High-tensile hydrogel conductive optical fiber as well as preparation method and application thereof
A hydrogel fiber, hydrogel technology, applied in cladding fiber, optical waveguide light guide, optics, etc., can solve the problems of high cost, low stretchability and low dissipation.
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[0049] The present invention also provides a method for preparing a high-stretch hydrogel conductive optical fiber, comprising the following steps:
[0050] A) heating and dissolving anionic polyacrylamide in a mixed solvent of water and an organic solvent, and obtaining anionic polyacrylamide hydrogel fibers by drawing and spinning after cooling;
[0051] B) immersing the anionic polyacrylamide hydrogel fiber in an inorganic salt solution for ion doping;
[0052] C) immersing the ion-doped fiber into a polyacrylate compound solution for coating to obtain a high-stretch hydrogel conductive optical fiber.
[0053] In the invention, the anionic polyacrylamide is heated and dissolved in a mixed solvent composed of water and an organic solvent to obtain a uniform translucent polymer solution, which is cooled at room temperature for standby use.
[0054] In the present invention, the organic solvent is preferably one or more of dimethyl sulfoxide, methanol, ethanol, acetone, N,N-d...
Embodiment 1
[0072] This embodiment is used to illustrate the preparation method of MAPAM hydrogel conductive optical fiber
[0073] Take 0.3g of anionic polyacrylamide (PAM) granular solid (Mw~2.2×10 7 Da), dissolved in a mixed solvent of 5g water / DMSO, the solvent contained 3g water and 2gDMSO, heated and stirred at 90°C for 1h, so that PAM was dissolved in the mixed solvent of water and DMSO, and a uniform translucent spinning solution was obtained.
[0074] Cool the resulting PAM solution to room temperature, then directly stretch out the PAM fiber from the solution, fix the two ends of the fiber, and let it stand in the air for a certain period of time (1-2 minutes), resulting in a PAM gel with a diameter of 200±50 μm fiber.
[0075] Then the synthetic fibers were soaked in 0.1M calcium chloride solution, 0.1M sodium sulfate solution and 0.5M lithium chloride solution for the same time (30 seconds) to form an ion cross-linked network in the PAM gel fiber to obtain an ion cross-link ...
Embodiment 2
[0079] This embodiment is used to illustrate the preparation method of MAPAM hydrogel conductive optical fiber material
[0080] Take 0.25g of anionic polyacrylamide (PAM) granular solid (Mw~2.2×10 7 Da), dissolved in a mixed solvent of 5g water / DMSO, the solvent contains 2.85g water and 2.15g DMSO, heated and stirred at 90°C for 1h, so that PAM is dissolved in the mixed solvent of water and DMSO to obtain uniform translucent spinning solution.
[0081] Cool the resulting PAM solution to room temperature, then directly stretch out the PAM fiber from the solution, fix the two ends of the fiber, and let it stand in the air for a certain period of time (1-2 minutes), resulting in a PAM gel with a diameter of 200±50 μm fiber.
[0082] Then the synthetic fibers were soaked in 0.1M calcium chloride solution, 0.1M sodium sulfate solution and 0.5M lithium chloride solution for the same time (30 seconds) to form an ion cross-linked network in the PAM gel fiber to obtain an ion cross-...
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Abstract
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