The application discloses a high-
crystallinity sodium-rich rhombohedral structure
Prussian blue material and a preparation method thereof, and comprises the following steps: S1, preparation of a first precursor solution: uniformly dissolving and mixing
transition metal salt, doped active
metal salt and a chelating agent to obtain the first precursor solution; S2, preparation of a second precursor solution: dissolving
ferrocyanide salt in water to obtain the second precursor solution; S3, preparation of a precursor mixture: injecting the first precursor solution and the second precursor solution into a
buffer solution containing inorganic
sodium salt and a surfactant, and continuously stirring to obtain the precursor mixture; S4, separation of the
Prussian blue material, and the
Prussian blue material is obtained; wherein the stoichiometric ratio of the
transition metal salt, the doped active
metal salt, the
ferrocyanide salt and the chelating agent is (5-x):x:5:y, y is greater than or equal to 3, and the value range of x is 0.1-5. The application has the characteristics of high
crystallinity, excellent electrochemical performance and controllable process.