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Method for fast mfg. metal/high-molecular composite material parts

A composite material and polymer technology, applied in the field of rapid prototyping of metal/polymer composite parts, can solve the problems of low manufacturing temperature, small interface reaction, and low production efficiency, and achieve short manufacturing cycle, simple process and low cost Effect

Active Publication Date: 2006-03-29
HUAZHONG UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the squeeze casting method is to first make the reinforcing agent into a preform, put it into a fixed mold and preheat it to a certain temperature, pour the metal melt, press down the male mold and pressurize it, and quickly cool it down and then demould it. Parts, this method has the advantage of improving the wettability of the metal melt and eliminating defects such as pores, but the requirements for equipment are relatively high and the process is complicated
The vacuum-air pressure casting method is relatively new and considered to be a better method. This method is to make a preformed body into the mold cavity with a reinforcing agent, heat and vacuum, and then press the metal melt into the mold cavity with air pressure. , rapid cooling and demoulding, because this method is vacuum first and then lower pressure, so the damage to the fiber is small, and its mechanical properties are better than extrusion, but the process is also very complicated, and the equipment requirements are also high
The powder metallurgy method is to sprinkle a layer of metal powder on the long polymers arranged, alternately overlap the fibers and metal powder, cold press, and then sinter to shape. The advantage of this method is that the manufacturing temperature is low, and it is suitable for a variety of metal substrates and high The disadvantage of the combination of molecules is that the polymer chain segment is damaged, the distribution is uneven, the content is not high, and the process is complicated
The diffusion bonding method is to make a precursor wire by impregnating the reinforcing agent with metal after surface treatment, and then laminate it with metal foil (or powder) under vacuum conditions (or protective atmosphere) and at a temperature slightly lower than the melting point of the metal. Bonding molding, this method has little fiber loss and high density of the composite material, but the production efficiency is low and the equipment requirements are high
The extrusion or rolling method combines the polymer with the layered matrix. The advantage of this method is that the interface reaction is small and the orientation is regular. The disadvantage is that the chain segment of the polymer is easily damaged, and the type of metal matrix is ​​also limited, and the cost requirement is high.
To sum up, the current manufacturing methods of metal / polymer composite parts are not only complicated in manufacturing process, high in manufacturing conditions, low in production efficiency and high in cost requirements, but also difficult to control the precision and strength of parts
Therefore, the manufacturing method of traditional metal / polymer composite parts has greatly hindered its large-scale production and application.

Method used

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  • Method for fast mfg. metal/high-molecular composite material parts
  • Method for fast mfg. metal/high-molecular composite material parts
  • Method for fast mfg. metal/high-molecular composite material parts

Examples

Experimental program
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Effect test

Embodiment 1

[0026] The present invention adopts epoxy resin powder and 300-mesh 316L stainless steel powder to be mixed uniformly under a certain ratio (such as 1:100) as raw materials, through the HRPS-III type selective laser sintering (SLS) molding system of Huazhong University of Science and Technology, parameter setting For: laser energy 15W; scanning speed 2000mm / s; sintering spacing 0.1mm; sintering layer thickness 0.1mm. The obtained prototype blank is degreased at a temperature of 400°C-600°C under a reducing atmosphere, then heated to 1180°C for high-temperature sintering, and cooled to obtain a porous metal part blank.

[0027] Mix epoxy resin and phenolic resin by 1:2, add 50% methyltetrahydrophthalic anhydride (MeTHPA) as a curing agent at a temperature of 60 ° C, and stir it evenly, then gradually increase the temperature to 90 ℃. At the same time, the porous metal part (1) is also preheated to 90°C. During the heating process, the viscosity of the solution gradually decrea...

Embodiment 2

[0030] The present invention uses epoxy resin powder and 350-mesh 420L stainless steel powder in a certain ratio (such as 5:100) to mix uniformly as raw materials, and through the HRPS-III selective laser sintering (SLS) molding system of Huazhong University of Science and Technology, the parameters are set For: laser energy 15W; scanning speed 2000mm / s; sintering spacing 0.1mm; sintering layer thickness 0.1mm. The obtained prototype blank is degreased at a temperature of 400°C-600°C in a reducing atmosphere, then heated to 1100°C for high-temperature sintering, cooled and taken out to obtain a porous metal part blank.

[0031] Mix epoxy resin and phenolic resin by 1:1, add 50% methyltetrahydrophthalic anhydride (MeTHPA) as a curing agent at a temperature of 60 ° C, and stir it evenly, and then gradually increase the temperature to 100 ℃. At the same time, the porous metal part (1) is also preheated to 100°C. During the heating process, the viscosity of the solution gradually...

Embodiment 3

[0034] The present invention adopts epoxy resin powder and 400 order 1Cr18Ni9Ti powder to mix evenly under certain proportioning ratio (such as 1: 100) as raw material, through HRPS-III type selective laser sintering (SLS) forming system of Huazhong University of Science and Technology, parameter setting is : Laser energy 15W; scanning speed 2000mm / s; sintering pitch 0.1mm; sintering layer thickness 0.1mm. The obtained prototype blank is degreased at a temperature of 400°C-600°C under a reducing atmosphere, and then heated to a temperature of 1200°C for high-temperature sintering, cooled and taken out to obtain a porous metal part blank.

[0035] Mix epoxy resin and modified silicone at a ratio of 2:1, add 50% methyltetrahydrophthalic anhydride (MeTHPA) as a curing agent at a temperature of 60°C, and stir it evenly, then gradually increase the temperature to 110°C. At the same time, the porous metal part (1) is also preheated to 110°C. During the heating process, the viscosit...

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Abstract

A process for quickly preparing the metal / high-molecular material workpiece includes such steps as preparing the immersing liquid through proportionally mixing epoxy resin with phenolic resin or modified organosilicon, heating to 60-80 deg.C, adding methyl tetrahydrophenyl diformic anhydride and stirring, preparing the workpiece blank from metal and high-molecular material, degreasing, sintering to become porous blank, immersing it in said immersing liquid at 90-110 deg.C until no air bubbles, solidifying at 140-180 deg.C, and cooling.

Description

technical field [0001] The invention belongs to the field of advanced manufacturing, in particular to a rapid prototyping method for metal / polymer composite material parts. Background technique [0002] At present, the traditional manufacturing methods of metal / polymer composite parts mainly include: squeeze casting method, vacuum-air pressure casting method, powder metallurgy method, diffusion bonding method, extrusion method, rolling method, etc. Among them, the squeeze casting method is to first make the reinforcing agent into a preform, put it into a fixed mold and preheat it to a certain temperature, pour the metal melt, press down the male mold and pressurize it, and quickly cool it down and then demould it. Parts, this method has the advantage of improving the wettability of the metal melt and eliminating defects such as pores, but the requirements for equipment are relatively high and the process is complicated. The vacuum-air pressure casting method is relatively n...

Claims

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Application Information

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IPC IPC(8): C22C1/00B29C70/00C22C45/00
Inventor 史玉升黄树槐陈继兵刘锦辉
Owner HUAZHONG UNIV OF SCI & TECH
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