Electrophoresis method for detecting effective components of aloe polysaccharide
A technology of aloe polysaccharides and active ingredients, applied in the field of biochemical analysis, can solve the problems of large molecular weight of acetylated mannan, complicated identification and detection process, inability to carry out polysaccharide structure, etc., and achieve high sensitivity, low cost, and shortened experiment time Effect
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Embodiment 1
[0039] An electrophoresis method for detecting active ingredients of aloe polysaccharides, comprising the following steps:
[0040] (1) Peel the leaves of Aloe vera whose age is 12 months, June and March, and smash them to obtain sample solutions of fresh aloe polysaccharides A1, A2 and A3; the dry powder of aloe polysaccharides is according to the solid-liquid ratio of 1:60 and 1:40, Distilled water was added to redissolve to obtain aloe polysaccharide dry powder P1 and P2 sample solutions; the aloe product was diluted with distilled water at a ratio of 1:1 to obtain aloe product C1 sample solution.
[0041] (2) Take 5ml of the above sample solution, add 10mg of FITC (fluorescein isothiocyanate) reagent, adjust the pH value to 9.0 with sodium hydroxide, and react on a shaker at 150r / min at 45°C for 2h.
[0042] (3) Take 1ml of the above-mentioned solution that has completed the reaction, add 1ml of medical glycerin, mix evenly to obtain a test solution, and set aside.
[004...
Embodiment 2
[0056] An electrophoresis method for detecting active ingredients of aloe polysaccharides, comprising the following steps:
[0057] (1) Peel the fresh aloe leaves and smash them to obtain the fresh aloe polysaccharide A1 sample solution; the aloe polysaccharide dry powder is redissolved in distilled water according to the solid-liquid ratio of 1:40 to obtain the aloe polysaccharide dry powder P1 sample solution; the aloe product is according to the ratio of 1:40 1 ratio, distilled water was added to dilute to obtain the aloe product C1 sample solution.
[0058] (2) O-acetyl color development: Accurately measure 1ml of the sample and place it in a test tube, add 2ml of freshly prepared alkaline hydroxylamine solution, shake well, let it stand at room temperature for 4 minutes, add 1ml of 4mol / L hydrochloric acid solution, shake well, Add 1ml of 0.37mol / L ferric chloride solution and shake well.
[0059] (3) Take 1ml of the above-mentioned solution that has completed the reacti...
Embodiment 3
[0065] In this embodiment, the gel of the aloe polysaccharide electrophoresis band obtained in Example 1 is taken out, and is passed through high-performance liquid gel permeation chromatography (HPGPC), ion chromatography (IC5000+), gas chromatography-mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy ( NMR) and other methods were used to analyze the monosaccharide composition, methylation and NMR of the samples.
[0066] Such as image 3 As shown in Table 1, the monosaccharide composition was measured by ion spectrometer, and the result showed that the monosaccharide composition of the polysaccharide in the electrophoresis strip was mainly mannose.
[0067] Table 1 Monosaccharide composition of polysaccharides in the gel
[0068]
[0069]
[0070] As shown in Table 2, the connection mode of the polysaccharide sample was measured by GC-MS after derivatization such as methylation, and the results showed that the connection mode of the polysaccharide in t...
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