LCD sheet glass

A liquid crystal display and glass technology, applied in the field of boro-aluminosilicate substrate glass, can solve the problems of difficult clarification and homogenization of glass liquid, easy crystallization, high viscosity at high temperature, etc., to improve chemical stability and reduce expansion coefficient. , the effect of reducing the liquidus temperature

Inactive Publication Date: 2007-10-31
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these glasses have a high strain temperature, because the glass does not contain alkali metal oxides, the glass is difficult to melt. Generally, the melting temperature is higher than 1620 ° C. Due to the high melting temperature and high viscosity at high temperature, the glass liquid is not easy to clarify and homogenize. and because the molding temperature is relatively high, the temperature of the tin bath rises, causing serious volatilization of the tin liquid, which brings great difficulties to production
[0003] The applicant of this patent has basically solved the above problems by adding rare earth elements such as lanthanum, cerium, praseodymium and ytterbium, but there are still deficiencies, such as lowering the melting and clarifying temperature of the glass is still not ideal, and it is easy to produce analyte during the glass forming process. crystal phenomenon, therefore, it is necessary to further solve the above problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] The glass tank kiln adopts double-flow liquid hole negative pressure clarification kiln, adopts the existing oxy-fuel combustion technology and negative pressure clarification technology for production, and adopts conventional float glass technology to form.

[0018] The specific operation is: the glass batch material of the liquid crystal display substrate glass contains quartz sand, alumina, boric acid, calcium carbonate, barium carbonate and rare earth oxides; the contents of the basic glass oxides are (kg): SiO 2 50, Al 2 o 3 6,B 2 o 3 1, CaO 3, BaO 0.5, the contents of mixed rare earth oxides are (kg): La 2 o 3 0.5, CeO 2 5, Y 2 o 3 1, Nd 2 o 3 1.5; Add the batch materials containing the above oxides into the double-flow liquid hole negative pressure clarification kiln. The tank enters the forming part—the tin tank to form a strip-shaped continuous glass plate, which is cut into finished products after annealing.

[0019] During the implementation...

Embodiment 2

[0027]The utilization and processing method of the glass tank kiln are the same as in the first embodiment, the difference is that the glass basic oxide components and mixed rare earth oxide components of the liquid crystal display substrate glass are selected differently, and the basic glass oxide and mixed rare earth oxide components in this embodiment The weight unit of oxide is kilogram, wherein: SiO 2 70 parts by weight, Al 2 o 3 20 parts by weight, B 2 o 3 15 parts by weight, 15 parts by weight of MgO, 20 parts by weight of CaO, 15 parts by weight of SrO, 19 parts by weight of BaO, 9 parts by weight of ZnO, ZrO 2 2 parts by weight, SnO 2 5 parts by weight, TiO 2 5 parts by weight, La 2 o 3 5.0 parts by weight, CeO 2 0.001 parts by weight, Y 2 o 3 0.001 parts by weight.

[0028] During the production process, it was observed that the molten glass can be fully clarified and homogenized, and no crystallization phenomenon occurs during the glass forming pr...

Embodiment 3

[0030] The utilization and processing method of the glass tank kiln are the same as the first embodiment, the difference is that the glass basic oxide components of the liquid crystal display substrate glass are selected differently, the basic glass oxide content and the weight unit of the mixed rare earth oxide in this embodiment In kilograms, of which: SiO 2 62 parts by weight, Al 2 o 3 20 parts by weight, B 2 o 3 8 parts by weight, MgO 5.5 parts by weight, CaO 4 parts by weight, SrO 5 parts by weight, BaO 2.2 parts by weight, ZnO 2 parts by weight, ZrO 2 1 part by weight, La 2 o 3 0.01 parts by weight, CeO 2 8 parts by weight, Y 2 o 3 2 parts by weight, Nd 2 o 3 0.001 parts by weight.

[0031] During the production process, it was found that the molten glass can be fully clarified and homogenized, and no crystallization occurs during the glass forming process.

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Abstract

The invention discloses a base plate glass with rare-earth element to dope liquid crystal display device (TFT-LCD), which is characterized by the following: comprising glass basic oxide, lanthanum oxide, cerium oxide, neodymium oxide and or yttrium oxide; setting the mass ratio at (60. 5-195):(0. 003-28) of the glass basic oxide and all rare-earth oxide; adding at least three rare-earth oxide; improving the fusion of the glass; accelerating clarification and equalization in the course of formation; preventing glass crystallizer; decreasing the liquid phase temperature; delaying devitrification speed of the glass; fitting for productive technology of float glass; improving chemical stability of the glass; decreasing the expansion coefficient; fitting for large scale float glass procession.

Description

technical field [0001] The invention relates to a boroaluminosilicate substrate glass, in particular to a boroaluminosilicate alkali-free substrate glass doped with rare earth elements, which is used for manufacturing a display screen of a thin film transistor liquid crystal display (TFT-LCD). Background technique [0002] In the process of manufacturing thin film transistor liquid crystal display (TFT-LCD), the substrate glass is subjected to repeated heat treatment, with the highest temperature reaching 625°C. In order to prevent dimensional changes caused by glass deformation, the substrate glass must remain rigid at this temperature without any viscous flow phenomenon, so the strain temperature Tst of the glass must be higher than 625°C, if the insurance amount of 25°C is added , the strain temperature of the glass should reach 650°C; considering the matching of the thermal expansion coefficient, the thermal expansion coefficient of the substrate glass should be controll...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/095
CPCC03C3/095
Inventor 黄幼榕崔竹高锡平李长久顾真安
Owner CHINA BUILDING MATERIALS ACAD
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