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High-tensile hydrogel conductive optical fiber as well as preparation method and application thereof

A hydrogel fiber, hydrogel technology, applied in cladding fiber, optical waveguide light guide, optics, etc., can solve the problems of high cost, low stretchability and low dissipation.

Active Publication Date: 2021-12-07
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, some flexible hydrogel optical fibers with stretchability and low dissipation have been developed for the biomedical field, most of which are hydrogel fibers based on calcium alginate / acrylamide (AAm) core-sheath structure. , the preparation method of using tubular mold molding, this complicated process is difficult for the continuous preparation of large-sized optical fibers, and the cost is too high
Moreover, existing hydrogel-based optical fibers are still difficult to combine optical, electrical, mechanical properties and stability to meet application requirements.

Method used

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  • High-tensile hydrogel conductive optical fiber as well as preparation method and application thereof
  • High-tensile hydrogel conductive optical fiber as well as preparation method and application thereof
  • High-tensile hydrogel conductive optical fiber as well as preparation method and application thereof

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preparation example Construction

[0049] The present invention also provides a method for preparing a high-stretch hydrogel conductive optical fiber, comprising the following steps:

[0050] A) heating and dissolving anionic polyacrylamide in a mixed solvent of water and an organic solvent, and obtaining anionic polyacrylamide hydrogel fibers by drawing and spinning after cooling;

[0051] B) immersing the anionic polyacrylamide hydrogel fiber in an inorganic salt solution for ion doping;

[0052] C) immersing the ion-doped fiber into a polyacrylate compound solution for coating to obtain a high-stretch hydrogel conductive optical fiber.

[0053] In the invention, the anionic polyacrylamide is heated and dissolved in a mixed solvent composed of water and an organic solvent to obtain a uniform translucent polymer solution, which is cooled at room temperature for standby use.

[0054] In the present invention, the organic solvent is preferably one or more of dimethyl sulfoxide, methanol, ethanol, acetone, N,N-d...

Embodiment 1

[0072] This embodiment is used to illustrate the preparation method of MAPAM hydrogel conductive optical fiber

[0073] Take 0.3g of anionic polyacrylamide (PAM) granular solid (Mw~2.2×10 7 Da), dissolved in a mixed solvent of 5g water / DMSO, the solvent contained 3g water and 2gDMSO, heated and stirred at 90°C for 1h, so that PAM was dissolved in the mixed solvent of water and DMSO, and a uniform translucent spinning solution was obtained.

[0074] Cool the resulting PAM solution to room temperature, then directly stretch out the PAM fiber from the solution, fix the two ends of the fiber, and let it stand in the air for a certain period of time (1-2 minutes), resulting in a PAM gel with a diameter of 200±50 μm fiber.

[0075] Then the synthetic fibers were soaked in 0.1M calcium chloride solution, 0.1M sodium sulfate solution and 0.5M lithium chloride solution for the same time (30 seconds) to form an ion cross-linked network in the PAM gel fiber to obtain an ion cross-link ...

Embodiment 2

[0079] This embodiment is used to illustrate the preparation method of MAPAM hydrogel conductive optical fiber material

[0080] Take 0.25g of anionic polyacrylamide (PAM) granular solid (Mw~2.2×10 7 Da), dissolved in a mixed solvent of 5g water / DMSO, the solvent contains 2.85g water and 2.15g DMSO, heated and stirred at 90°C for 1h, so that PAM is dissolved in the mixed solvent of water and DMSO to obtain uniform translucent spinning solution.

[0081] Cool the resulting PAM solution to room temperature, then directly stretch out the PAM fiber from the solution, fix the two ends of the fiber, and let it stand in the air for a certain period of time (1-2 minutes), resulting in a PAM gel with a diameter of 200±50 μm fiber.

[0082] Then the synthetic fibers were soaked in 0.1M calcium chloride solution, 0.1M sodium sulfate solution and 0.5M lithium chloride solution for the same time (30 seconds) to form an ion cross-linked network in the PAM gel fiber to obtain an ion cross-...

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Abstract

The invention provides high-tensile hydrogel conductive optical fiber. The high-tensile hydrogel conductive optical fiber comprises a polyacrylamide inner core and a polyacrylate coating layer; the polyacrylamide inner core is anionic polyacrylamide hydrogel fiber doped with metal ions; and the metal ions are one or more of Na<+>, K<+>, Li<+>, Ca<+>, Mg<2+>, Fe<3+> and Zn<2+>. According to the invention, the ions are doped into a polymer chain of the polyacrylamide fiber to form crosslinking, so that the mechanical property is enhanced, ionic conductivity is provided, and the water evaporation and freezing point of hydrogel are reduced by utilizing the high hydration degree of the ions. PMA is selected as the coating layer of the optical fiber, so that the moisture content of the fiber is kept for a long time without being influenced by the external environment, and light is limited in the core to be totally reflected for conduction. The invention further provides a preparation method and application of the high-tensile hydrogel conductive optical fiber.

Description

technical field [0001] The invention belongs to the technical field of biomedicine, and in particular relates to a high-stretch hydrogel conductive optical fiber, its preparation method and application. Background technique [0002] Hydrogel is a three-dimensional cross-linked porous polymer with unique properties such as good mechanical strength, flexibility, and biocompatibility. Conductive hydrogels with additional conductivity, which combine high conductivity and softness, become one of the ideal interface materials to achieve perfect compatibility between the human body and bioelectronic devices. [0003] Currently, conducting polymer hydrogels can be divided into two categories, conducting polymer hydrogels and ionically conducting hydrogels. One is to introduce conductive components such as conductive polymers or nanomaterials into the hydrogel based on electron transport. However, most conductive materials are expensive, and the conductive components are very easy t...

Claims

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Application Information

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IPC IPC(8): D06M15/263G02B1/00G02B1/04G02B6/02A61B18/22D06M101/34
CPCD06M15/263G02B1/048G02B1/046G02B1/00G02B6/02A61B18/22D06M2101/34A61B2018/2222
Inventor 马明明霍子昱
Owner UNIV OF SCI & TECH OF CHINA
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