Bright red underglaze color, overglaze and their prepn process

A red and glaze technology, applied to clay products, other household utensils, applications, etc., can solve problems such as cracks, glaze shrinkage, surface glaze erosion of red glaze, etc., and achieve bright and bright colors

Inactive Publication Date: 2007-01-03
胡天霏 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 2. So far, cadmium sulfur selenide is the only ceramic pigment that can show bright red color, but this substance is not resistant to high temperature. Pure cadmium sulfur selenide will decompose at about 500°C, not only cannot show bright red color, but also produce toxic substance
In the prior art, there are invention patents "high temperature resistant cadmium sulfur selenide red glaze for ceramic glaze and its manufacturing method" (patent number: 01128545.1), "high temperature red glaze and its preparation method" (patent number: 200410047011.1) revealing Different degrees of high temperature-resistant bright red pigments containing cadmium selenide sulfur, in practical applications, the two inventions can not withstand the high temperature above 1350 ℃, can not fire underglaze color ceramic products, but can only be used as the surface color of ceramics. The glaze and surface color are used to fire cer

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Take tantalum pentoxide, zinc oxide, antimony trioxide, and silicon dioxide powder and mix and grind them to 250 mesh according to the following weight ratio of 10:0.2:3:12, heat rapidly to 1300°C, keep warm for 40 minutes, and then rapidly cool. Soak in 10 times the weight of 6% hydrochloric acid for 1 day, filter, wash with distilled water until pH > 5, and dry. Add Lithium Carbonate 5 and Molybdenum Trioxide 2 (based on the weight of tantalum pentoxide as 10) to grind finely, heat to 1200°C, keep warm for 20 minutes, and cool to form a stabilizer.

[0024] Take stabilizer 12, silicon dioxide 30, lead oxide 12, cadmium sulfur selenide 18.3, aluminum oxide 12, boron trioxide 10, zirconium dioxide 53, germanium dioxide 1.1, magnesium oxide 2.4, carbonic acid by weight Calcium 8, Lithium Carbonate 2, Potassium Carbonate 16, Sodium Carbonate 2, mixed with water of 1 times the weight of the above raw materials, and ground to 200 mesh. It can be stale for 1 month.

[0025...

Embodiment 2

[0027] Take tantalum pentoxide, zinc oxide, antimony trioxide, and silicon dioxide powder and mix and grind them to 250 mesh according to the following weight ratio of 10:0.2:3:12, heat rapidly to 1300°C, keep warm for 40 minutes, and then rapidly cool. Soak in 10 times the weight of 5% sulfuric acid for 1 day, filter, wash with distilled water until pH > 5, and dry. Add Lithium Carbonate 5 and Molybdenum Trioxide 2 (based on the weight of tantalum pentoxide as 10) to grind finely, heat to 1200°C, keep warm for 20 minutes, and cool to form a stabilizer.

[0028] Take stabilizer 67, silicon dioxide 20, lead oxide 8, cadmium sulfur selenide 4, aluminum oxide 6, boron trioxide 14, zirconium dioxide 48, germanium dioxide 15, magnesium oxide 3, carbonic acid by weight Calcium 8, Lithium Carbonate 12, Potassium Carbonate 3, Sodium Carbonate 4, mixed with water of 1 times the weight of the above raw materials, and ground to 200 mesh. Stale for 35 days, you can.

[0029] The resulti...

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PUM

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Abstract

The present invention discloses one kind of bright red underglaze color, one kind of overglaze and their preparation process. The bright red underglaze color consists of stabilizer, 0.02-34 wt%, silica 11.3-56 wt%, lead oxide 2.4-27 wt%, cadmium sulfoselenide 2-20 wt%, Al2O3 1.7-27 wt%, B2O3 1.5-27 wt%, CrO2 0.3-32 wt%, GeO2 0.08-33 wt%, MgO 1.4-13 wt%, CaO 0.7-15 wt%, Li2O 0.7-13.2 wt%, K2O 1-7 wt% and NaO 1-5.3 wt%; and the overglaze consists of clinker 5-55 wt%, ZnO 3-12 wt%, albite 5-30 wt%, potash feldspar 7-35 wt%, baked talc 2-16 wt%, silica 2-18 wt%, and kaolin 2-26 wt%. The bright red underglaze color and the overglaze have pure color and very low Pb and Cd leaching amount.

Description

technical field [0001] The invention relates to bright red glaze for firing ceramic underglaze color and its preparation method, ceramic surface glaze and its preparation method and bright red ceramic underglaze color. Background technique [0002] Ceramic underglaze generally refers to ceramic products made by applying colored glaze or painting on the porcelain surface or bottom glaze, and then applying a layer of layer glaze. Because of the protection of the surface glaze, the ceramic products do not fade for a long time, such as brown-green underglaze in the Tang Dynasty. After thousands of years of wind and rain, the color is bright and has a unique artistic effect. Moreover, the coverage of the surface glaze blocks the environmental pollution and human health hazards of toxic substances in underglaze pigments to a certain extent. Compared with overglaze ceramic products, the release of toxic substances is much lower. Xiacai's ceramic products are very popular and have ...

Claims

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Application Information

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IPC IPC(8): C04B41/86C03C8/02C03C8/14C04B33/34
Inventor 胡晓鸿胡天霏胡晓沩
Owner 胡天霏
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