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Gradient compound material and preparation method

A composite material and gradient technology, which is applied in the preparation of gradient composite materials, metal gradient composite materials and its preparation, can solve the problems of large gaps in physical and chemical properties, high cost, and difficult composite layers, etc., and achieve small differences in physical and chemical properties and high composition Large variance, the effect of reducing manufacturing costs

Inactive Publication Date: 2010-06-09
NANJING SHENGRUN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Such as mechanically connected and bonded composite materials, the interface is poorly bonded; the interface composition of the welding material changes sharply, the bonding strength is low, and the physical and chemical properties vary greatly; the explosive composite and rolling composite materials not only have a sharp change in the interface composition, but the thickness of the composite layer is small and uniform. Poor performance, and only suitable for plate and strip; Diffusion welding materials have high requirements on workpiece shape and surface, and high manufacturing cost (need to be carried out under vacuum and certain pressure); Materials manufactured by self-propagating method can only form part of the metallurgical bond with the matrix, which is very difficult It is difficult to form a continuous and uniform composite layer, and the interfacial bonding strength is low; the material varieties manufactured by casting composite and sintering methods are limited and the manufacturing cost is high; ion implantation, laser cladding, thermal dipping, hot dipping, thermal spraying, Laser heat treatment and electron beam heat treatment are not only expensive processing equipment, complicated process and high cost, but also the working layer is very thin, generally only 0.1-3mm, such as the method of plasma scanning spraying metal surface mentioned in CN011151979, for large workpieces, Complicated cross-sections or workpieces that require subsequent processing have little practical value; electroplating, chemical conversion treatment, electroless plating, vapor deposition, and coating layers cannot form metallurgical bonds with the substrate, and the interface bonding strength is low, which does not constitute a metal structure in the actual sense Composite materials; spray welding and surfacing layer materials can form a firm metallurgical bond with the substrate, but the material interface composition obtained by the current process changes sharply, the physical and chemical properties vary greatly, and the working layer has a single performance. Most of them are used for workpiece size repair
[0007] To sum up, in the existing metal composite materials and composite technology, there is no concept and method of gradient composite materials in which the matrix, interface layer, and working layer material composition and performance change in a gradient manner, and the use of this method for wider applications

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032]The base material of the gradient composite profile steel blanking roll is 70Mn cast steel with a unit weight of 5 tons. The first transition layer is made of Cr-based alloy (containing Cr0.5-5%) and the thickness is 0.1-3mm; the second transition layer is made of CrMo-based alloy. (Containing Cr0.5~5%, Mo0.1~4%), thickness 0.5~3mm; working layer material adopts WCrMoV series high-speed steel (containing W4~15%, Cr2~8%, Mo2~15%, V2~10 %), thickness 3-30mm. The materials of the first transition layer and the second transition layer were prepared as solid welding wires with a diameter of 4mm, and the materials of the working layer were prepared as 2.4mm flux-cored welding wires. The composite process adopts submerged arc welding, the composite working current of the first transition layer and the second transition layer is 360A, the working voltage is 36V, and the flux is sintered; the composite working current of the working layer is 280A, the working voltage is 36V, and ...

Embodiment 2

[0034] Gradient composite material stainless steel strip blanking roll base material is semi-steel with a carbon content of 1.2-2.0 with a unit weight of 5 tons, and the first transition layer is made of NiCr alloy (containing Ni0.5-5%, Cr0.5-5%) , thickness 1-5mm; the second transition layer adopts NiCrMo alloy (containing Ni0.5-5%, Cr2-10%, Mo0.5-3%), thickness 1-5mm; working layer material adopts WC alloy (WC 0.05~5%), thickness 3~30mm. The materials of the first transition layer and the second transition layer were prepared as solid welding wires with a diameter of 3.2mm, and the materials of the working layer were prepared as 2.4mm flux-cored welding wires. The composite process adopts submerged arc welding, the composite working current of the first transition layer and the second transition layer is 360A, the working voltage is 36V, and the flux is sintered; the composite working current of the working layer is 280A, the working voltage is 36V, and the flux is sintered....

Embodiment 3

[0036] The base material of gradient composite material stainless steel strip blanking roll is 75CrMo with a unit weight of 5 tons, and the first transition layer and the second transition layer are both made of NiCrMo alloy (containing Ni0. ~3%), the total thickness is 2~7mm; the material of the working layer is martensitic stainless steel, and the thickness is 3~30mm. The materials of the first transition layer, the second transition layer and the working layer are all prepared as solid welding wire with a diameter of 3.2mm, and the last material of the working layer has a particle size of 50-100 mesh nickel-based tungsten carbide and titanium carbide powder (containing 0.01-50% tungsten carbide) , titanium carbide 0.01 to 50%). The first transition layer, the second transition layer, and the material composite process of the working layer all adopt submerged arc welding. The composite working current of the first transition layer and the second transition layer is 380A, the...

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Abstract

The gradient composite material consists of a base, transition layers and a working layer combined through metallurgical combination, and has composition and performance in controlled gradient changefrom the base to the working layer. The transition layers include several layers, and the working layer may be one or several layers. Each of the transition layers has thickness of 0.1-50 mm, preferably 0.5-5 mm, and the working layer has thickness of 0.1-1000 mm, preferably 2-30 mm. When the working layer is of ceramic or high alloy, the transition layer adjacent to the working layer has high content of ceramic or alloy. The composite material has reasonable comprehensive performance and the working layer has excellent performance.

Description

1. Technical field [0001] The invention relates to a preparation method of a gradient composite material, in particular to a metal gradient composite material and the preparation method, and belongs to the technical field of metal structure composite materials. 2. Background technology [0002] With the rapid development of modern industry, higher requirements are put forward for metal parts, requiring products to work for a long time under high parameters (such as high temperature, high speed, high pressure), high automation and harsh working conditions, which will inevitably affect the material The requirements for wear resistance and corrosion resistance are becoming increasingly stringent. In some cases, it is often uneconomical or impractical to use precious metals or alloys to manufacture overall equipment and parts even if they can meet the performance requirements. required material. Therefore, new structural composite materials are of great significance for improv...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B33/00B32B15/00B32B18/00
Inventor 陈洪冰徐俊陈家苏
Owner NANJING SHENGRUN TECH
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