The invention discloses a preparation method of rhombohedral alpha type
ferric oxide. The preparation method comprises the following steps of S1, preparing a water-soluble
ferric salt water solution;S2, adding a
phosphine organic matter into the water-soluble
ferric salt water solution, and obtaining a reaction mixture; S3, carrying out
microwave hydrothermal reaction on the reaction mixture for0.5h to 2.0h at 180 DEG C to 220 DEG C, and obtaining a
solid-liquid mixture; S4, carrying out
solid-liquid separation on the
solid-liquid mixture, and cleaning and
drying a solid to obtain the rhombohedral alpha type ferric
oxide. According to the preparation method of the rhombohedral alpha type ferric
oxide provided by the invention, the water-soluble ferric salt is adopted as a
raw material, the
phosphine organic matter is then added, a
lone pair electron carried by a
phosphorus atom is utilized to be selectively adsorbed on the particle surface, and the growth rate of the particle surfaceespecially a special (104)
crystal face in a
specific growth direction is slowed down, so that the specific
crystal face is finally exposed on the surface. According to the preparation method of therhombohedral alpha type ferric oxide provided by the invention, the reaction efficiency is high, the preparation process is simple, and the preparation cost is effectively reduced; meanwhile, the obtained product is high in purity, high in yield, uniform in particle size and stable in performance.