Porous organic polymer as well as preparation method and application thereof
A technology of polymer and polymerization reaction, applied in the direction of separation method, method of chemically changing substances by atmospheric pressure, alkali metal compounds, etc., can solve the problems of unable to mass-produce operating conditions, low reactivity, shortening reaction time, etc. Achieve the effects of easy expansion of reaction scale, short synthesis cycle and increased reaction rate
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Embodiment 1
[0028] Different reaction temperatures regulate the channels of B-H coupling polymer PTPA: 1 mmol of tris(4-bromophenyl)amine (centron), 1 mmol of p-phenylenediamine (linker), 5mol% Pd(dba) 2, 9 mol% xPhos and 7 eq. NaOtBu were added into the miniature autoclave, and 70 ml of tetrahydrofuran was injected, and the reaction pressure was 2 MPa at 100°C, 120°C, 140°C, and 160°C for 5 hours, and the obtained The product was successively washed by suction filtration of tetrahydrofuran, chloroform, ethanol and hot water, and the solid product PTPA was vacuum-dried at 70°C for 24 hours to remove the solvent. The product is bright blue in color, exhibits obvious redox polyaniline characteristics, and is insoluble in various organic solvents and acid-base solvents, with good experimental reproducibility. After drying, the product yield was calculated, and the average yield was above 95%, and the specific surface area of abundant micropores was as high as 1145 m 2 / g. Compared with t...
Embodiment 2
[0032] Channel regulation of B-H coupling polymer PTPA with different reaction times: 1 mmol tris(4-bromophenyl)amine (centron), 1 mmol p-phenylenediamine (linker), 5mol% Pd(dba) 2 , 9 mol% xPhos and 7 eq. NaOtBu were added into a miniature autoclave, and 70 ml of tetrahydrofuran was injected. Suction filtration and washing with chloroform, ethanol and hot water, and the solid product PTPA was vacuum-dried at 70° C. for 24 hours to remove the solvent. Experiments have found that when the temperature is increased, even if the reaction time is shortened to 1 hour, the product with excellent shape can be obtained, and the rapid reaction is realized, which solves the previous limitation of low reactivity, and the reaction time often needs to be 2-3 days. , or even weeks of problems.
[0033] image 3 It is the infrared spectrum of the linker and the infrared spectrum of PTPA obtained through B-H coupling reaction at different reaction times. It can be found that the infrared ch...
Embodiment 3
[0036] Different reaction pressures control the channels of B-H coupling polymer PTPA: 1 mmol tris(4-bromophenyl)amine (centron), 1 mmol p-phenylenediamine (linker), 5mol% Pd(dba) 2 , 9 mol% xPhos and 7 eq. NaOtBu were added into the miniature autoclave, injected with 70 ml tetrahydrofuran, and reacted for 5 hours at 120°C, and the reaction pressure was set to 0 MPa, 1 MPa, and 2 MPa respectively, and the obtained product Suction filtration and washing of tetrahydrofuran, chloroform, ethanol, and hot water in sequence, and the solid product PTPA was vacuum-dried at 70° C. for 24 hours to remove the solvent.
[0037] Figure 5 It is the infrared spectrum of the linker and the infrared spectrum of PTPA obtained through B-H coupling reaction at different reaction times. It can be found that the infrared characteristic peaks of all samples are basically consistent with those in Example 1, and the corresponding amino characteristic peaks and the weakening of the C-Br peak have all...
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