002] Cellulose fiber products include woven fabrics, knitted fabrics or non-woven fabrics processed from cotton, hemp, viscose and tencel fibers, which have the advantages of soft hand feeling and good moisture absorption. fields are widely used. In recent years, attention has been paid to the development of functional cellulose fiber products, especially fiber products with self-heating function under certain conditions, which are popular in autumn and winter clothing and home textile materials. [0003] There are several different types of self-heating textiles, including heating by conduction, heating by light, and others. Conductive heating textiles are coated with conductive media such as carbon black, graphene, carbon nanotubes or conductive polymers (suc...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): D06M11/53D06M14/04D06M13/203D06M101/06
CPCD06M11/53D06M14/04D06M16/00D06M13/203D06M2101/06
Inventor 王平任义文王飞宇周曼余圆圆王强
Owner JIANGNAN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap