Unlock instant, AI-driven research and patent intelligence for your innovation.

Preparation method of chitin nanofiber antireflection coating, antireflection coating and substrate

An anti-reflection coating and nanofiber technology, which can be applied to coatings, chitin polysaccharide coatings, and devices for coating liquids on surfaces, etc. The preparation method is simple, the drying time is shortened, and the production efficiency is improved.

Active Publication Date: 2022-07-15
JILIN UNIV
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The "top-down" strategy uses imprint lithography, colloid etching, plasma etching and other methods to prepare nanocone or convex hull arrays with precise shapes on the substrate surface, but most of them require expensive equipment or complicated processes. , high cost and time-consuming
Although a variety of methods for preparing anti-reflection surfaces or coatings have been developed, the following problems still exist: the first is that the production cost of most preparation methods has a large gap with the acceptable price in the market, and the low-cost and large-area (more than 1 square meter) ) The preparation of anti-reflection surface or coating is still a challenge at present; the second is that the nanomastoid arrays prepared on the substrate surface are usually fragile, easily damaged or polluted, resulting in a decline in anti-reflection performance, which limits its wide application; the third is Using sol-gel methods to construct anti-reflection coatings on glass surfaces requires high-temperature treatment. This type of method is not suitable for polymer material substrates with a glass transition temperature lower than 200 ° C. It should be prepared at the lowest possible temperature. Anti-reflection coatings remain a great challenge
For example, the coating with anti-reflection function can be prepared by alternately dipping the water dispersion of chitin nanofibers and polyacrylic acid solution on the glass surface, but this method is cumbersome and time-consuming, and the polyacrylic acid adhesive fills the coating. Partial voids between chitin nanofibers in the layer are not conducive to further reduction of the refractive index of the coating

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of chitin nanofiber antireflection coating, antireflection coating and substrate
  • Preparation method of chitin nanofiber antireflection coating, antireflection coating and substrate
  • Preparation method of chitin nanofiber antireflection coating, antireflection coating and substrate

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0046] The preparation method of the chitin nanofiber anti-reflection coating provided by the present invention comprises the following steps: firstly preparing a certain concentration of chitin nanofiber aqueous suspension; then, placing the substrate in the chitin nanofiber suspension, and then vertically A DC electric field of a certain intensity was applied in the direction of the surface to be coated (light incident surface) of the substrate and maintained for a certain period of time; finally, the substrate was taken out and placed in an oven at 50° C. to dry for 5 minutes to obtain the chitin nanofiber anti-reflection coating.

[0047] In the present invention, the concentration of the chitin nanofiber aqueous suspension is between 0.05wt% and 1.00wt%.

[0048] In the present invention, the size of the chitin nanofibers is 5-50nm in width and 200-600nm in length,

[0049] The steps of one embodiment of preparing the chitin nanofiber aqueous suspension described in the p...

Embodiment 1

[0054] (1) Weigh 2g of chitin powder and 10g of maleic anhydride, put them in a conical flask and mix thoroughly, seal the flask and put it into a 120°C oven for 3h reaction. The reacted product was centrifuged and washed with absolute ethanol until it was colorless, and then centrifuged with purified water until neutral. Add a few drops of 1 mol / L sodium hydroxide solution dropwise to adjust the pH to 11, and then continue to centrifuge and wash with purified water until neutral.

[0055] (2) Disperse the washed product in water with a concentration of 0.5 wt %. 30 g of the dispersion was ultrasonically treated with an ultrasonic cell crusher at a power of 500 W for 45 min to obtain a chitin nanofiber suspension with negative charges on the surface.

[0056] (3) Pour 60 mL of chitin nanofiber suspension into a petri dish between two horizontally arranged electrode plates, place the glass slide on the bottom of the petri dish, connect the upper plate to the negative electrode...

Embodiment 2

[0059] (1) Weigh 2g of chitin powder and 10g of maleic anhydride, put them in a conical flask and mix thoroughly, seal the flask and put it into a 120°C oven for reaction for 3h. The reacted product was centrifuged and washed with absolute ethanol until it was colorless, and then centrifuged with purified water until neutral. Add a few drops of 1 mol / L sodium hydroxide solution dropwise to adjust the pH to 11, and then continue to centrifuge and wash with purified water until neutral.

[0060] (2) The washed product was mixed with a 35% concentration NaOH solution at a ratio of 1:25 (g / mL) and reacted at 90° C. for 4 h, and the flask was shaken every 20 min. After the reaction was completed, the supernatant was washed by repeated centrifugation with purified water until the supernatant was neutral.

[0061] (3) Disperse the above product in water, the concentration is 0.5wt%, add acetic acid dropwise to adjust the pH value to 3~4, use an ultrasonic cell crusher to ultrasonica...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
widthaaaaaaaaaa
lengthaaaaaaaaaa
glass transition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention provides a chitin nanofiber anti-reflection coating preparation method, an anti-reflection coating and a substrate, the chitin nanofiber anti-reflection coating preparation method comprises the following steps: firstly preparing a chitin nanofiber water suspension, putting the substrate into a container filled with the chitin nanofiber water suspension, putting the container between a positive electrode and a negative electrode, applying a direct current electric field in a direction perpendicular to a to-be-coated surface of the substrate, the surface of the substrate is coated with the chitin nanofibers, the strength is 0.56-5.59 * 10 < 3 > V / m, the chitin nanofibers with charges on the surfaces move towards the to-be-coated surface of the substrate and are deposited on the to-be-coated surface of the substrate, and the substrate with the chitin nanofiber anti-reflection coating is obtained.According to the method, the anti-reflection coating can be constructed on the surface of the substrate within 10-20 min; the light transmittance gain of the antireflection coating within the wavelength range of 400-800 nm can reach 5%, and the antireflection coating can be applied to plastic and biological material substrates.

Description

technical field [0001] The invention belongs to the technical field of anti-reflection coatings, in particular to a preparation method of a chitin nanofiber anti-reflection coating. Background technique [0002] Anti-reflection coating plays an extremely important role in optical components, light-emitting devices, flat panel and flexible displays, photovoltaic devices, optical biosensors, etc. It can increase the luminous flux and sensitivity of the optical system, improve the performance and efficiency of light-emitting devices, and improve display performance The display effect under sunlight suppresses the glare effect, improves the photoelectric conversion efficiency of photovoltaic devices, and the like. In many applications, every percent loss of luminous flux can cause a significant decrease in device performance or functionality. [0003] The anti-reflection coatings currently developed mainly include graded refractive index coatings, multi-layer interference coati...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B05D7/24B05D1/00B05D5/06C09D105/08C09D5/00C08B37/08
CPCB05D7/24B05D1/00B05D5/061C09D105/08C09D5/006C08B37/003
Inventor 周江韦宏远寇律恒王培壮呼芷晴张立商佳琦任丽丽
Owner JILIN UNIV
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More