Preparation method of chitin nanofiber antireflection coating, antireflection coating and substrate
An anti-reflection coating and nanofiber technology, which can be applied to coatings, chitin polysaccharide coatings, and devices for coating liquids on surfaces, etc. The preparation method is simple, the drying time is shortened, and the production efficiency is improved.
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[0046] The preparation method of the chitin nanofiber anti-reflection coating provided by the present invention comprises the following steps: firstly preparing a certain concentration of chitin nanofiber aqueous suspension; then, placing the substrate in the chitin nanofiber suspension, and then vertically A DC electric field of a certain intensity was applied in the direction of the surface to be coated (light incident surface) of the substrate and maintained for a certain period of time; finally, the substrate was taken out and placed in an oven at 50° C. to dry for 5 minutes to obtain the chitin nanofiber anti-reflection coating.
[0047] In the present invention, the concentration of the chitin nanofiber aqueous suspension is between 0.05wt% and 1.00wt%.
[0048] In the present invention, the size of the chitin nanofibers is 5-50nm in width and 200-600nm in length,
[0049] The steps of one embodiment of preparing the chitin nanofiber aqueous suspension described in the p...
Embodiment 1
[0054] (1) Weigh 2g of chitin powder and 10g of maleic anhydride, put them in a conical flask and mix thoroughly, seal the flask and put it into a 120°C oven for 3h reaction. The reacted product was centrifuged and washed with absolute ethanol until it was colorless, and then centrifuged with purified water until neutral. Add a few drops of 1 mol / L sodium hydroxide solution dropwise to adjust the pH to 11, and then continue to centrifuge and wash with purified water until neutral.
[0055] (2) Disperse the washed product in water with a concentration of 0.5 wt %. 30 g of the dispersion was ultrasonically treated with an ultrasonic cell crusher at a power of 500 W for 45 min to obtain a chitin nanofiber suspension with negative charges on the surface.
[0056] (3) Pour 60 mL of chitin nanofiber suspension into a petri dish between two horizontally arranged electrode plates, place the glass slide on the bottom of the petri dish, connect the upper plate to the negative electrode...
Embodiment 2
[0059] (1) Weigh 2g of chitin powder and 10g of maleic anhydride, put them in a conical flask and mix thoroughly, seal the flask and put it into a 120°C oven for reaction for 3h. The reacted product was centrifuged and washed with absolute ethanol until it was colorless, and then centrifuged with purified water until neutral. Add a few drops of 1 mol / L sodium hydroxide solution dropwise to adjust the pH to 11, and then continue to centrifuge and wash with purified water until neutral.
[0060] (2) The washed product was mixed with a 35% concentration NaOH solution at a ratio of 1:25 (g / mL) and reacted at 90° C. for 4 h, and the flask was shaken every 20 min. After the reaction was completed, the supernatant was washed by repeated centrifugation with purified water until the supernatant was neutral.
[0061] (3) Disperse the above product in water, the concentration is 0.5wt%, add acetic acid dropwise to adjust the pH value to 3~4, use an ultrasonic cell crusher to ultrasonica...
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Abstract
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