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High-heat-dissipation perovskite nanosheet laser and preparation method thereof

A nanosheet and perovskite technology, applied in the field of high heat dissipation perovskite nanosheet lasers, can solve the problems of increasing scattering loss contact thermal resistance, aggravating the thermal effect of devices, and nanosheet light field leakage, etc. Thermal effects, reduced power dissipation, good thermal contact between layers

Pending Publication Date: 2022-05-24
TAIYUAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Importantly, direct introduction of high thermal conductivity substrates such as Si ( kappa ~130 W / (m K), n~3.43), SiC ( kappa ~490W / (m K), n~2.6), diamond ( kappa ~1800 W / (m K), n~2.42), due to its high refractive index, which leads to a large light field leakage in the nanosheet, making it impossible to form a resonance to generate laser light
And because the roughness of these materials is generally large, it will increase the scattering loss and the contact thermal resistance between the two materials, and the increase of the contact thermal resistance will aggravate the thermal effect in the device
[0006] At present, the temperature of perovskite laser devices rises sharply under high pump power density, and the combined action of water, oxygen and material surface defects will lead to thermal degradation of materials, which is the biggest challenge for the commercialization of perovskite laser devices

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  • High-heat-dissipation perovskite nanosheet laser and preparation method thereof

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Embodiment 1

[0036]The invention provides a perovskite nano-sheet laser, which, combined with heat dissipation design, ensures excellent packaging characteristics and high light field confinement capability. It can solve the thermal instability problem faced by perovskite material laser devices.

[0037] Specifically, as Figure 1~2 As shown, a high heat dissipation perovskite nanosheet laser according to an embodiment of the present invention includes: a thermally conductive base 4, on which a silicon dioxide bonding layer 3 is arranged, and the silicon dioxide bonding layer 3 is provided on the thermally conductive base 4. A perovskite nanosheet 1 is arranged on the composite layer 3 as a laser gain medium, a polyvinylidene fluoride (PVDF) encapsulation layer 2 is arranged above the perovskite nanosheet 1, and the polyvinylidene fluoride encapsulation layer 2 covers the Above and outside the perovskite nanosheet 1, the perovskite nanosheet 1 is encapsulated.

[0038] Specifically, in t...

Embodiment 2

[0050] The second embodiment of the present invention provides a preparation method of a perovskite nanosheet laser, which specifically includes the following preparation and implementation steps:

[0051] S1. Magnetron sputtering a layer of SiO on the surface of the diamond substrate 2 layer, specifically, SiO 2 The thickness of the layer is 200 nm and the surface roughness after coating is RMS < 2 nm.

[0052] S2. Using a two-step vapor deposition method, deposit MAPbI on the mica sheet 3 Nanosheets. Among them, the nanosheet surface roughness RMS<1 nm.

[0053] S3, then using the physical transfer method, transfer the target nanosheets from the mica sheet to the diamond-SiO prepared in step S1 2 On the substrate, the side length of the nanosheet is 40 μm and the thickness is 150 nm.

[0054] S4. Finally, at 50 °C, the PVDF powder was dissolved in N,N-dimethylformamide (DMF) to make a 10% (w / v) solution. in diamond-SiO 2 - Spin coating on the nanosheet at a high speed...

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Abstract

The invention belongs to the technical field of laser design, and discloses a high-heat-dissipation perovskite nanosheet laser which comprises a heat conduction base, a silicon dioxide bonding layer is arranged on the heat conduction base, and a perovskite nanosheet is arranged on the silicon dioxide bonding layer to serve as a laser gain medium. A polyvinylidene fluoride encapsulation layer is arranged above the perovskite nanosheet, and the polyvinylidene fluoride encapsulation layer is used for encapsulating the perovskite nanosheet. According to the invention, the temperature of the device is greatly reduced through the heat-conducting base; the polyvinylidene fluoride layer has the physical properties of high temperature resistance and effective isolation of water / oxygen, and can improve the stability of the device. And secondly, the polyvinylidene fluoride packaging layer and the silicon dioxide layer serve as double-sided waveguides, so that the highest light limiting capability of the structure is ensured, the power consumption and the heat effect are reduced, and the thermal stability of the device is improved.

Description

technical field [0001] The invention belongs to the technical field of laser design, and in particular relates to a high heat dissipation perovskite nanosheet laser, which improves the thermal stability of the laser device by improving the heat dissipation effect of the device. Background technique [0002] In recent years, perovskite, as an emerging semiconductor material, exhibits material properties such as higher optical gain, low defect state density and low Auger loss than traditional semiconductor materials. Therefore, perovskite-based micro-nano lasers exhibit lower lasing thresholds and non-radiative losses. Continuously realizing long-term stable operation of CW-injected perovskite micro-nano lasers is a key step towards the application of electrically pumped lasers and high-density optoelectronic integrated devices. As a high-quality resonant cavity, nanosheets can be mass-produced and miniaturized, which is more conducive to the development of optoelectronic int...

Claims

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Application Information

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IPC IPC(8): H01S5/02H01S5/024H01S5/36B82Y30/00
CPCH01S5/02484H01S5/02461H01S5/0213H01S5/0206H01S5/36B82Y30/00Y02E10/549
Inventor 李国辉魏衍福侯缜崔艳霞
Owner TAIYUAN UNIV OF TECH
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