Fluorine gypsum composite cementing material and preparation method thereof
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- ANHUI JINYANG FLUORINE CHEM
- Publication Date
- 2022-08-05
Abstract
Description
technical field
[0001] The invention belongs to the technical field of building materials, and in particular relates to a fluorogypsum composite cementitious material and a preparation method thereof. Background technique
[0002] Fluorogypsum is a by-product of the production process of hydrofluoric acid. The industrial waste mainly calcium sulfate is produced by the reaction of sulfuric acid and fluorite powder. For every 1 ton of hydrofluoric acid produced, 3.6 tons of anhydrous fluoride gypsum are produced. The production reaction equation is as follows shown:
[0003] H 2 SO 4 +CaF 2 =2HF+CaSO 4
[0004] When the fluorine gypsum is discharged from the reactor, the temperature of the material is 180-230°C, and the temperature of the gas is 800-1000°C. The main component of the discharged gypsum is type II anhydrous calcium sulfate, which is strongly acidic, pH=2-4, and is discharged annually. The amount exceeds 2.5 million tons, so the output of fluorogypsum is con...